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Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

We propose a computational method that simplifies drastically the inclusion of spin-orbit interaction in density functional theory implemented on localised atomic orbital basis sets. Our method is based on a well-known procedure for…

Materials Science · Physics 2009-11-11 Lucas Fernandez-Seivane , Miguel A. Oliveira , Stefano Sanvito , Jaime Ferrer

Multipole electron modes beyond the Mie plasmon in atomic clusters are investigated within the time-dependent local density approximation theory (TDLDA). We consider the origin of the modes, their connection with basic cluster properties…

Atomic and Molecular Clusters · Physics 2014-02-04 V. O. Nesterenko , P. -G. Reinhard , W. Kleinig

We extend the capabilities of correlation energy functionals based on the adiabatic-connection fluctuation-dissipation theorem by implementing the analytical atomic forces within the random phase approximation (RPA), in the context of plane…

Materials Science · Physics 2026-03-19 Damian Contant , Maria Hellgren

We propose a formalism to take account of the correction of the spatial fluctuations to the local self-energy obtained by the dynamical mean-field approximation. For this purpose, the approximate dynamical susceptibility in the framework of…

Strongly Correlated Electrons · Physics 2009-11-11 Hiroaki Kusunose

We propose a numerical method to simulate electrohydrodynamic phenomena in charged colloidal dispersions. This method enables us to compute the time evolutions of colloidal particles, ions, and host fluids simultaneously by solving Newton,…

Soft Condensed Matter · Physics 2007-05-23 Kang Kim , Yasuya Nakayama , Ryoichi Yamamoto

We present a comparative study of particle-hole and particle-particle channels of random-phase approximation (RPA) for molecular dissociations of different bonding types. We introduced a \textit{direct} particle-particle RPA scheme, in…

Materials Science · Physics 2019-06-05 Muhammad N. Tahir , Xinguo Ren

We report the successful adaptation of the quasi-boson approximation, a technique traditionally employed in nuclear physics, to the analysis of the two-dimensional electron gas. We show that the correlation energy estimated from this…

Strongly Correlated Electrons · Physics 2025-05-05 Tobias M. R. Wolf , Chunli Huang

The traditional way of estimating the gravitational field from observed motions of test objects is based on the virial relation between their kinetic and potential energy. We find a more efficient method. It is based on the natural…

Astrophysics · Physics 2009-11-10 Andrei M. Beloborodov , Yuri levin

A new wavefunction which improves the Gutzwiller-type local ansatz method has been proposed to describe the correlated electron system. The ground-state energy, double occupation number, momentum distribution function, and quasiparticle…

Strongly Correlated Electrons · Physics 2009-11-13 Y. Kakehashi , T. Shimabukuro , C. Yasuda

The paper discusses a variant of the local similarity theory, employing the second moment of vertical velocity and the "spectral" Prandtl mixing length as basic parameters. This approach allows expressing the turbulent exchange coefficient,…

Atmospheric and Oceanic Physics · Physics 2024-12-10 A. N. Vulfson , P. V. Nikolaev

We investigate the role of the electron correlation effects in the calculations of the electric dipole polarizabilities (\alpha) of elements belonging to three different groups of periodic table. To understand the propagation of the…

Atomic Physics · Physics 2014-05-21 Yashpal Singh , B. K. Sahoo

Binary mixtures of hard-spheres with different diameters and square-well attraction between different particles are studied by theory and Monte Carlo simulations. In our mesoscopic theory, local fluctuations of the volume fraction of the…

Soft Condensed Matter · Physics 2021-10-04 O. Patsahan , A. Meyra , A. Ciach

The performance of time-independent, orbital optimized calculations of excited states is assessed with respect to charge transfer excitations in organic molecules in comparison to the linear-response time-dependent density functional theory…

Chemical Physics · Physics 2024-05-22 Elli Selenius , Alec Elías Sigurdarson , Yorick L. A. Schmerwitz , Gianluca Levi

We derive analytical expressions for chemical potentials within the random phase approximation (RPA), equivalently the $GW$ energy functional evaluated using non interacting Green's functions ($G_s$). The chemical potential is obtained…

Chemical Physics · Physics 2026-03-20 Jiachen Li , Weitao Yang

A stochastic approach to time-dependent density functional theory (TDDFT) is developed for computing the absorption cross section and the random phase approximation (RPA) correlation energy. The core idea of the approach involves…

Chemical Physics · Physics 2016-11-04 Yi Gao , Daniel Neuhauser , Roi Baer , Eran Rabani

We construct the complementary short-range correlation relativistic local-density-approximation functional to be used in relativistic range-separated density-functional theory based on a Dirac-Coulomb Hamiltonian in the no-pair…

Chemical Physics · Physics 2021-05-26 Julien Paquier , Julien Toulouse

Spatially localized one-electron orbitals, orthogonal and nonorthogonal, are widely used in electronic structure theory to describe chemical bonding and speed up calculations. In order to avoid linear dependencies of localized orbitals, the…

Chemical Physics · Physics 2020-03-04 Ziling Luo , Rustam Z. Khaliullin

We demonstrate how to determine numerically nearly exact orthonormal orbitals that are optimal for evaluation of the energy of arbitrary (correlated) states of atoms and molecules by minimization of the energy Lagrangian. Orbitals are…

Compact objects evolving in an astrophysical environment experience a gravitational drag force known as dynamical friction. We present a multipole-frequency decomposition to evaluate the orbit-averaged energy and angular momentum…

Astrophysics of Galaxies · Physics 2025-09-22 Gali Eytan , Vincent Desjacques , Yonadav Barry Ginat