Related papers: Charge-Transfer Dynamics and Nonlocal Dielectric P…
Surface plasmon polariton, hyberbolic dispersion of energy and momentum, and emission interference provide opportunities to control photoluminescence properties. However, the interplays between these regimes need to be understood to take…
A systematic study of nonlocal and size effects on the energy transfer of a dipole (e.g. a molecule or a quantum dot) induced by the proximity of a metal slab is presented. Nonlocal effects are accounted for using the hydrodynamic model…
A charge transfer (CT) model is introduced for strong acceptors like A = F4TCNQ that are ionized on surfaces at low coverage {\theta}. Each A forms a CT dimer with a surface state S. Dipole-dipole repulsion grows as {\theta}^(3/2) up to…
Optical activation of material properties illustrates the potentials held by tuning light-matter interactions with impacts ranging from basic science to technological applications. Here, we demonstrate for the first time that composite…
We investigate the effects of hydrodynamic nonlocal response in hyperbolic metamaterials (HMMs), focusing on the experimentally realizable parameter regime where unit cells are much smaller than an optical wavelength but much larger than…
Graphene-based hyperbolic metamaterials have been predicted to transport evanescent fields with extraordinarily large vacuum wave-vectors. It is particularly at much higher wave vector values that the commonly employed descriptional models…
Electron transfer (ET) in molecular donor-acceptor dye systems is crucial for charge transport in organic semiconductors. Classically, ET rates should decrease with increasing donor-acceptor distance while the microscopic mechanism is more…
Hyperbolic Metamaterials (HMMs) continue to be intriguing due to their applications in super resolution imaging and spontaneous emission control. One of the successful realizations of HMMs is a layered metal-dielectric film. Despite the…
Hybrid materials are crucial in photovoltaics where the overall efficiency of the heterostructure is closely related to the level of charge transfer at the interface. Here, using various metal / poly(3-hexylthiophene)(P3HT) heterostructure…
We suggest a new class of hyperbolic metamaterials for THz frequencies based on multilayer graphene structures. We calculate the dielectric permittivity tensor of the effective nonlocal medium with a periodic stack of graphene layers and…
We show that hyperbolic electromagnetic metamaterials implemented as multilayers based on two material constituents arranged according to Thue-Morse (ThM) aperiodic sequence may exhibit strong nonlocal effects, manifested as the appearance…
Localized cavity resonances due to nanostructures at material surfaces can greatly enhance radiative heat transfer (RHT) between two closely placed bodies owing to stretching of cavity states in momentum space beyond light line. Based on…
The formation of bound electron-hole pairs, also called charge-transfer (CT) states, in organic-based photovoltaic devices is one of the dominant loss mechanisms hindering performance. While CT state dynamics following electron transfer…
Recently synthesized 3D materials with Dirac spectrum exhibit peculiar electric transport qualitatively different from its 2D analogue, graphene. Neglecting impuritiy scattering, the real part of the conductivity is strongly frequency…
Charge transfer is a common phenomenon in van der Waals heterostructures with proper work function mismatch, which enables electrostatic gating to control band alignment and interlayer charge distributions. This provides a tunable platform…
Ultrathin polymer-graphene heterostructures are promising materials for next generation optoelectronic and photovoltaic technologies, while the influence of the polymer's structural variation on interfacial charge transfer remains unclear.…
The dipole P(F) of systems with periodic boundary conditions (PBC) in a static electric field F is applied to one-dimensional Peierls-Hubbard models for organic charge-transfer (CT) salts. Exact results for P(F) are obtained for finite…
Charge-carrier transport in a paradigmatic semicrystalline polymer semiconductor (P3HT) is important for both fundamental understanding and applications. In samples with enhanced structural disorder due to ad-hoc point defects, the mobility…
The concept of periodic structures has driven the development of advanced materials like photonic and phononic crystals. These metamaterials typically rely on complex repeating units or meta-atoms, limiting their adaptability after…
We develop an analytical theory that accounts for the image and surface charge interactions between a charged dielectric membrane and a DNA molecule translocating through the membrane. Translocation events through neutral carbon-based…