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In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids (RTILs) on charged electrodes since the publication of Kornyshev's seminal paper in 2007. We pay…

Soft Condensed Matter · Physics 2021-12-28 Yury A. Budkov , Andrei L. Kolesnikov

We consider the liquid-vapor type phase transition for fluids confined within spatially periodic external fields. For a fluid in d=3 dimensions, the periodic field induces an additional phase, characterized by large density modulations…

Statistical Mechanics · Physics 2015-03-19 Richard L. C. Vink , A. J. Archer

We present a phase-field model based on the Cahn-Hilliard equation to investigate the properties of phase separation in DNA nanostar systems. Leveraging a realistic free-energy functional derived from Wertheim theory, our model captures the…

Soft Condensed Matter · Physics 2025-04-23 Marco Cappa , Francesco Sciortino , Lorenzo Rovigatti

A diffuse-interface model for microstructure with an arbitrary number of components and phases was developed from basic thermodynamic and kinetic principles and formalized within a variational framework. The model includes a composition…

Materials Science · Physics 2011-07-28 Daniel A. Cogswell , W. Craig Carter

Phase separation can drive spatial organization of multicomponent mixtures. For instance in developing animal embryos, effective phase separation descriptions have been used to account for the spatial organization of different tissue types.…

Soft Condensed Matter · Physics 2023-01-18 Simon Gsell , Matthias Merkel

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

Current research presents an innovative model of half-space plasmon excitations for electron gas of arbitrary degeneracy in an ambient jellium-like positive background . The linearized Schr\"{o}dinger-Poisson system is used to derive…

Plasma Physics · Physics 2021-01-15 M. Akbari-Moghanjoughi

A class of variational schemes for the hydrodynamic-electrodynamic model of lossless free-electron gas in a quasineutral background is developed for high-quality simulations of surface plasmon polaritons. The Lagrangian density of lossless…

Computational Physics · Physics 2019-02-27 Qiang Chen , Lifei Geng , Xiang Chen , Xiaojun Hao , Chuanchuan Wang , Xiaoyang Wang

An existence result is proved for a nonlinear diffusion problem of phase-field type, consisting of a parabolic system of two partial differential equations, complemented by Neumann homogeneous boundary conditions and initial conditions.…

Analysis of PDEs · Mathematics 2012-02-24 Pierluigi Colli , Gianni Gilardi , Paolo Podio-Guidugli , Jürgen Sprekels

Phase-field models are a popular choice in computational physics to describe complex dynamics of substances with multiple phases and are widely used in various applications. We present nonlocal non-isothermal phase-field models of…

Analysis of PDEs · Mathematics 2023-10-13 Olena Burkovska

Most of our current understanding of phase separation is based on ideas that disregard correlaions. Here we illuminate unexpected effects of correlations on the structure and thermodynamics of interfaces and in turn phase separation, which…

Statistical Mechanics · Physics 2024-03-15 Kristian Blom , Noah Ziethen , David Zwicker , Aljaž Godec

Electrical double layer (EDL) is formed when an electrode is in contact with an electrolyte solution, and is widely used in biophysics, electrochemistry, polymer solution and energy storage. Poisson-Boltzmann (PB) coupled equations provides…

Mesoscale and Nanoscale Physics · Physics 2022-03-02 Cherq Chua , Chun Yun Kee , L. K. Ang , Yee Sin Ang

Electrostatic correlations and variable permittivity of electrolytes are essential for exploring many chemical and physical properties of interfaces in aqueous solutions. We propose a continuum electrostatic model for the treatment of these…

Soft Condensed Matter · Physics 2015-06-23 Manman Ma , Zhenli Xu

Ionic polymer-metal composites consist in a thin film of electro-active polymers (Nafion R for example) sandwiched between two metallic electrodes. They can be used as sensors or actuators. The polymer is saturated with water, which causes…

Computational Physics · Physics 2021-01-18 Mireille Tixier , Joël Pouget

Colloid-polymer mixtures are an archetype for modeling phase transition processes, as they a exhibit low-density gas phase, high-density crystalline phase and an intervening liquid phase. While their equilibrium behavior has been studied…

Soft Condensed Matter · Physics 2024-12-18 Lauren Barnes , Boris Khusid , Lou Kondic , William V. Meyer , Anand U. Oza

Mixtures of nematic liquid crystals and isotropic fluids display a diverse range of phase behaviors, arising from the coupling between orientational order and concentration fluctuations. In this review, we introduce a simplified…

Soft Condensed Matter · Physics 2026-04-13 Margarida M. Telo da Gama , Rodrigo C. V. Coelho

We consider phase-field models with and without lateral flow for the numerical simulation of lateral phase separation and coarsening in lipid membranes. For the numerical solution of these models, we apply an unfitted finite element method…

Numerical Analysis · Mathematics 2023-06-02 Maxim Olshanskii , Yerbol Palzhanov , Annalisa Quaini

We have developed a molecular mean-field theory -- fourth-order Poisson-Nernst-Planck-Bikerman theory -- for modeling ionic and water flows in biological ion channels by treating ions and water molecules of any volume and shape with…

Soft Condensed Matter · Physics 2020-05-18 Jinn-Liang Liu , Bob Eisenberg

In this paper we study a model for phase separation and damage in thermoviscoelastic materials. The main novelty of the paper consists in the fact that, in contrast with previous works in the literature (cf., e.g., [C. Heinemann, C. Kraus:…

Analysis of PDEs · Mathematics 2015-10-14 C. Heinemann , C. Kraus , E. Rocca , R. Rossi

Phase separation and coarsening is a phenomenon commonly seen in binary physical and chemical systems that occur in nature. Often times, thermal fluctuations, modeled as stochastic noise, are present in the system and the phase segregation…

Soft Condensed Matter · Physics 2017-04-19 Prerna Gera , David Salac