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We present a scalable single-particle framework to treat electronic correlation in molecules and materials motivated by Green's function theory. We derive a size-extensive Brillouin-Wigner perturbation theory from the single-particle…

Chemical Physics · Physics 2023-09-12 Christopher J. N. Coveney , David P. Tew

We describe an ab initio method for calculating the electronic structure, electronic transport, and forces acting on the atoms, for atomic scale systems connected to semi-infinite electrodes and with an applied voltage bias. Our method is…

Materials Science · Physics 2009-11-07 Mads Brandbyge , Jose-Luis Mozos , Pablo Ordejon , Jeremy Taylor , Kurt Stokbro

Based on a functional-integral formalism, a generalization of the self-energy-functional theory (SFT) is proposed which is applicable to systems of interacting electrons with disorder. Similar to the pure case without disorder, a…

Strongly Correlated Electrons · Physics 2013-05-29 Michael Potthoff , Matthias Balzer

Ab initio description of point defects in semiconductors, characterized by in-gap states of significant multideterminant character, presents a longstanding theoretical challenge for density functional theory (DFT) methods. In this study, we…

Materials Science · Physics 2024-11-27 Zsolt Benedek , Ádám Ganyecz , Anton Pershin , Viktor Ivády , Gergely Barcza

Embedded density functional theory (e-DFT) is used to describe the electronic structure of strongly interacting molecular subsystems. We present a general implementation of the Exact Embedding (EE) method [J. Chem. Phys. 133, 084103 (2010)]…

Other Condensed Matter · Physics 2011-07-27 Jason D. Goodpaster , Taylor A. Barnes , Thomas F. Miller

We introduce the subdimensional entanglement entropy (SEE), defined on subdimensional entanglement subsystems (SESs) embedded in the bulk, as an entanglement-based probe of how geometry and topology jointly shape universal properties of…

Strongly Correlated Electrons · Physics 2026-04-16 Meng-Yuan Li , Peng Ye

Density matrix embedding theory (DMET) describes finite fragments in the presence of a surrounding environment. In contrast to most embedding methods, DMET explicitly allows for quantum entanglement between both. In this chapter, we discuss…

Strongly Correlated Electrons · Physics 2018-02-19 Sebastian Wouters , Carlos A. Jiménez-Hoyos , Garnet K. -L. Chan

We analyse the possibilities for quantum state engineering offered by a model for Kerr-type non-linearity enhanced by electromagnetically induced transparency (EIT), which was recently proposed by Petrosyan and Kurizki [{\sl Phys. Rev. A}…

Quantum Physics · Physics 2015-06-26 M. Paternostro , M. S. Kim , B. S. Ham

We present an overview of electronic device modeling using non-equilibrium Green function techniques. The basic approach developed in the early 1970s has become increasingly popular during the last 10 years. The rise in popularity was…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Roger K. Lake , Rajeev R. Pandey

We present a new perturbation theory for quantum mechanical energy eigenstates when the potential equals the sum of two localized, but not necessarily weak potentials $V_{1}(\vec{r})$ and $V_{2}(\vec{r})$, with the distance $L$ between the…

Quantum Physics · Physics 2007-05-23 Seok Kim , Choonkyu Lee

First principles approaches have been successful in solving many-body Hamiltonians for real materials to an extent when correlations are weak or moderate. As the electronic correlations become stronger often embedding methods based on first…

PET requires accurate, precise, and efficient scatter correction techniques. Conventional scatter estimation typically relies on tail-fitted single-scatter simulation (SSS) strategy. However, the accuracy of tail-fitted SSS is limited, for…

Within many-body perturbation theory, Hedin's formalism offers a systematic way to iteratively compute the self-energy $\Sigma$ of any interacting system, provided one can evaluate the interaction vertex $\Gamma$ exactly. This is however…

Chemical Physics · Physics 2022-11-04 Carlos Mejuto-Zaera , Vojtěch Vlček

In order to investigate the systematics of the loop expansion in high temperature gauge theories beyond the leading order hard thermal loop (HTL) approximation, we calculate the two-loop electron proper self-energy in high temperature QED.…

High Energy Physics - Phenomenology · Physics 2010-04-06 Emil Mottola , Zsolt Szep

We analyze the induced self-energy and self-force on a scalar point-like charged test particle placed at rest in the spacetime of a global monopole admitting a general spherically symmetric inner structure to it. In order to develop this…

High Energy Physics - Theory · Physics 2011-03-03 D. Barbosa , U. de Freitas , E. R. Bezerra de Mello

We present an efficient implemention of a non-equilibrium Green function (NEGF) method for self-consistent calculations of electron transport and forces in nanostructured materials. The electronic structure is described at the level of…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 Jingzhe Chen , Kristian S. Thygesen , Karsten W. Jacobsen

Local electronic-structure methods in quantum chemistry operate on the ability to compress electron correlations more efficiently in a basis of spatially localized molecular orbitals than in a parent set of canonical orbitals. However, many…

Chemical Physics · Physics 2024-08-01 Jonas Greiner , Jürgen Gauss , Janus J. Eriksen

The Hubbard model on a semi-infinite three-dimensional lattice is considered to investigate electron-correlation effects at single-crystal surfaces. The standard second-order perturbation theory in the interaction U is used to calculate the…

Strongly Correlated Electrons · Physics 2009-10-30 M. Potthoff , W. Nolting

We formulate the theory of an extremely correlated electron liquid, generalizing the standard Fermi liquid. This quantum liquid has specific signatures in various physical properties, such as the Fermi surface volume and the narrowing of…

Strongly Correlated Electrons · Physics 2010-01-22 B Sriram Shastry

We have developed and implemented a self-consistent density functional method using standard norm-conserving pseudopotentials and a flexible, numerical LCAO basis set, which includes multiple-zeta and polarization orbitals. Exchange and…