Related papers: F and Vk centres in LaF3, CeF3 crystals
Bismuth ferrite, BiFeO3, is a multiferroic solid that is attracting increasing attention as a potential photocatalytic material, because the ferroelectric polarisation enhances the separation of photogenerated carriers. With the motivation…
We study orbital excitations in the optical absorption spectra of YVO3 and HoVO3. We focus on an orbital absorption band observed at 0.4 eV for polarization E parallel c. This feature is only observed in the intermediate, monoclinic phase.…
High-resolution far-ultraviolet broadband Fourier-transform photoabsorption spectra of ${}^{32}{\rm S}^{16}{\rm O}$, ${}^{33}{\rm S}^{16}{\rm O}$, ${}^{34}{\rm S}^{16}{\rm O}$, and ${}^{36}{\rm S}^{16}{\rm O}$ are recorded in a microwave…
X-ray absorption spectroscopy measurements in Pr0.5Ca0.5CoO3 were performed at the Pr M4,5, Pr L3, and Ca L2,3 absorption edges as a function of temperature below 300 K. Ca spectra show no changes down to 10 K while a noticeable thermally…
We report on the effects of thermal treatment and ultraviolet irradiation on the point defect concentrations and optical absorption profiles of single crystal CVD synthetic diamond. All thermal treatments were below 850 K, which is lower…
We present the results of an archival 54 ks long Chandra observation of the peculiar source Cir X--1 during the phase passage 0.223-0.261. A comparative analysis of X-ray spectra, selected at different flux levels of the source, allows us…
The polycrystalline samples of LaGa1-xFexO3 have been prepared by standard solid state reaction route. The phase purity of the prepared samples is confirmed by powder xray diffraction experiments followed by Rietveld analysis. It has been…
Pure acetonitrile (CH3CN) and mixed CO:CH3CN and H2O:CH3CN ices have been irradiated at 15K with Vacuum UltraViolet (VUV) photons in the 7-13.6 eV range using synchrotron radiation. VUV photodesorption yields of CH3CN and of photo-products…
We report the detection of eight vibronic bands of C$_3$, seven of which have been hitherto unobserved in astrophysical objects, in the translucent cloud towards HD~169454. Four of these bands are also found towards two additional objects:…
We define and characterize a photometric bandpass (called "Y") that is centered at 1.035 um, in between the traditionally classified ``optical'' and ``infrared'' spectral regimes. We present Y magnitudes and Y-H and Y-K colors for a sample…
We report growth of high-quality single crystals of CeCl3 using a modified Bridgman Stockbarger method in an infrared image furnace. The grown crystals are characterized using single-crystal/powder X-ray diffraction, Laue X-ray diffraction,…
This study investigates the mechanisms underlying ultrafast cross-luminescence observed in BaF$_2$ crystals doped with LaF$_3$. We identified an ultrafast luminescent component with a decay time of approximately 150 ps, which emerges under…
Multiferroic compounds have gained research attention in the field of ferroelectric photovoltaics due to the presence of transition-metal d states from magnetic ions, which tend to reduce the bandgap value. In this work,…
Hexagonal LuFeO$_3$ films have been studied using x-ray absorption and optical spectroscopy. The crystal splittings of Fe$^{3+}$ are extracted as $E_{e'}-E_{e"}$=0.7 eV and $E_{a_1'}-E_{e'}$=0.9 eV and a 2.0 eV optical band gap is…
The adsorption geometry of perfluorinated copper-phthalocyanine molecules (F_{16}CuPc) on Cu(111) and Ag(111) is studied using X-ray standing waves. A detailed, element-specific analysis taking into account non-dipolar corrections to the…
We report studies of the Yb$^{3+}$ site distribution in Er$^{3+}$ co-doped upconverting alkaline earth fluoride nanoparticles using high-resolution absorption measurements. Similar to bulk crystals, Yb$^{3+}$ single ion cubic (O$_h$), and…
The existence of intervalence charge transfer (IVCT) luminescence is reported. It is shown that the so called anomalous luminescence of Ce-doped elpasolite Cs2LiLuCl6, which is characterized mainly by a very large Stokes shift and a very…
In this work, we report the effects of calcination temperature on structural, dielectric, semiconducting and optical properties of YFeO3 nanoparticles prepared by a high energy ball milling process. The structural analysis of the X-ray…
We have obtained FUV (904 -- 1187 \AA) spectra of U Gem in outburst with FUSE. Three of the observations were acquired during the plateau phase of the outburst, while the fourth was obtained during late outburst decline. The plateau spectra…
We measure temperature-dependent one-photon and two-photon induced photoluminescence from (CH3NH3)PbBr3 single crystals cleaved in ultrahigh vacuum. An approach is presented to extract absorption spectra from a comparison of both…