Related papers: Interstellar Fullerene Compounds and Diffuse Inter…
The carbonaceous macromolecules imprinting in astronomical spectra the numerous absorptions called Diffuse Interstellar Bands (DIBs) are omnipresent in the Galaxy and beyond and represent a considerable reservoir of organic matter. However,…
Polycyclic aromatic hydrocarbons (PAHs) and fullerenes play a major role in the physics and chemistry of the interstellar medium. Based on a number of recent experimental and theoretical investigations we developed a model in which PAHs are…
We present observations which probe the small-scale structure of the interstellar medium using diffuse interstellar bands (DIBs). Towards HD 168075/6 in the Eagle Nebula, significant differences in DIB absorption are found between the two…
Diffuse interstellar bands (DIBs) trace warm neutral and weakly-ionized diffuse interstellar medium (ISM). Here we present a dedicated, high signal-to-noise spectroscopic study of two of the strongest DIBs, at 5780 and 5797 \AA, in optical…
The chemical composition of diffuse interstellar clouds is not fully established. They host an active chemistry despite their relatively low density and the ubiquitous presence of far-UV radiation. To further explore the chemical…
Diffuse interstellar bands (DIBs) can trace different conditions of the ISM along the sightline toward the observed stars. A small survey was made in optical wavelengths, producing high resolution and high signal to noise spectra. We…
We study the behavior of eight diffuse interstellar bands (DIBs) in different interstellar environments, as characterized by the fraction of hydrogen in molecular form [$f$(H$_2$)], with comparisons to the corresponding behavior of various…
This work proposes deuteronated PAH (DPAH+ ) molecules as a potential carrier of the 4.4 and 4.65 {\mu}m mid infrared emission bands that have been observationally detected towards the Orion and M17 regions. Density Functional Theory…
It is well known that interstellar spectral features correlate with color excess E(B$-$V). This suggests that measuring intensities of these features allows one to estimate reddening of stars. The aim of this paper is to check how tight…
Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation…
We report the detection of the Diffuse Interstellar Bands (``$DIBs$'') in the optical spectra of seven far-infrared-selected starburst galaxies. The $\lambda$6283.9 \AA and $\lambda$ 5780.5 \AA features are detected with equivalent widths…
We present the first results of a systematic search for Diffuse Interstellar Bands in a carefully selected sample of post-AGB stars observed with high resolution optical spectroscopy. These stars are shown to be ideal targets to study this…
The main goal of this thesis is to unveil some questions related to the formation of complex fullerene-based molecules in space, with the aim of resolving some key problems in astrophysics. The unexpected detections of fullerenes and…
Data-driven models of stellar spectra are useful tools to study non-stellar information, such as the Diffuse Interstellar Bands (DIBs) caused by intervening interstellar material. Using $\sim 55000$ spectra of $\sim 17000$ red clump stars…
We demonstrate that by combining two robust theoretical quantum chemistry calculation techniques, stepwise ionization of C60 fullerene by UV and extreme UV photons can in principle occur up to a limit as high as q=+26 before coulomb…
The carriers of the still (mostly) unidentified diffuse interstellar bands (DIBs) have been a long-standing mystery ever since their first discovery exactly 100 years ago. In recent years, the ubiquitous detection of a large number of DIBs…
The systematic analysis of the correlations between diffuse interstellar bands (DIBs) is extended to weak DIBs through the comprehensive catalogue of the Apache Peak Observatory (APO) of 559 DIBs in 25 lines of sight with diverse…
We report the first detection of buckminsterfullerene (C60) in a proto-planetary nebula (PPN). The vibrational transitions of C60 at 7.0, 17.4, and 18.9um are detected in the Spitzer/IRS spectrum of IRAS 01005+7910. This detection suggests…
Echelle spectra of the double-lined spectroscopic binary HD 204827 were obtained on five nights, at a resolving power R = 38,000 and with a S/N ratio = 750 near 6000 A in the final, combined spectrum. The stars show E(B-V) = 1.11 and…
Interstellar lines observed toward stellar targets change slowly over long timescales, mainly due to the proper motion of the background target relative to the intervening clouds. On longer timescales, the cloud's slowly changing physical…