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The change of the von Neumann entropy of a set of harmonic oscillators initially in thermal equilibrium and interacting linearly with an externally driven quantum system is computed by adapting the Feynman-Vernon influence functional…

Statistical Mechanics · Physics 2018-04-04 Erik Aurell , Ralf Eichhorn

Non-equilibrium and equilibrium thermodynamics of an interacting component in a relativistic multi-component system is discussed covariantly by exploiting an entropy identity. The special case of the corresponding free component is…

General Relativity and Quantum Cosmology · Physics 2020-01-08 Wolfgang Muschik

The article presents new model of equilibrium in open chemical systems suggesting a linear dependence of the reaction shift from equilibrium in presence of the external thermodynamic force. Basic equation of this model contains traditional…

Chemical Physics · Physics 2007-05-23 B. Zilbergleyt

Equilibrium statistical mechanics provides a robust framework for characterizing phase transitions in systems whose microsopic dynamics are time-reversible. Efforts to develop and validate theoretical frameworks for time-irreversible,…

Soft Condensed Matter · Physics 2025-12-18 Stuart J. Thomson , Jack-William Barotta , Daniel M. Harris

Onsager's phenomenological equations successfully describe irreversible thermodynamic processes. They assume a symmetric coupling matrix between thermodynamic fluxes and forces. It is easily shown that the antisymmetric part of a coupling…

Chemical Physics · Physics 2020-08-10 Thomas Heimburg

The concept of work is studied in quantum thermostatistics of a system surrounded by an environment and driven by an external force. It is found that there emerges the gauge theoretical structure in a nonequilibrium process, the field of…

Statistical Mechanics · Physics 2009-11-11 Sumiyoshi Abe , Satoshi Kaneko

On the assumption that experimentally validated tabulated thermodynamic properties of saturated fluids published by the National Institute of Standards and Technology are accurate, a theoretical thermodynamic cycle can be demonstrated that…

Chemical Physics · Physics 2018-08-15 Matthew David Marko

Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the…

Statistical Mechanics · Physics 2013-02-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

The excess work required to drive a stochastic system out of thermodynamic equilibrium through a time-dependent external perturbation is directly related to the amount of entropy produced during the driving process, allowing excess work and…

Statistical Mechanics · Physics 2021-03-15 Steven J Large , Jannik Ehrich , David A Sivak

Simulations are performed of a small quantum system interacting with a quantum environment. The system consists of various initial states of two harmonic oscillators coupled to give normal modes. The environment is "designed" by its level…

Statistical Mechanics · Physics 2015-06-15 George L. Barnes , Michael E. Kellman

Starting from microscopic mechanics, we derive thermodynamic relations for heat conducting nonequilibrium steady states. The extended Clausius relation enables one to experimentally determine nonequilibrium entropy to the second order in…

Statistical Mechanics · Physics 2009-11-13 Teruhisa S. Komatsu , Naoko Nakagawa , Shin-ichi Sasa , Hal Tasaki

The nature of the behaviour of an isolated many-body quantum system periodically driven in time has been an open question since the beginning of quantum mechanics. After an initial transient, such a system is known to synchronize with the…

Statistical Mechanics · Physics 2014-04-22 Achilleas Lazarides , Arnab Das , Roderich Moessner

The Casimir-Polder force is analyzed when an atom is moving at a constant velocity relative to a collection of translationally invariant macroscopic bodies with generic shapes and compositions. The interaction is described within an…

Quantum Physics · Physics 2026-02-19 D. Reiche , B. Beverungen , K. Busch , F. Intravaia

In striking contrast to equilibrium systems, inertia can profoundly alter the structure of active systems. Here, we demonstrate that driven systems can exhibit effective equilibrium-like states with increasing particle inertia, despite…

Soft Condensed Matter · Physics 2023-02-23 Ahmad K. Omar , Katherine Klymko , Trevor GrandPre , Phillip L. Geissler , John F. Brady

Thermodynamic quantities of the hard-sphere system in the steady state with a small heat flux are calculated within the continuous media approach. Analytical expressions for pressure, internal energy, and entropy are found in the…

Statistical Mechanics · Physics 2017-02-13 Y. A. Humenyuk

Entropy in nonequilibrium statistical mechanics is investigated theoretically so as to extend the well-established equilibrium framework to open nonequilibrium systems. We first derive a microscopic expression of nonequilibrium entropy for…

Statistical Mechanics · Physics 2007-06-13 Takafumi Kita

It is theoretically predicted that the Nernst coefficient is strongly suppressed and the thermal conductance is quantized in the quantum Hall regime of the two-dimensional electron gas. The Nernst effect is the induction of a thermomagnetic…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Hiroaki Nakamura , Naomichi Hatano , Ryoen Shirasaki

In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…

Statistical Mechanics · Physics 2025-01-22 Markus Hofer , Jan Korbel , Rudolf Hanel , Stefan Thurner

The extension of equilibrium thermodynamics to non-equilibrium systems is based on the assumption of "local equilibrium," followed by the assumption that an entropy-density function may be defined, and that this entropy-density would have…

Chemical Physics · Physics 2018-03-12 Arieh Ben-Naim

A classical particle system coupled with a thermostat driven by an external constant force reaches its steady state when the ensemble-averaged drift velocity does not vary with time. The statistical mechanics of such a system is derived…

Statistical Mechanics · Physics 2020-12-02 Jie Yao , Yanting Wang
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