Related papers: A generalized detailed balance relation
A complete derivation, from first principles, of the reaction-rate formula for a generic process taking place in a heat bath of finite volume is given. It is shown that the formula involves no finite-volume correction. Through perturbative…
We establish the path integral approach for the time-dependent heat exchange of an externally driven quantum system coupled to a thermal reservoir. We derive the relevant influence functional and present an exact formal expression for the…
In the presence of interactions, periodically-driven quantum systems generically thermalize to an infinite-temperature state. Recently, however, it was shown that in random kicked rotors with local interactions, this long-time equilibrium…
We present a new method for the numerical calculation of canonical reaction rate constants in complex molecular systems, which is based on a path integral formulation of the flux-flux correlation function. Central is the partitioning of the…
The proof of the long-standing conjecture is presented that Markovian quantum master equations are at odds with quantum thermodynamics under conventional assumptions of fluctuation-dissipation theorems (implying a translation invariant…
A tomographic study of near-field radiative heat exchanges between a mesoscopic object and a substrate immersed in a thermal bath is carried out within the theoretical framework of fluctuational electrodynamics. By using the…
We study the role of the system-bath coupling for the generalized canonical thermalization [S. Popescu, et al., Nature Physics 2,754(2006) and S. Goldstein et al., Phys. Rev. Lett. 96, 050403(2006)] that reduces almost all the pure states…
Any evolving system can change of state via thermal mechanisms (hopping a barrier) or via quantum tunneling. Most of the time, efficient classical mechanisms dominate at high temperatures. This is why an increase of the temperature can…
To model a complex system intrinsically separated by a barrier, we use two random Hamiltonians, coupled to each other either by a tunneling matrix element or by an intermediate transition state. We study that model in the universal limit of…
An adiabatic transition between two equilibrium states corresponding to different stiffnesses in an infinite chain of particles is studied. Initially, the chain particles have random displacements and random velocities corresponding to a…
The crucial condition in the derivation of the Jarzynski equality (JE) from the fluctuation theorem is that the time integral of the phase space contraction factor can be exactly expressed as the entropy production resulting from the heat…
The thermodynamic properties of highly charged colloidal suspensions in contact with a salt reservoir are investigated in the framework of the Renormalized Jellium Model (RJM). It is found that the equation of state is very sensitive to the…
In molecular dynamics (MD) simulations, accessing transition probabilities between states is crucial for understanding kinetic information, such as reaction paths and rates. However, standard MD simulations are hindered by the capacity to…
In relativistic kinetic theory, which underlies relativistic hydrodynamics, the molecular chaos hypothesis stands at the basis of the equilibrium Maxwell-Juttner probability distribution for the four-momentum $p^{\alpha}$. We investigate…
We provide a short historic of the early development of kinetic theory in plasma physics and synthesize the basic kinetic equations describing the evolution of systems with long-range interactions derived in Paper I. We describe the…
Thermalization in open systems coupled to macroscopic environments is usually analyzed from the perspective of relaxation of the reduced state of the system to the equilibrium state. Less emphasis is given to the change of the state of the…
This paper revisits the classical problem of representing a thermal bath interacting with a system as a large collection of harmonic oscillators initially in thermal equilibrium. As is well known the system then obeys an equation, which in…
We study the dynamics of an open quantum system interacting with a non-thermal bath. Here, "non-thermal" means that the bath modes do not need to have the same temperature, but they have an effective temperature distribution. We find that,…
Collisional reservoirs are becoming a major tool for modelling open quantum systems. In their simplest implementation, an external agent switches on, for a given time, the interaction between the system and a specimen from the reservoir.…
When an open system is contacted with several thermal baths, the entropy produced by the irreversible processes ($dS_{\mathrm{i}}=dS-\sum_{\alpha}\text{\dj}Q_{\alpha}/T_{\alpha}$) keeps increasing, and this entropy production rate is always…