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After the efficiency of organic photovoltaic (OPV) cells achieved more than 10%, the control of stability and degradation mechanisms of solar cells became a prominent task. The improvement of device efficiency due to incorporation of a…

Irreproducibility is a serious issue in thin film organic photovoltaic (OPV) devices, as smallest local inhomogeneities can change the entire behaviour of identically built devices without showing obvious failure. Inhomogeneities can occur…

A detailed investigation of the functionality of inverted organic photovoltaics (OPVs) using bare Ag contacts as top electrode is presented. The inverted OPVs without hole transporting layer (HTL) exhibit a significant gain in hole carrier…

Materials Science · Physics 2016-11-01 Achilleas Savva , Ignasi Burgues-Ceballos , Giannis Papazoglou , Stelios A. Choulis

The great progress in organic photovoltaics (OPV) over the past few years has been largely achieved by the development of non-fullerene acceptors (NFAs), with power conversion efficiencies now approaching 20%. To further improve device…

High power conversion efficiency (PCE) inverted organic photovoltaics (OPVs) usually use thermally evaporated MoO3 as a hole transporting layer (HTL). Despite the high PCE values reported, stability investigations are still limited and the…

The charge accumulation properties of p-i-n perovskite solar cells were investigated using three representative organic and inorganic hole transporting layer (HTLs): a) Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS, Al…

Applied Physics · Physics 2018-07-20 Fedros Galatopoulos , Achilleas Savva , Ioannis T. Papadas , Stelios A. Choulis

Polymer based organic photovoltaic (OPV) technology offers a relatively inexpensive option for solar energy conversion provided its efficiency increases beyond the current level (6-7%) along with significant improvements in operational…

Materials Science · Physics 2015-03-17 Biswajit Ray , Pradeep R. Nair , Muhammad A. Alam

Here, we focus on induced degradation and spatial inhomogeneity of organic photovoltaic devices under different environmental conditions, uncoupled from the influence of a hole-transport (HT) layer. During testing of devices comprising the…

Applied Physics · Physics 2018-08-21 Huei-Ting Chien , Peter W. Zach , Bettina Friedel

Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is widely used to build optoelectronic devices. However, as a hygroscopic water-based acidic material, it brings major concerns for stability and degradation, resulting in…

Non-fullerene acceptors based on perylenediimides (PDIs) have garnered significant interest as an alternative to fullerene acceptors in organic photovoltaics (OPVs), but their charge transport phenomena are not well understood, especially…

Inclusion of heavy metal atoms in a polymer backbone allows transitions between the singlet and triplet manifolds. Interfacial dissociation of triplet excitons constitutes a viable mechanism for enhancing photovoltaic (PV) efficiencies in…

Materials Science · Physics 2009-08-10 K. Yang , U. Scherf , S. Guha

We investigated the influence of oxygen on the performance of P3HT:PCBM (poly(3-hexylthiophene):[6,6]-phenyl C61 butyric acid methyl ester) solar cells by current--voltage, thermally stimulated current (TSC) and charge extraction by…

We demonstrate enhanced light extraction for monochrome top-emitting organic light-emitting diodes (OLEDs). The enhancement by a factor of 1.2 compared to a reference sample is caused by the use of a hole transport layer (HTL) material…

In perovskite solar cells, photovoltaic action is created by charge transport layers (CTLs) either side of the light-absorbing metal halide perovskite semiconductor. Hence, the rates for desirable charge extraction and unwanted interfacial…

SCAPS 1-D was used for the simulation of lead-free environmentally benign methylammonium tin-iodide (CH3NH3SnI3) based solar cell. Indium sulphide (In2S3) was utilized as the electron transport layer (ETL) for its high carrier mobility and…

Materials Science · Physics 2020-12-17 Intekhab Alam , Md Ali Ashraf

Hybrid conjugated polymer/fullerene filaments based on MEH-PPV/PVP/PCBM are prepared by electrospinning, and their properties assessed by scanning electron, atomic and lateral force, tunnelling, and confocal microscopy, as well as by…

Photodiodes are widely used to convert lights into electrical signals. The conventional silicon (Si) based photodiodes boast high photoelectric conversion efficiency and detectivity. However, in general, inorganic-based photodiodes have low…

Instrumentation and Detectors · Physics 2016-09-21 Seong Bin Lim , Chan Hyuk Ji , Ki Tae Kim , Se Young Oh

This study delves into the effects of doping Spiro-OMeTAD, a widely employed hole transport material (HTM) in perovskite solar cells, with three distinct impurities: lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI), FK209, and…

Materials Science · Physics 2024-12-31 Mehran Hosseinzadeh Dizaj

In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

The internal quantum efficiency (IQE) of an organic photovoltaic device (OPV) is proportional to the number of free charge carriers generated and their conductivity, per absorbed photon. However, both the IQE and the quantities that…

Mesoscale and Nanoscale Physics · Physics 2016-06-15 Livia Noëmi Glanzmann , Duncan John Mowbray
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