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Quantum interference (QI) effects in molecular junctions may be used to obtain large thermoelectric responses. We study the electrical conductance G and the thermoelec- tric response of a series of molecules featuring a quinoid core using…

Mesoscale and Nanoscale Physics · Physics 2015-07-02 M. Strange , J. S. Seldenthuis , C. J. O. Verzijl , J. M. Thijssen , G. C. Solomon

This overview will give a glimpse into chemical design principles for exploiting quantum interference (QI) effects in molecular-scale devices. Direct observation of room temperature QI in single-molecule junctions has stimulated growing…

Mesoscale and Nanoscale Physics · Physics 2017-12-19 Colin J. Lambert , Shi-Xia Liu

We study the charge transport properties of triangular quantum dot molecule (TQDM) connected to metallic electrodes, taking into account all correlation functions and relevant charging states. The quantum interference (QI) effect of TQDM…

Mesoscale and Nanoscale Physics · Physics 2015-02-24 Chih-Chieh Chen , Yia-chung Chang , David M T Kuo

Quantum interference in coherent transport through single molecular rings may provide a mechanism to control current in molecular electronics. We investigate its applicability by using a single-particle Green function method combined with…

Mesoscale and Nanoscale Physics · Physics 2009-08-11 San-Huang Ke , Weitao Yang , Harold U. Baranger

Quantum interference (QI) in molecular transport junctions can lead to dramatic reductions of the electron transmission at certain energies. In a recent work [Markussen et al., Nano Lett. 2010, 10, 4260] we showed how the presence of such…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 Troels Markussen , Robert Stadler , Kristian S. Thygesen

This tutorial outlines the basic theoretical concepts and tools which underpin the fundamentals of phase-coherent electron transport through single molecules. The key quantity of interest is the transmission coefficient T(E), which yields…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 C J Lambert

We give a detailed discussion of the Quantum Interference Effect Transistor (QuIET), a proposed device which exploits interference between electron paths through aromatic molecules to modulate current flow. In the off state, perfect…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Charles A. Stafford , David M. Cardamone , Sumit Mazumdar

Destructive quantum interference (QI) has been a source of interest as a new paradigm for molecular electronics as the electronic conductance is widely dependent on the occurrence or absence of destructive QI effects. In order to interpret…

Mesoscale and Nanoscale Physics · Physics 2022-09-23 O. Sengul , A. Valli , R. Stadler

Destructive quantum interference in single molecule electronics is an intriguing phe- nomenon; however, distinguishing quantum interference effects from generically low transmission is not trivial. In this paper, we discuss how quantum…

Mesoscale and Nanoscale Physics · Physics 2014-10-01 Jacob Lykkebo , Alessio Gagliardi , Alessandro Pecchia , Gemma C. Solomon

Quantum interference (QI) can strongly enhance thermoelectric response, with higher-order "supernodes" predicted to yield scalable gains in thermopower and efficiency. A central question, however, is whether such features are intrinsically…

Mesoscale and Nanoscale Physics · Physics 2025-10-09 Justin P. Bergfield

Quantum interference can profoundly affect charge transport in single molecules, but experiments can usually measure only the conductance at the Fermi energy. Because in general the most pronounced features of the quantum interference are…

The quantum interference and orbital filling effects on the thermoelectric (TE) properties of quantum dot molecules with high figure of merit are illustrated via the full solution to the Hubbard- Anderson model in the Coulomb blockade…

Mesoscale and Nanoscale Physics · Physics 2015-07-02 Chih-Chieh Chen , David M T Kuo , Yia Chung Chang

We present a general framework for quantum interference (QI) between multiple, fundamentally different processes. Our framework reveals the importance of shaped input wavefunctions in enabling QI, and predicts unprecedented interactions…

Quantum Physics · Physics 2023-10-10 J. Lim , Y. S. Ang , L. K. Ang , L. J. Wong

The realization of self-assembled molecular-electronic films, whose room-temperature transport properties are controlled by quantum interference (QI), is an essential step in the scale-up QI effects from single molecules to parallel arrays…

If simple guidelines could be established for understanding how quantum interference (QI) can be exploited to control the flow of electricity through single molecules, then new functional molecules, which exploit room-temperature QI could…

Mesoscale and Nanoscale Physics · Physics 2019-03-11 Lara Ulčakar , Tomaž Rejec , Jure Kokalj , Sara Sangtarash , Hatef Sadeghi , Anton Ramšak , John H. Jefferson , Colin J. Lambert

Molecular transistors have the potential for switching with lower gate voltages than conventional field-effect transistors. We have calculated the performance of a single-molecule device in which there is interference between electron…

Mesoscale and Nanoscale Physics · Physics 2016-07-28 Ying Li , Jan Mol , Simon Benjamin , Andrew Briggs

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

Destructive quantum interference (DQI) in single molecule electronics is a purely quantum mechanical effect and entirely defined by inherent properties of the molecule in the junction such as its structure and symmetry. This definition of…

Mesoscale and Nanoscale Physics · Physics 2017-01-04 Xin Zhao , Victor Geskin , Robert Stadler

Interference represents one of the most striking manifestation of quantum physics in low-dimensional systems. Despite evidences of quantum interference in charge transport have been known for a long time, only recently signatures of…

Mesoscale and Nanoscale Physics · Physics 2015-09-16 Luca Vannucci , Flavio Ronetti , Giacomo Dolcetto , Matteo Carrega , Maura Sassetti

As the dimensions of a conductor approach the nano-scale, quantum effects will begin to dominate its behavior. This entails the exciting possibility of controlling the conductance of a device by direct manipulation of the electron wave…

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