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The phase diagram of ice Ih, II, and III is studied by a quasi-harmonic approximation. The results of this approach are compared to phase diagrams previously derived by thermodynamic integration using path integral and classical…

Chemical Physics · Physics 2012-10-16 R. Ramirez , N. Neuerburg , C. P. Herrero

We perform molecular dynamics simulations of 512 water-like molecules that interact via the TIP5P potential and are confined between two smooth hydrophobic plates that are separated by 1.10 nm. We find that the anomalous thermodynamic…

Soft Condensed Matter · Physics 2009-11-11 Pradeep Kumar , Sergey V. Buldyrev , Francis W. Starr , Nicolas Giovambattista , H. Eugene Stanley

Experiments and computer simulations have shown that the melt-ing temperature of solid hydrogen drops with pressure above about 65 GPa, suggesting that a liquid state might exist at low temperatures. It has also been suggested that this low…

We present the results of classical molecular dynamics simulations to assess the relative contributions to interfacial thermal conductance from inelastic phonon processes at the interface and in the adjacent bulk materials. The simulated…

A structural transformation in water upon compression was recently observed at the temperature $T=277$~K in the vicinity of the pressure $p \approx 2\;000$~Atm [R.M. Khusnutdinoff, A.V. Mokshin, J. Non-Cryst. Solids \textbf{357}, 1677…

Disordered Systems and Neural Networks · Physics 2015-06-03 Ramil M. Khusnutdinoff , Anatolii V. Mokshin

We present molecular dynamics simulations of the SPC/E model of water to probe the dynamic properties at temperatures from 350 K down to 190 K and pressures from 2.5GPa (25kbar) down to -300MPa (-3kbar). We compare our results with those…

Condensed Matter · Physics 2009-10-31 Francis W. Starr , Francesco Sciortino , H. Eugene Stanley

Using the non-empirical Variational Induced Breathing (VIB) model, the thermal properties of periclase (MgO) under high pressures and temperatures are investigated using molecular dynamics, which includes all anharmonic effects. Equations…

mtrl-th · Physics 2015-06-26 Iris Inbar , R. E. Cohen

Most experimentally known high-pressure ice phases have a body-centred cubic (bcc) oxygen lattice. Our atomistic simulations show that, amongst these bcc ice phases, ices VII, VII' and X are the same thermodynamic phase under different…

The effect of thermophoresis on the impaction of particles on a cylinder is investigated for different particle sizes, particle conductivities, temperature gradients and for Reynolds numbers between 100 and 1600. Simulations are performed…

Including quantum mechanical effects on the dynamics of nuclei in the condensed phase is challenging, because the complexity of exact methods grows exponentially with the number of quantum degrees of freedom. Efforts to circumvent these…

Chemical Physics · Physics 2015-06-23 Mariana Rossi , Hanchao Liu , Francesco Paesani , Joel Bowman , Michele Ceriotti

We report results of molecular dynamics simulations of amorphous ice for pressures up to 22.5 kbar. The high-density amorphous ice (HDA) as prepared by pressure-induced amorphization of Ih ice at T=80 K is annealed to T=170 K at various…

Statistical Mechanics · Physics 2009-11-11 R. Martonak , D. Donadio , M. Parrinello

We present results from Molecular Dynamics simulations of the thermal glass transition in a dense polymer melt. In previous work we compared the simulation data with the idealized version of mode coupling theory (MCT) and found that the…

Soft Condensed Matter · Physics 2009-10-31 Christoph Bennemann , Wolfgang Paul , J"org Baschnagel , Kurt Binder

We performed simulations for solid molecular hydrogen at high pressures (250GPa$\leq$P$\leq$500GPa) along two isotherms at T=200 K (phases III and VI) and at T=414 K (phase IV). At T=200K we considered likely candidates for phase III, the…

Materials Science · Physics 2017-11-22 Giovanni Rillo , Miguel A. Morales , David M. Ceperley , Carlo Pierleoni

High-performance fusion plasmas, requiring high pressure $\beta$, are not well-understood in stellarator-type experiments. Here, the effect of $\beta$ on ion-temperature-gradient-driven (ITG) turbulence is studied in Wendelstein 7-X (W7-X),…

Possible variations in the dynamical behaviour of LiYF$_{4}$ due to its several structural changes under pressure are examined by making use of the complementary techniques of quasi-harmonic lattice dynamics and molecular dynamics…

Materials Science · Physics 2007-05-23 A. Sen , S. L. Chaplot , R. Mittal

Thermophysical properties of hydrogen, helium, and hydrogen-helium mixtures have been investigated in the warm dense matter regime at electron number densities ranging from $6.02\times10^{29}\sim2.41\times10^{30}$/m$^{3}$ and temperatures…

Materials Science · Physics 2015-06-16 Cong Wang , Xian-Tu He , Ping Zhang

The temperature dependence of the solid-liquid interfacial free energy, {\gamma}, is investigated for Al and Ni at the undercooled temperature regime based on a recently developed persistent-embryo method. The atomistic description of the…

Chemical Physics · Physics 2018-11-06 Yang Sun , Feng Zhang , Huajing Song , Mikhail I. Mendelev , Cai-Zhuang Wang , Kai-Ming Ho

Path-integral molecular dynamics (PIMD) simulations are crucial for accurately capturing nuclear quantum effects in materials. However, their computational intensity and reliance on multiple software packages often limit their applicability…

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

Materials Science · Physics 2015-10-20 Tian Lan

Rare-gas solids (Ne, Ar, Kr, and Xe) under hydrostatic pressure up to 30 kbar have been studied by path-integral Monte Carlo simulations in the isothermal-isobaric ensemble. Results of these simulations have been compared with available…

Materials Science · Physics 2009-11-11 Carlos P. Herrero , Rafael Ramirez