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A recent modification of the Perdew-Zunger self-interaction-correction (SIC) to the density-functional formalism (Pederson, Ruzsinszky, Perdew) has provided a framework for explicitly restoring unitary invariance to the expression for the…

Chemical Physics · Physics 2015-06-23 Mark R. Pederson

The Hartree-Fock approximation of Quantum Electrodynamics provides a rigorous framework for the description of relativistic electrons in external fields. This nonlinear model takes into account the infinitely many virtual electrons of…

Mathematical Physics · Physics 2012-11-21 Julien Sabin

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

The main objective of this paper is to propose an alternative procedure to carry out one of the key steps of immersion and invariance stabilising controller design. Namely, the one that ensures attractivity of the manifold whose internal…

Systems and Control · Computer Science 2016-11-18 Lei Wang , Fulvio Forni , Romeo Ortega , Hongye Su

We present the quantum-selected configuration interaction-tailored coupled-cluster (QSCI-TCC) method, a hybrid quantum-classical scheme that tailors coupled-cluster (CC) theory with a quantum-selected configuration interaction (QSCI) wave…

Chemical Physics · Physics 2025-06-23 Luca Erhart , Yuichiro Yoshida , Wataru Mizukami

Most nonrelativistic electron correlation methods can be adapted to account for relativistic effects, as long as the relativistic molecular spinor integrals are available, from either a four-, two-, or one-component mean-field calculation.…

Strongly Correlated Electrons · Physics 2024-07-17 Zijun Zhao , Francesco A. Evangelista

The effect of external electric field on electron-hole correlation in GaAs quantum dots is investigated. The electron-hole Schrodinger equation in the presence of external electric field is solved using explicitly correlated full…

Chemical Physics · Physics 2013-02-06 Christopher J. Blanton , Christopher Brenon , Arindam Chakraborty

We investigate the electrostatic interactions between two charged anisotropic conductors using a combination of asymptotic and numerical methods. For widely separated particles, we employ the method of reflections to analyze the…

Soft Condensed Matter · Physics 2025-01-13 Harshit Joshi , Anubhab Roy

We derive from a microscopic Hamiltonian a set of stochastic equations of motion for a system of spinless charged particles in an electromagnetic (EM) field based on a consistent application of a dimensionful 1/c expansion of quantum…

Quantum Physics · Physics 2012-06-05 C. H. Fleming , P. R. Johnson , B. L. Hu

In this article, we consider fixed spin-1/2 particles interacting through the quantized electromagnetic field in a constant magnetic field. We give approximate evolutions of coherent states. This uses spins-photon classical Hamiltonian…

Analysis of PDEs · Mathematics 2015-12-29 L. Amour , J. Nourrigat

In this work we include electron-electron interaction beyond Hartree-Fock level in our non-equilibrium Green's function approach by a crude form of GW through the Single Plasmon Pole Approximation. This is achieved by treating all…

Mesoscale and Nanoscale Physics · Physics 2016-05-02 David O. Winge , Martin Franckié , Claudio Verdozzi , Andreas Wacker , Mauro F. Pereira

We discuss the analytic and diagrammatic structure of ionization potential (IP) and electron affinity (EA) equation-of-motion coupled-cluster (EOM-CC) theory, in order to put it on equal footing with the prevalent $GW$ approximation. The…

Chemical Physics · Physics 2019-04-16 Malte F. Lange , Timothy C. Berkelbach

A relativistic version of the coupled-cluster single-double (CCSD) method is developed for atoms with a single valence electron. In earlier work, a linearized version of the CCSD method (with extensions to include a dominant class of triple…

Atomic Physics · Physics 2009-11-13 Rupsi Pal , M. S. Safronova , W. R. Johnson , Andrei Derevianko , Sergey G. Porsev

The single-centre convergent close-coupling approach to ion-atom collisions has been extended to model collisions involving arbitrary multi-electron atoms and partially stripped ions. This is accomplished by generating a set of target…

Atomic Physics · Physics 2026-05-12 N. W. Antonio , A. S. Kadyrov

In a previous paper we proposed a Projected Configuration Interaction method that uses sets of axially deformed single particle states to build up the many body basis. We show that the choice of the basis set is essential for the efficiency…

Nuclear Theory · Physics 2013-05-29 Zao-Chun Gao , Mihai Horoi , Y. S. Chen

For a system of spinless fermions in a disordered mesoscopic ring, interactions can give rise to an enhancement of the persistent current by orders of magnitude. The increase in the current is associated with a charge reorganization of the…

Strongly Correlated Electrons · Physics 2009-10-31 A. Kambili , C. J. Lambert , J. H. Jefferson

The $GW$ method for calculating quasi-particle energies of solids commonly begin from a DFT Hamiltonian and Kohn-Sham orbitals in a plane wave basis. Screening of the coulomb interaction is implemented using the inverse dielectric function…

Materials Science · Physics 2026-05-20 Charles H. Patterson

Here is presented an original program based on molecular Schrodinger equations. It is dedicated to target specific states of infrared vibrational spectrum in a very precise way with a minimal usage of memory. An eigensolver combined with a…

Computational Physics · Physics 2018-07-26 Romain Garnier

We find that for simple metal clusters a single-electron description of the ground state employing self-interaction correction (SIC) in the framework of local-density approximation strongly contaminates the high energy photoionization cross…

Atomic and Molecular Clusters · Physics 2009-11-07 M. E. Madjet , Himadri S. Chakraborty , Jan-M. Rost

Many chemical systems cannot be described by quantum chemistry methods based on a singlereference wave function. Accurate predictions of energetic and spectroscopic properties require a delicate balance between describing the most important…

Chemical Physics · Physics 2018-06-12 Erik Donovan Hedegård , Julien Toulouse , Hans Jørgen Aagaard Jensen
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