Related papers: Ferrielectricity in smectic-C* dechiralisation lin…
Ferroelectric ordering, the electroclinic effect and chiral smectic C (SmC*) - smectic A (SmA*) phase transitions in thin planar ferroelectric liquid crystal (FLC) cells are studied by means of linear electrooptic and second harmonic…
The ferroelectric (Sm C$^*$) -- antiferroelectric (Sm C$^*_A$) -- reentrant ferroelectric (re Sm C$^*$) phase temperature sequence was observed for system with competing synclinic - anticlinic interactions. The basic properties of this…
Recently we have formulated theory of bi-layer-dimerized chiral liquid antiferroelectric crystals. The spontaneous polarization has been increased owing to the strong interaction of the aromatic cores of the rod like liquid crystal…
We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…
Equilibrium and dynamic behaviors of dechiralisation lines occurring below SmC* cell boundaries in planar geometry consitute a polemic topic for several decades. We report new observations in the SmC* phase of the strongly polarized liquid…
Ferroelectric ordering in liquids is a fundamental question of physics. Here, we show that ferroelectric ordering of the molecules causes formation of recently reported splay nematic liquid-crystalline phase. As shown by dielectric…
We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The…
Under an electric field, chiral smectic liquid crystals transit usually to the unwound SmC* phase where the helical structure is completely unrolled. Sometimes the sample transits initially towards an intermediate polar state before the…
Metal-organic frameworks comprehend a wide class of hybrid organic-inorganic materials with general structure A$_m$BX$_n$, with $A$ and $X$ being organic molecules and B a metal cation. This often results in enhanced structural flexibility…
Using a generalized Landau theory involving orientational, layering, tilt, and biaxial order parameters we analyze the smectic-A* and smectic-C* (Sm-A* -- Sm-C*) transition, showing that a combination of small orientational order and large…
The polarization and density modulation associated with antiferroelectric ordering is studied experimentally as a function of temperature in two ferroelectric nematic liquid crystals, the prototypical single compound (DIO) and a commercial…
The Landau theory of phase transitions has been re-examined under the framework of a modified mean field theory in ferroelectrics. By doing so, one can see that there are two atomic movements involved in the ferroelectric phase transition;…
A material showing a sequence of three ferroelectric liquid crystalline phases below the paraelectric nematic phase has been synthesized and studied. The polar order of molecules appearing due to the dipole-dipole interactions in the NF…
Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with…
The recent discovery of spontaneous chiral symmetry breaking has demonstrated the possibility of discovering the exotic textures of ferromagnetic systems in liquid crystalline fluid ferro-electrics. We show that the polar smectic mesophase…
In the review we briefly analyze the state-of-art in the theory of flexoelectric phenomena and analyze how significantly the flexoelectric coupling can change the polar order parameter distribution in different ferroics and liquid crystals.…
General microscopic mechanism of ferroelectric ordering in chiral smectic C* liquid crystals is considered. It is shown that if the mesogenic molecules have a sufficiently low symmetry, the spontaneous polarization is proportional to one of…
We explore the possibility that the large electroclinic effect observed in ferroelectric liquid crystals arises from the presence of an ordered array of disclination lines and walls. If the spacing of these defects is in the subvisible…
The discovery of the ferroelectric nematic phase has brought with it a plethora of new polar liquid crystalline phases. One in particular is the anti-ferroelectric smectic A SmA\textsubscript{AF} phase. In this letter we show via…
Thermoelastic phenomena associated with orientational phase transition in solid C60 are considered. Coupling of the order parameter with elastic strain is analyzed in the Landau theory of phase transitions. Wide range of possible…