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We present a simple and efficient approximation to the electron-phonon scattering rate suitable for high-throughput screening of candidate materials for thermoelectric devices, based on electronic transport. The method is applied to…

Materials Science · Physics 2015-11-30 Georgy Samsonidze , Boris Kozinsky

Thermoelectrics are a promising class of materials for renewable energy owing to their capability to generate electricity from waste heat, with their performance being governed by a competition between charge and thermal transport. A…

The predictive performance screening of novel compounds can significantly promote the discovery of efficient, cheap, and non-toxic thermoelectric materials. Large efforts to implement machine-learning techniques coupled to materials…

Applied Physics · Physics 2020-12-07 Patrizio Graziosi , Chathurangi Kumarasinghe , Neophytos Neophytou

This article reviews the theory of electron-phonon interactions in solids from the point of view of ab-initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive non-empirical calculations…

Materials Science · Physics 2017-03-08 Feliciano Giustino

First-principles prediction of thermal conductivity and radiative properties is crucial. However, computing phonon scattering, especially for four-phonon scattering, could be prohibitively expensive, and the thermal conductivity even for…

Materials Science · Physics 2023-11-23 Ziqi Guo , Zherui Han , Dudong Feng , Guang Lin , Xiulin Ruan

Electronic and phononic thermal conductivity are involved in the thermal conduction for metals and Wiedemann-Franz law is usually employed to predict them separately. However, Wiedemann-Franz law is shown to be invalid at intermediate…

Applied Physics · Physics 2020-11-18 Shouhang Li , Zhen Tong , Xinyu Zhang , Hua Bao

The bottleneck in modern thermoelectric power generation and cooling is the low energy conversion efficiency of thermoelectric materials. The detrimental effects of lattice phonons on performance can be mitigated, but achieving a high…

First-principles calculations combining density functional theory and many-body perturbation theory can provide microscopic insight into the dynamics of electrons and phonons in materials. We review this theoretical and computational…

Materials Science · Physics 2016-11-23 Marco Bernardi

A first-principles informed approach to the calculation of Lorenz numbers for complex thermoelectric materials is presented and discussed. Example calculations illustrate the importance of using accurate band structures and energy-dependent…

Materials Science · Physics 2018-03-14 Xufeng Wang , Vahid Askarpour , Jesse Maassen , Mark Lundstrom

The half-Heusler (hH) compounds are currently considered promising thermoelectric (TE) materials due to their favorable thermopower and electrical conductivity. Accurate estimates of these properties are therefore highly desirable and…

Materials Science · Physics 2026-04-07 Vinod Kumar Solet , Sudhir K. Pandey

We use first-principles electronic structure methods to calculate the electronic thermoelectric properties (i.e. due to electronic transport only) of single-crystalline bulk $n$-type silicon-germanium alloys vs Ge composition, temperature,…

Materials Science · Physics 2025-02-03 F. Murphy-Armando

Thermoelectric materials can achieve direct energy conversion between electricity and heat, thus can be applied to waste heat harvesting and solid-state cooling. The discovery of new thermoelectric materials is mainly based on experiments…

Materials Science · Physics 2024-05-07 Tao Fan , Artem R. Oganov

Over the last two decades a plethora of new thermoelectric materials, their alloys, and their nanostructures were synthesized. The ZT figure of merit, which quantifies the thermoelectric efficiency of these materials increased from values…

Materials Science · Physics 2023-07-27 Neophytos Neophytou , Pankaj Priyadarshi , Zhen Li , Patrizio Graziosi

The electronic transport behaviour of materials determines their suitability for technological applications. We develop an efficient method for calculating carrier scattering rates of solid-state semiconductors and insulators from first…

The electrical resistivity, thermoelectric power and electronic thermal conductivity of simple (isotropic) metals are studied in a uniform way. Starting from results of a variational solution of the Boltzmann equation, a generalized…

Materials Science · Physics 2009-11-07 M. Ausloos , K. Durczewski , J. Ulner

We have combined the Boltzmann transport equation with an {\it ab initio} approach to compute the thermoelectric coefficients of semiconductors. Electron-phonon, ionized impurity, and electron-plasmon scattering rates have been taken into…

Materials Science · Physics 2018-10-26 Z. Wang , S. Wang , S. Obukhov , N. Vast , J. Sjakste , V. Tyuterev , N. Mingo

We perform an ab initio computational investigation of the electronic and thermoelectric transport properties of one of the best performance half-Heusler (HH) alloys, NbFeSb. We use Boltzmann Transport equation while taking into account the…

Materials Science · Physics 2025-10-28 Bhawna Sahni , Yao Zhao , Zhen Li , Rajeev Dutt , Patrizio Graziosi , Neophytos Neophytou

The effective mass of charge carriers is a fundamental descriptor of the electronic structure of materials, and can be used to assess performance in electronics applications, or to screen for thermoelectrics and transparent conductors.…

Materials Science · Physics 2025-12-02 Szymon Błazucki , Junfeng Qiao , Nicola Marzari

To increase the performance of thermoelectric materials, the electronic parameters in the figure of merit must be improved. In this paper, we use full, numerical band structures and solve the Boltzmann equation in the relaxation time…

Materials Science · Physics 2018-12-17 Evan Witkoske , Xufeng Wang , Jesse Maassen , Mark Lundstrom

It is generally assumed in the thermoelectric community that the lattice thermal conductivity of a given material is independent of the electronic properties. This perspective is however questionable since the electron-phonon coupling could…

Materials Science · Physics 2018-01-03 D. D. Fan , H. J. Liu , L. Cheng , J. H. Liang , P. H. Jiang
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