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Related papers: Cavity-controlled chemistry in molecular ensembles

200 papers

We study a generic cavity-QED system where a set of (artificial) two-level dipoles is coupled to the electric field of a single-mode LC resonator. This setup is used to derive a minimal quantum mechanical model for cavity QED, which…

Quantum Physics · Physics 2018-04-19 Daniele De Bernardis , Tuomas Jaako , Peter Rabl

In this paper we develop quantum dynamical methods capable of treating the dynamics of chemically reacting systems in an optical cavity in the vibrationally strong-coupling (VSC) limit at finite temperatures and in the presence of a…

Quantum Physics · Physics 2025-02-11 Lachlan P. Lindoy , Arkajit Mandal , David R. Reichman

Manipulation of quantum systems is the basis for many promising quantum technologies. However, how quantum mechanical principles can be used to manipulate the dynamics of quantum dissipative systems remains unanswered because of strong…

Mesoscale and Nanoscale Physics · Physics 2019-02-27 Nguyen Thanh Phuc , Akihito Ishizaki

Quantum control of a system requires the manipulation of quantum states faster than any decoherence rate. For mesoscopic systems, this has so far only been reached by few cryogenic systems. An important milestone towards quantum control is…

Quantum Physics · Physics 2021-02-01 Andrés de los Ríos Sommer , Nadine Meyer , Romain Quidant

In this work, we provide an overview of how well-established concepts in the fields of quantum chemistry and material sciences have to be adapted when the quantum nature of light becomes important in correlated matter-photon problems.…

Quantum Physics · Physics 2017-04-12 Johannes Flick , Michael Ruggenthaler , Heiko Appel , Angel Rubio

Strong light-matter interaction in cavity environments is emerging as a promising approach to control chemical reactions in a non-intrusive and efficient manner. The underlying mechanism that distinguishes between steering, accelerating, or…

Quantum Physics · Physics 2022-12-20 Christian Schäfer , Johannes Flick , Enrico Ronca , Prineha Narang , Angel Rubio

The light-matter interaction can be utilized to qualitatively alter physical properties of materials. Recent theoretical and experimental studies have explored this possibility of controlling matter by light based on driving many-body…

Mesoscale and Nanoscale Physics · Physics 2020-11-11 Yuto Ashida , Atac Imamoglu , Jerome Faist , Dieter Jaksch , Andrea Cavalleri , Eugene Demler

Recently, we predicted theoretically that in cavities that support several longitudinal modes, strong coupling can occur in very different manners, depending on the system parameters. Distinct longitudinal cavity modes are either entangled…

Quantum Physics · Physics 2023-10-10 M. Godsi , A. Golombek , M. Balasubrahmaniyam , T. Schwartz

We propose a quantum simulation of a two-level atom coupled to a single mode of the electromagnetic field in the ultrastrong-coupling regime based upon resonant Raman transitions in an atom interacting with a high finesse optical cavity…

Quantum Physics · Physics 2014-08-27 Arne L. Grimsmo , Scott Parkins

Plasmonic nanocavities are a promising platform for strong light-matter coupling and enhanced spectroscopies at the single-molecule level. These nanoscale environments are challenging to model due to their strongly multimodal character and…

Chemical Physics · Physics 2026-03-16 Jonathan H. Fetherolf , Tao E. Li , Sharon Hammes-Schiffer

Electrical control of spins at the nanoscale offers significant architectural advantages in spintronics, because electric fields can be confined over shorter length scales than magnetic fields. Thus, recent demonstrations of electric-field…

Mesoscale and Nanoscale Physics · Physics 2021-10-15 Junjie Liu , Jakub Mrozek , Aman Ullah , Yan Duan , José J. Baldoví , Eugenio Coronado , Alejandro Gaita-Ariño , Arzhang Ardavan

Polaritonic states, which arise from strong coupling between light and matter, show great promise in modifying chemical reactivity. However, reproducible enhancement of chemical reactions with polaritons is challenging due to a lack of…

Chemical Physics · Physics 2025-01-14 Shahzad Alam , Yicheng Liu , Russell J. Holmes , Renee R. Frontiera

When molecular transitions strongly couple to photon modes, they form hybrid light-matter modes called polaritons. Collective vibrational strong coupling is a promising avenue for control of chemistry, but this can be deterred by the large…

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

Many effects in the interaction between atoms and a cavity that are usually de-scribed in quantum mechanical terms (cavity quantum electrodynamics, cavity QED) can be understood and quantitatively analyzed within a classical framework. We…

The quantized lateral motional states and the spin states of electrons trapped on the surface of superfluid helium have been proposed as basic building blocks of a scalable quantum computer. Circuit quantum electrodynamics (cQED) allows…

Mesoscale and Nanoscale Physics · Physics 2016-03-30 Ge Yang , A. Fragner , G. Koolstra , L. Ocola , D. A. Czaplewski , R. J. Schoelkopf , D. I. Schuster

Suggestion of modifications of finite-dimensional QED models are proposed for interpreting chemical reactions in terms of artificial atoms and molecules on quantum dots placed in optical cavities. Moving both photons and atoms is possible…

This study investigates the dynamic behavior of polaritons in an optical cavity containing one million molecules, emphasizing the influence of molecular rotation and level disorder on the coupling between molecules and photons. Through…

Optics · Physics 2024-02-22 Wei Liu , Jingqi Chen , Wenjie Dou

Polaritons have gained significant attention for the tantalizing possibility of modifying chemical properties and dynamics by coupling molecules to resonant cavity modes to create hybrid light-matter quantum states. Herein, we implement the…

Chemical Physics · Physics 2025-06-24 Scott M. Garner , Xiaosong Li , Sharon Hammes-Schiffer

Despite the potential paradigm breaking capability of microcavities to control chemical processes, the extent to which photonic devices change properties of molecular materials is still unclear, in part due to challenges in modeling hybrid…

Chemical Physics · Physics 2021-12-30 Raphael F. Ribeiro
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