Related papers: A time-dependent formulation of multi-reference pe…
In this work we intend to study a class of time-dependent quantum systems with non-Hermitian Hamiltonians, particularly those whose Hermitian counterpart are important for the comprehension of posed problems in quantum optics and quantum…
We consider a version of the symmetric Anderson impurity model (compactified) which has a non-Fermi liquid weak coupling regime. We find that in the Majorana fermion representation, perturbation theory can be conveniently developed in terms…
We develop a time-dependent variational Monte Carlo (t-VMC) method for quantum dynamics of strongly correlated electrons. The t-VMC method has been recently applied to bosonic systems and quantum spin systems. Here, we propose a…
In this work we develop a new classical perturbation theory for water which incorporates the transition to tetrahedral symmetry in both the dispersion and hydrogen bonding contributions to the free energy. This transition is calculated…
We present an algebraic, nondiagrammatic derivation of finite-temperature second-order many-body perturbation theory [FT-MBPT(2)], using techniques and concepts accessible to theoretical chemical physicists. We give explicit expressions not…
Treating electron correlation more accurately and efficiently is at the heart of the development of electronic structure methods. In the present work, we explore the use of stochastic approaches to evaluate high-order electron correlation…
In the past decades, time ordered perturbation theory was very successful in describing relativistic scattering processes. It was developed for local quantum field theories. However, there are field theories which are governed by non-local…
Noether and Lie symmetry analyses based on point transformations that depend on time and spatial coordinates will be reviewed for a general class of time-dependent Hamiltonian systems. The resulting symmetries are expressed in the form of…
We make the first steps towards a generic theory for energy spreading and quantum dissipation. The Wall formula for the calculation of friction in nuclear physics and the Drude formula for the calculation of conductivity in mesoscopic…
We propose a perturbative approach to determine the time-dependent Dyson map and the metric operator associated with time-dependent non-Hermitian Hamiltonians. We apply the method to a pair of explicitly time-dependent two dimensional…
We study the 2nd-order scalar, vector and tensor metric perturbations in Robertson-Walker (RW) spacetime in synchronous coordinates during the radiation dominated (RD) stage. The dominant radiation is modeled by a relativistic fluid…
Assuming the S-matrix on noncommutative (NC) spacetime can still be developped perturbatively in terms of the time-ordered exponential of the interaction Lagrangian, we investigate the perturbation theory of NC field theory. We first work…
There is an incompatibility between gauge invariance and the semi-classical time-dependent perturbation theory commonly used to calculate light absorption and scattering cross-sections. There is an additional incompatibility between…
The original formulation (Phys. Rev. Lett. 119, 063002, 2017) of the natural orbital functional - second-order M{\o}ller-Plesset (NOF-MP2) method is based on the MP2 that uses the canonical Hartree-Fock molecular orbitals. The current work…
Second-order M{\o}ller-Plesset perturbation theory (MP2) often breaks down catastrophically in small-gap systems, leaving much to be desired in its performance for myriad chemical applications such as noncovalent interactions,…
A new general approach is introduced for definining an optimum zero-order Hamiltonian for Rayleigh-Schr\"odinger perturbation theory. Instead of taking the operator directly from a model problem, it is constructed to be a best fit to the…
We present a method for calculation of the second-order exchange-dispersion energy in the framework of the symmetry-adapted perturbation theory (SAPT) for weakly interacting monomers described with multiconfigurational wave functions. The…
The ordinary time-dependent perturbation theory of quantum mechanics, that describes the interaction of a stationary system with a time-dependent perturbation, predicts that the transition probabilities induced by the perturbation are…
The theoretical description of the thermodynamics of water is challenged by the structural transition towards tetrahedral symmetry at ambient conditions. As perturbation theories typically assume a spherically symmetric reference fluid,…
Variational and perturbative relativistic energies are computed and compared for two-electron atoms and molecules with low nuclear charge numbers. In general, good agreement of the two approaches is observed. Remaining deviations can be…