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Related papers: Ab-initio modeling of an anion $C_{60}^-$ pseudopo…

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A simple, yet accurate solution of the electron-phonon coupling problem in C_{60} is presented. The basic idea behind it is to be found in the parametrization of the ground state electronic density of the system calculated making use of…

Condensed Matter · Physics 2009-10-31 N. Breda , R. A. Broglia , G. Colo` , H. E. Roman , F. Alasia , G. Onida , V. Ponomarev , E. Vigezzi

We present an ab initio pseudopotential local density functional calculation for stoichiometric high-Tc cuprate YBa_2Cu_3O_7 using the plane-wave basis set. We have overcome well-known difficulties in applying pseudopotential methods to…

Condensed Matter · Physics 2009-10-22 Hanchul Kim , Jisoon Ihm

Strutinsky shell corrections for the Cesium-coated fullerenes were investigated. The single particle levels of electrons are obtained using the spherical mean-field potential of a shifted Wood-Saxon type. The parameters of the potential are…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 P. Mierzynski , K. Pomorski

The interactions between atoms and molecules may be described by a potential energy function of the nuclear coordinates. Non-bonded interactions are dominated by repulsive forces at short range and attractive dispersion forces at long…

Cyanation C60 to C60(CN)18 and aziridination from C60 to C60(NH)9 have been studied by unrestricted broken spin symmetry Hartree-Fock approach implemented in semiempirical codes based on AM1 technique. The calculations were focused on…

Mesoscale and Nanoscale Physics · Physics 2010-07-26 E. F. Sheka

We show that C$_{60}$ fullerene molecules can serve as promising building blocks in the construction of versatile crystal structures with unique symmetries using first-principles calculations. These phases include quasi-2D layered…

Mesoscale and Nanoscale Physics · Physics 2025-04-03 Darius Kayley , Bo Peng

The electron--phonon coupling in fullerene C28 has been calculated from first principles. The value of the associated coupling constant lambda/N(0) is found to be a factor three larger than that associated with C60. Assuming similar values…

Superconductivity · Physics 2009-10-31 N. Breda , R. A. Broglia , G. Colo` , G. Onida , D. Provasi , E. Vigezzi

We provide the initial insight into the angle-differential photodetachment spectra of fullerene anions beyond the dipole approximation by utilizing a broadly used modelling of C$_{n}$. In the model, the C$_{n}$ cage is approximated by a…

Atomic Physics · Physics 2018-10-02 V K Dolmatov , A Edwards , C G Lane

By fitting to a database of ab-initio forces and energies, we can extract pair potentials for alloys, with a simple six-parameter analytic form including Friedel oscillations, which give a remarkably faithful account of many complex…

Materials Science · Physics 2015-05-30 M. Mihalkovic , C. L. Henley

We report the synthesis and the electrical properties of fullerene-based molecular junctions on silicon substrate in which the highly \pi-conjugated molecule C60 (\pi quantum well) is isolated from the electrodes by alkyl chains (\sigma…

Mesoscale and Nanoscale Physics · Physics 2010-04-02 D. Guerin , S. Lenfant , S. Godey , D. Vuillaume

We study the electron-phonon coupling in the C60 fullerene within the first-principles GW approach, focusing on the lowest unoccupied t1u three-fold electronic state which is relevant for the superconducting transition in electron doped…

Materials Science · Physics 2015-05-30 Carina Faber , Jonathan Laflamme Janssen , Michel Côté , E. Runge , X. Blase

Buckminsterfullerene C60 has received extensive research interest ever since its discovery. In addition to its interesting intrinsic properties of exceptional stability and electron-accepting ability, the broad chemical tunability by…

Chemical Physics · Physics 2023-11-03 Jianzhi Xu , Joost M. Bakker , Olga V. Lushchikova , Peter Lievens , Ewald Janssens , Gao-Lei Hou

In this paper, motivated by the experimental evidence of rapidly rotating $C_{60}$ molecules in fullerite, we study the low-energy electronic states of rotating fullerene within a continuum model. In this model, the low-energy spectrum is…

Mesoscale and Nanoscale Physics · Physics 2014-05-27 Jonas R. F. Lima , Julio Brandao , Marcio M. Cunha , F. Moraes

A method is developed for generating pseudopotentials for use in correlated-electron calculations. The paradigms of shape and energy consistency are combined and defined in terms of correlated-electron wave-functions. The resulting energy…

Materials Science · Physics 2017-05-26 John R. Trail , Richard J. Needs

A pseudo-Jahn-Teller model describing central atom distortions is proposed for endohedral fullerenes of the form A@C$_{60}$ where A is either a rare gas or a metal atom. A critical (dimensionless) coupling $g_c$ is found, below which the…

Condensed Matter · Physics 2009-10-30 Dennis P. Clougherty , Frederick G. Anderson

We present an optimization algorithm to construct pseudopotentials and use it to generate a set of Optimized Norm-Conserving Vanderbilt (ONCV) pseudopotentials for elements up to Z=83 (Bi) (excluding Lanthanides). We introduce a quality…

Materials Science · Physics 2016-05-04 Martin Schlipf , Francois Gygi

Photoionization cross section of the fullerene ion C60+ has been calculated within a single-electron approximation and also by using a consistent many-body theory accounting for many-electron correlations.

Atomic and Molecular Clusters · Physics 2016-09-20 R. G. Polozkov , V. K. Ivanov , A. V. Solov'yov

We study the electronic states of isolated fullerene anions C$^{n-}_{60}$ ($1\le n \le 6$) taking into account the effective interaction between electrons due to exchange of intramolecular phonons. If the vibronic coupling is strong enough…

Condensed Matter · Physics 2010-03-25 L. Bergomi , Th. Jolicoeur

Considering C$_{60}$ as a model system for describing field emission from the extremity of a carbon nanotip, we explore electron emission from this fullerene excited by an intense, near-infrared, few-cycle laser pulse…

Atomic and Molecular Clusters · Physics 2016-03-23 Cong-Zhang Gao , Phuong Mai Dinh , Peter Kluepfel , Chris Meier , Paul-Gerhard Reinhard , Eric Suraud

Attention: this version-$2$ of the manuscript differs from its previously uploaded version-$1$ (arXiv:1112.6158v1) and subsequently published in 2012 J. Phys. B \textbf{45} 105102 only by a removed typo in Eq.(2) of version-$1$; there was…

Atomic Physics · Physics 2015-06-03 V. K. Dolmatov , J. L. King , J. C. Oglesby