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The Cahn--Hilliard equation is one of the most common models to describe phase segregation processes in binary mixtures. In recent times, various dynamic boundary conditions have been introduced to model interactions of the materials with…

Analysis of PDEs · Mathematics 2021-10-12 Patrik Knopf , Andrea Signori

We study a diffusion model of phase field type, consisting of a system of two partial differential equations encoding the balances of microforces and microenergy; the two unknowns are the order parameter and the chemical potential. By a…

Analysis of PDEs · Mathematics 2011-03-24 Pierluigi Colli , Gianni Gilardi , Paolo Podio-Guidugli , Juergen Sprekels

The Cahn--Hilliard equation is a widely used model that describes amongst others phase separation processes of binary mixtures or two-phase flows. In the recent years, different types of boundary conditions for the Cahn--Hilliard equation…

Numerical Analysis · Mathematics 2021-03-04 Stefan Metzger

We consider a system which consists of a Cahn-Hilliard equation coupled with a Cahn-Hilliard-Oono equation in a bounded domain of $\mathbb{R}^d$, $d = 2, 3$. This system accounts for macrophase and microphase separation in a polymer mixture…

Analysis of PDEs · Mathematics 2022-03-25 Andrea Di Primio , Maurizio Grasselli

We consider a Cahn-Hilliard equation which is the conserved gradient flow of a nonlocal total free energy functional. This functional is characterized by a Helmholtz free energy density, which can be of logarithmic type. Moreover, the…

Analysis of PDEs · Mathematics 2013-11-15 Helmut Abels , Stefano Bosia , Maurizio Grasselli

In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis…

Materials Science · Physics 2016-02-03 Gyula I. Toth , Mojdeh Zarifi , Bjorn Kvamme

The Cahn--Hilliard equation is one of the most common models to describe phase separation processes of a mixture of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Analysis of PDEs · Mathematics 2021-04-27 Patrik Knopf , Kei Fong Lam , Chun Liu , Stefan Metzger

We propose a new class of phase field models coupled to viscoelasticity with large deformations, obtained from a diffuse interface mixture model composed by a phase with elastic properties and a liquid phase. The model is formulated in the…

Analysis of PDEs · Mathematics 2022-04-12 Abramo Agosti , Pierluigi Colli , Harald Garcke , Elisabetta Rocca

In this paper, we study the longtime asymptotic behavior of a phase separation process occurring in a three-dimensional domain containing a fluid flow of given velocity. This process is modeled by a viscous convective Cahn-Hilliard system,…

Analysis of PDEs · Mathematics 2018-03-13 Pierluigi Colli , Gianni Gilardi , Jürgen Sprekels

We derive a new effective macroscopic Cahn-Hilliard equation whose homogeneous free energy is represented by 4-th order polynomials, which form the frequently applied double-well potential. This upscaling is done for perforated/strongly…

Mathematical Physics · Physics 2013-10-02 Markus Schmuck , Marc Pradas , Greg A. Pavliotis , Serafim Kalliadasis

We consider a class of Cahn-Hilliard equation that models phase separation process of binary mixtures involving nontrivial boundary interactions in a bounded domain with non-permeable wall. The system is characterized by certain dynamic…

Analysis of PDEs · Mathematics 2023-07-28 Takeshi Fukao , Hao Wu

We study a phase-field variational model for the solvaiton of charged molecules with an implicit solvent. The solvation free-energy functional of all phase fields consists of the surface energy, solute excluded volume and solute-solvent van…

Analysis of PDEs · Mathematics 2022-11-01 Shibin Dai , Bo Li , Jianfeng Lu

The Cahn-Hilliard equation is the most common model to describe phase separation processes of a mixture of two components. For a better description of short-range interactions of the material with the solid wall, various dynamic boundary…

Analysis of PDEs · Mathematics 2020-10-20 Harald Garcke , Patrik Knopf

We prove existence and regularity for the solutions to a Cahn-Hilliard system describing the phenomenon of phase separation for a material contained in a bounded and regular domain. Since the first equation of the system is perturbed by the…

Analysis of PDEs · Mathematics 2020-05-05 Michele Colturato

An asymptotic analysis for a system with equation and dynamic boundary condition of Cahn-Hilliard type is carried out as the coefficient of the surface diffusion acting on the phase variable tends to 0, thus obtaining a forward-backward…

Analysis of PDEs · Mathematics 2021-06-03 Pierluigi Colli , Takeshi Fukao , Luca Scarpa

We investigate a new diffuse-interface model that describes creeping two-phase flows (i.e., flows exhibiting a low Reynolds number), especially flows that permeate a porous medium. The system of equations consists of a Brinkman equation for…

Analysis of PDEs · Mathematics 2025-09-15 Pierluigi Colli , Patrik Knopf , Giulio Schimperna , Andrea Signori

In this article we consider the numerical modeling and simulation via the phase field approach of two-phase flows of different densities and viscosities in superposed fluid and porous layers. The model consists of the…

Numerical Analysis · Mathematics 2021-12-09 Yali Gao , Daozhi Han , Xiaoming He , Ulrich Rüde

We propose finite-volume schemes for the Cahn-Hilliard equation which unconditionally and discretely preserve the boundedness of the phase field and the dissipation of the free energy. Our numerical framework is applicable to a variety of…

Numerical Analysis · Mathematics 2023-12-18 Rafael Bailo , José A. Carrillo , Serafim Kalliadasis , Sergio P. Perez

A common paradigm in phase-field models with singular potentials is that global-in-time weak solutions converge to a single equilibrium only after undergoing asymptotic regularization. However, in arXiv:2510.17296 we introduced a novel…

Analysis of PDEs · Mathematics 2026-04-01 Maurizio Grasselli , Andrea Poiatti

Phase field models frequently provide insight to phase transitions, and are robust numerical tools to solve free boundary problems corresponding to the motion of interfaces. A body of prior literature suggests that interface motion via…

Soft Condensed Matter · Physics 2015-09-30 Alpha A Lee , Andreas Münch , Endre Süli
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