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Polymer electrolytes are intensely investigated for use as solid electrolytes in next generation lithium-ion and lithium-metal batteries. However, little is known about the structural and dynamical properties of polymer electrolytes close…

Soft Condensed Matter · Physics 2021-12-02 Andreas Thum , Diddo Diddens , Andreas Heuer

This paper investigates the problem of electrophoretic motion of a polyelectrolyte capsule with a porous arbitrary charged conducting shell in an electrolyte under the action of an external electric field. The corresponding boundary value…

Fluid Dynamics · Physics 2021-08-11 Anatoly N. Filippov , Daria Yu. Khanukaeva , Petr A. Aleksandrov

Elastic MicroPhase Separation (EMPS) provides a simple route to create soft materials with homogeneous microstructures by leveraging the supersaturation of crosslinked polymer networks with liquids. At low supersaturation, network…

Polarimeric maps have been used on the characterization of the magnetic field in molecular clouds. However, it is difficult to determine the 3-dimensional properties of these regions from the projected maps. In that case, numerical…

Astrophysics · Physics 2008-12-23 D. Falceta-Goncalves , A. Lazarian , G. Kowal

The helix is a ubiquitous motif for biopolymers. We propose a heuristic, entropically based model that predicts helix formation in a system of hard spheres and semiflexible tubes. We find that the entropy of the spheres is maximized when…

Soft Condensed Matter · Physics 2007-05-23 Yehuda Snir , Randall D. Kamien

We study a simple model of conducting polymers in which a single electron propagates through a randomly tangled chain. The model has the geometry of a small-world network, with a small density $p$ of crossings of the chain acting as…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jorge Quintanilla , Vivaldo L. Campo

We determine exactly the short-distance leading behavior of the density correlation functions of a two-dimensional two-component charge-symmetric Coulomb gas composed of point particles, in the whole regime of stability where the coulombic…

Statistical Mechanics · Physics 2007-05-23 Gabriel Tellez

Charged (nano)particles confined in electrodynamic traps can evolve into strongly correlated Coulomb systems which are the subject of current investigation. Exciting physical phenomena associated to Coulomb systems are reported such as…

Plasma Physics · Physics 2023-04-04 Bogdan M. Mihalcea , Vladimir Filinov , Roman Syrovatka , Leonid Vasilyak

We extend recent studies of the minimal energy packings of short flexible polymers with hard-core-like repulsions and short-range attractions to include bond-angle interactions with the aim of describing the collapsed conformations of…

Soft Condensed Matter · Physics 2015-06-11 Robert S. Hoy , Jared Harwayne-Gidansky , Corey S. O'Hern

We develop a method in which the electronic densities of small fragments determined by Kohn-Sham density functional theory (DFT) are embedded using stochastic DFT to form the exact density of the full system. The new method preserves the…

Chemical Physics · Physics 2015-06-19 Daniel Neuhauser , Roi Baer , Eran Rabani

We investigate the reliability of simulations of polyelectrolyte systems in aqueous environments, simulations that are performed using an efficient multi scale coarse grained polarizable pseudo-particle particle approach, denoted as pppl,…

Soft Condensed Matter · Physics 2024-01-01 Michel Masella , Fabien Léonforté

Accurate simulations of a condensed system of ions or polar molecules are concerned with proper handlings of the involved electrostatics. For such a Coulomb system at a charged planar interface, the Coulomb interaction averaged over the…

Chemical Physics · Physics 2024-07-29 Zhonghan Hu

Over the past decade or two, the concept has emerged of using multiple types of weak interactions simultaneously to enhance the mechanical properties of elastomers. These weak interactions include physical entanglements, hydrogen bonds,…

Soft Condensed Matter · Physics 2022-11-14 Zhongtong Wang , Hongyi Cai , Meredith N. Silberstein

In this paper we study the equilibrium shape of an interface that represents the lateral boundary of a pore channel embedded in an elastomer. The model consists of a system of PDEs, comprising a linear elasticity equation for displacements…

Optimization and Control · Mathematics 2014-05-29 Peter Berg , Sven-Joachim Kimmerle , Arian Novruzi

We consider an osmotic equilibrium between bulk solutions of polyelectrolyte bounded by semipermeable membranes and separated by a thin film of salt-free liquid. Although the membranes are neutral, the counter-ions of the polyelectrolyte…

Soft Condensed Matter · Physics 2012-01-19 Olga I. Vinogradova , Lyderic Bocquet , Artem N. Bogdanov , Roumen Tsekov , Vladimir Lobaskin

By considering a metal/polymer/metal structure within a tight-binding one-dimensional model, we have investigated the polaron formation in the presence of an electric field. When a sufficient voltage bias is applied to one of the metal…

Strongly Correlated Electrons · Physics 2009-11-10 C. Q. Wu , Y. Qiu , K. Nasu

We investigate the formation of polycrystalline structures in a class of particle systems. The atomistic energy is modeled as a sum of particle energies that favor atoms being locally isometric to a reference lattice. The discrete frame…

Mesoscale and Nanoscale Physics · Physics 2026-04-22 Leonard Kreutz , Timo Ziereis

A variational approach is considered to calculate the free energy and the conformational properties of a polyelectrolyte chain in $d$ dimensions. We consider in detail the case of pure Coulombic interactions between the monomers, when…

Soft Condensed Matter · Physics 2007-05-23 G. Migliorini , V. G. Rostiashvili , T. A. Vilgis

A polymer network can imbibe water, forming an aggregate called hydrogel, and undergo large and inhomogeneous deformation with external mechanical constraint. Due to the large deformation, nonlinearity plays a crucial role, which also…

Biological Physics · Physics 2011-03-04 Hui-Hui Dai , Zilong Song

The Poisson-Boltzmann equation for a strongly charged plate inside a generic charge-asymmetric electrolyte is solved using the method of asymptotic matching. Both near field and far field asymptotic behaviors of the potential are…

Soft Condensed Matter · Physics 2015-06-05 Ming Han , Xiangjun Xing