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By generalizing the traditional concept of heat dQ and work dW to also include their time-dependent irreversible components d_{i}Q and d_{i}W allows us to express them in terms of the instantaneous internal temperature T(t) and pressure…

Chemical Physics · Physics 2011-05-30 P. D. Gujrati

The status of heat and work in nonequilibrium thermodynamics is quite confusing and non-unique at present with conflicting interpretations even after a long history of the first law in terms of exchange heat and work, and is far from…

Chemical Physics · Physics 2012-06-05 P. D. Gujrati

The review deals with a novel approach (MNEQT) to nonequilibrium thermodynamics (NEQT) that is based on the concept of internal equilibrium (IEQ) in an enlarged state space involving internal variables as additional state variables. The…

Statistical Mechanics · Physics 2021-12-15 P. D. Gujrati

For open systems described by the quantum Markovian master equation, we study a possible extension of the Clausius equality to quasistatic operations between nonequilibrium steady states (NESSs). We investigate the excess heat divided by…

Statistical Mechanics · Physics 2013-09-10 Tatsuro Yuge , Takahiro Sagawa , Ayumu Sugita , Hisao Hayakawa

This Article investigates dissipative preparation of entangled non-equilibrium steady states (NESS). We construct a collision model where the open system consists of two qubits which are coupled to heat reservoirs with different…

Quantum Physics · Physics 2021-12-08 Daniel Heineken , Konstantin Beyer , Kimmo Luoma , Walter T. Strunz

We initially prepare a quantum linear oscillator weakly coupled to a bath in equilibrium at an arbitrary temperature. We disturb this system by varying a Hamiltonian parameter of the coupled oscillator, namely, either its spring constant or…

Statistical Mechanics · Physics 2015-05-27 Ilki Kim

Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a…

Quantum Physics · Physics 2022-05-03 Ning Zhang , Si-Yuan Bai , Chong Chen

We report two results complementing the second law of thermodynamics for Markovian open quantum systems coupled to multiple reservoirs with different temperatures and chemical potentials. First, we derive a nonequilibrium free energy…

Statistical Mechanics · Physics 2019-04-18 Krzysztof Ptaszynski , Massimiliano Esposito

Classical thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a…

Quantum Physics · Physics 2018-12-18 Md. Manirul Ali , Wei-Ming Huang , Wei-Min Zhang

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

Statistical Mechanics · Physics 2013-02-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is…

Statistical Mechanics · Physics 2019-09-10 Sergey Sobolev

Recently, in their attempt to construct steady state thermodynamics (SST), Komatsu, Nakagwa, Sasa, and Tasaki found an extension of the Clausius relation to nonequilibrium steady states in classical stochastic processes. Here we derive a…

Statistical Mechanics · Physics 2015-05-28 Keiji Saito , Hal Tasaki

We extend on ideas from standard thermodynamics to show that temperature can be assigned to a general nonequilibrium quantum system. By choosing a physically motivated complete set of observables and expanding the system state thereupon,…

Quantum Physics · Physics 2021-05-26 S. Alipour , F. Benatti , M. Afsary , F. Bakhshinezhad , M. Ramezani , T. Ala-Nissila , A. T. Rezakhani

Isoenergetic thermalization amongst $n$ bodies is a well-known irreversible process, bringing the bodies to a common temperature $T_F$ and leading to a rise in the total entropy of the bodies. We express this change in entropy using the…

Statistical Mechanics · Physics 2024-11-07 Vansh Narang , Renuka Rai , Ramandeep S. Johal

An intriguing phenomenon in non-equilibrium quantum thermodynamics is the asymmetry of thermal processes. Relaxation to thermal equilibrium is the most important dissipative process, being a key concept for the design of heat engines and…

Quantum Physics · Physics 2025-04-09 Álvaro Tejero , Rafael Sánchez , Laiachi El Kaoutit , Daniel Manzano , Antonio Lasanta

A known aspect of the Clausius inequality is that an equilibrium system subjected to a squeezing $\d S<0$ of its entropy must release at least an amount $|\dbarrm Q|=T|\d S|$ of heat. This serves as a basis for the Landauer principle, which…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

We consider stationary driven systems in contact with a thermal equilibrium bath. There is a constant (Joule) heat dissipated from the steady system to the environment as long as all parameters are unchanged. As a natural generalization…

Statistical Mechanics · Physics 2020-01-29 Christian Maes , Karel Netocny

A definition of nonequilibrium free energy $\mathcal{F}_{\textsc{s}}$ is proposed for dynamical Gaussian quantum open systems strongly coupled to a heat bath and a formal derivation is provided by way of the generating functional in terms…

Statistical Mechanics · Physics 2021-03-10 Jen-Tsung Hsiang , B. L. Hu

The second law of thermodynamics is a fundamental law of Nature. It is almost universally associated with the Clausius inequality that lower bounds a change in entropy by the ratio of supplied heat and temperature. However, this result…

Quantum Gases · Physics 2020-05-11 Daniel Mayer , Eric Lutz , Artur Widera

Non-equilibrium quantum thermodynamics is an intensively developing field with many existing applications. We study the dynamics of temperatures and chemical potentials of fermionic reservoirs coupled to an open quantum system. We show that…

Quantum Physics · Physics 2024-12-23 I. V. Vovchenko , A. A. Zyablovsky , A. A. Pukhov , E. S. Andrianov
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