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We analyze the structure of the Fundamental Measure Theory for the free energy density functional of hard sphere mixtures. A comparative study of the different versions of the theory, and other density functional approaches, is done in…

Soft Condensed Matter · Physics 2009-11-07 Jose A. Cuesta , Yuri Martinez-Raton , Pedro Tarazona

It is shown that the DFT exchange and correlation functionals satisfy an expression that couples exchange and correlation functionals and functional derivatives evaluated at three different densities and for two particle numbers. This…

Materials Science · Physics 2015-05-30 Daniel P. Joubert

A versatile semiclassical approximation for intense laser-atom processes is presented. This uniform approximation is no more complicated than the frequently-used multi-dimensional saddle-point approximation and far superior, since it…

Atomic Physics · Physics 2016-09-08 C. Figueira de Morisson Faria , H. Schomerus , W. Becker

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

A new method that accurately describes strongly correlated states and captures dynamical correlation is presented. It is derived as a modification of coupled-cluster theory with single and double excitations (CCSD) through consideration of…

Chemical Physics · Physics 2013-07-15 Daniel Kats , Frederick R. Manby

The Debye-Huckel (DH) formalism of bulk electrolytes equivalent to the gaussian-level closure of the electrostatic Schwinger-Dyson identities without the interionic hard-core (HC) coupling is extended via the cumulant treatment of these…

Soft Condensed Matter · Physics 2024-04-11 Sahin Buyukdagli

In recent years it has been shown for hard sphere gas that, by retaining the correlation information, dynamical fluctuation and large deviation of empirical measure around Boltzmann equation could be proved, in addition to the classical…

Analysis of PDEs · Mathematics 2024-09-05 Chenjiayue Qi

We present a near-linear scaling formulation of the explicitly-correlated coupled-cluster singles and doubles with perturbative triples method (CCSD(T)$_{\overline{\text{F12}}}$) for high-spin states of open-shell species. The approach is…

Chemical Physics · Physics 2024-07-30 Ashutosh Kumar , Frank Neese , Edward F. Valeev

Standard approximations for the exchange-correlation (XC) functional in Kohn-Sham density functional theory (KS-DFT) typically lead to unacceptably large errors when applied to strongly-correlated electronic systems. Partition-DFT (PDFT) is…

Chemical Physics · Physics 2023-09-12 Yi Shi , Yuming Shi , Adam Wasserman

The electronic and magnetic properties of many strongly-correlated systems are controlled by a limited number of states, located near the Fermi level and well isolated from the rest of the spectrum. This opens a formal way for combining the…

Strongly Correlated Electrons · Physics 2010-07-15 I. V. Solovyev

Explicit solutions of differential equations of complex fractional orders with respect to functions and with continuous variable coefficients are established. The representations of solutions are given in terms of some convergent infinite…

Classical Analysis and ODEs · Mathematics 2021-03-15 Joel E. Restrepo , Michael Ruzhansky , Durvudkhan Suragan

Dynamical Mean-Field Theory (DMFT) has opened new perspectives for the investigation of strongly correlated electron systems and greatly improved our understanding of correlation effects in models and materials. In contrast to…

Strongly Correlated Electrons · Physics 2020-07-16 Dieter Vollhardt

A diagrammatic kinetic theory of density fluctuations in simple dense liquids at long times, described in the preceding paper, is applied to a high density Lennard-Jones liquid to calculate various equilibrium time correlation functions.…

Statistical Mechanics · Physics 2015-06-18 Kevin R. Pilkiewicz , Hans C. Andersen

Extending density functional theory (DFT) to an {\it ab initio} orbital functional theory (OFT) requires new methodology for nonlocal exchange and correlation potentials. This paper describes such modifications to a standard Dirac-Slater…

Condensed Matter · Physics 2007-05-23 R. K. Nesbet

The Gr\"uneisen parameter is evaluated for three-dimensional Yukawa systems in the strongly coupled regime. Simple analytical expression is derived from the thermodynamic consideration and its structure is analysed in detail. Possible…

Plasma Physics · Physics 2017-04-28 Sergey Khrapak

This work is dedicated to the quantization of the light-front Yukawa model in D=1+3 dimensions with higher order derivatives of the scalar field. The problem of the computing Dirac brackets and the (anti-) commutator algebra of interacting…

High Energy Physics - Theory · Physics 2022-07-29 Jan Żochowski

Canonical correlation analysis is a statistical technique that is used to find relations between two sets of variables. An important extension in pattern analysis is to consider more than two sets of variables. This problem can be expressed…

Machine Learning · Computer Science 2013-02-06 Jan Rupnik , Primoz Skraba , John Shawe-Taylor , Sabrina Guettes

In order to give a basis for the structure and correlation analysis of fine particle (dusty) plasma and colloidal suspensions, thermodynamic treatment of mixtures of macroscopic and microscopic charged particles within the adiabatic…

Plasma Physics · Physics 2015-06-11 Hiroo Totsuji

We demonstrate the importance of electron correlation effects in the hyperfine structure constants of many low-lying states in $^{210}$Fr and $^{212}$Fr. This is achieved by calculating the magnetic dipole and electric quadrupole hyperfine…

Atomic Physics · Physics 2015-05-20 B. K. Sahoo , D. K. Nandy , B. P. Das , Y. Sakemi

Using twisted Fock spaces, we formulate and study two twisted versions of the n-point correlation functions of Bloch-Okounkov, and then identify them with q-expectation values of certain functions on the set of (odd) strict partitions. We…

Quantum Algebra · Mathematics 2007-05-23 Weiqiang Wang