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A brief critical review is given of the 50-year history of experimental and theoretical studies of the magnetic properties of a new promising class of weak ferrimagnets such as RFe$_{1-x}$Cr$_x$O$_3$ with a non-magnetic R-ion (R = La , Y,…

Strongly Correlated Electrons · Physics 2024-01-19 Alexander Moskvin , Evgenii Vasinovich

In this work, we present an analysis of magnetic properties of weak ferrimagnets of the YFe$_{1-x}$Cr$_x$O$_3$ type. Taking into account the main spin interactions - isotropic Heisenberg superexchange, antisymmetric Dzyaloshinskii-Moriya…

Strongly Correlated Electrons · Physics 2024-12-24 E. V. Vasinovich , A. S. Moskvin

In this work, we have performed Monte Carlo simulations in a classical model for RFe$_{1-x}$Cr$_x$O$_3$ with R=Y and Lu, comparing the numerical simulations with experiments and mean field calculations. In the analyzed compounds, the…

The magnetic behavior of polycrystalline yttrium orthoferrite was studied from the experimental and theoretical points of view. Magnetization measurements up to 170 kOe were carried out on a single-phase YFeO3 sample synthesized from…

Materials Science · Physics 2011-03-24 E. Lima , T. B. Martins , H. R. Rechenberg , G. F. Goya , C. Cavelius , R. Rapalaviciute , S. Hao , S. Mathur

Crystal structure, thermal and magnetic properties were systematically studied in the Y$_{1-x}$Pr$_x$CrO$_3$ with $0 \leq x \leq 0.3$ compositions. Magnetic susceptibility and specific heat measurements show an increase of the…

Materials Science · Physics 2018-02-08 A. Durán , R. Escamilla , R. Escudero , F. Morales , E. Verdín

The chromium(II) orthophosphate {\alpha}-Cr3(PO4)2 is a weak ferrimagnet with the Curie temperature TC = 29 K confirmed by a \lambda-type peak in specific heat. Dominant antiferromagnetic interactions in this system are characterized by the…

Orthorhombic single crystals of TbMn0.5Fe0.5O3 are found to exhibit spin-reorientation, magnetization reversal and weak ferromagnetism. Strong anisotropy effects are evident in the temperature dependent magnetization measurements along the…

We have studied a nearly stoichiometric insulating Y$_{0.97(2)}$Cr$_{0.98(2)}$O$_{3.00(2)}$ single crystal by performing measurements of magnetization, heat capacity, and neutron diffraction. Albeit that the YCrO$_3$ compound behaviors like…

Strongly Correlated Electrons · Physics 2020-09-23 Yinghao Zhu , Ying Fu , Bao Tu , Tao Li , Jun Miao , Qian Zhao , Si Wu , Junchao Xia , Pengfei Zhou , Ashfia Huq , Wolfgang Schmidt , Zikang Tang , Zhubing He , Hai-Feng Li

We report a combined experimental and theoretical study on intriguing magnetic properties of quasiferroelectric orthochromates. Large single crystals of the family of RECrO$_3$ (RE = Y, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu) compounds were…

The magnetic interaction between rare-earth and Fe ions in hexagonal rare-earth ferrites (h-REFeO3), may amplify the weak ferromagnetic moment on Fe, making these materials more appealing as multiferroics. To elucidate the interaction…

The mixed ferrite-cobaltites LnFe0.5Co0.5O3, with Ln = Eu & Dy have been prepared by a sol-gel method and the samples have been characterized using X-ray diffraction and electron microscopy. The magnetic investigations reveal that both…

Materials Science · Physics 2019-07-16 Ashish Shukla , Oleg I. Lebedev , Md. Motin Seikh , Asish K. Kundu

We analyze the coupling between the ferroelectric and magnetic order parameters in the magnetoelectric multiferroic BiFeO_3 using density functional theory within the local spin density approximation and the LSDA+U method. We show that weak…

Materials Science · Physics 2007-05-23 Claude Ederer , Nicola A. Spaldin

The mixed rare-earth orthochromite Nd$_{0.5}$Dy$_{0.5}$CrO$_{3}$ has a N\'eel temperature ($T_\mathrm{{N}}$) of ${\sim}$ 175\,K, resulting in the G-type antiferromagnetic ordering of Cr$^{3+}$ spins. The inverse susceptibility shows a…

We investigate the magnetic behavior of polycrystalline CeCr$_x$Fe$_{1-x}$O$_3$ (x = 0, 0.33, 0.67, and 1) synthesized via solid state reaction. Rare earth orthoferrite and orthochromite materials are well known for exhibiting spin…

Materials Science · Physics 2025-07-01 Stephen Tsui , Sara J. Callori

We report ferroelectricity with fairly large spontaneous polarization (P ~ 0.2 - 0.8 \muC/cm2) below the N\'eel temperature of chromium (TNCr) in weakly ferromagnetic rare-earth orthochromites, RCrO3 (R=rare-earth) only when the rare-earth…

Materials Science · Physics 2012-12-19 B. Rajeswaran , D. I. Khomskii , A. K. Zvezdin , C. N. R. Rao , A. Sundaresan

The weak ferromagnet FeBO$_3$ is well known for being a unique system for modelling and testing magnetic dynamics primarily due to relatively simple and localized magnetic structure and its interesting spin wave dynamics. At room…

Strongly Correlated Electrons · Physics 2023-07-05 Jacob Franklin , Jacob Pfund , Joshua Bedard , Weiguo Zhang , P. Shiv Halasyamani , Menka Jain , Ilya Sochnikov

We report on a study of various RVO3 single-crystal samples (R = La, Nd, Sm, Gd, Er and Y) which show temperature-induced magnetization reversal. For compounds with lighter rare-earths (R = La, Nd and Sm), magnetization reversal can be…

Strongly Correlated Electrons · Physics 2007-05-23 L D Tung , M R Lees , G Balakrishnan , D McK Paul

This work addresses the effect of substituting Mn$^{3+}$ by Fe$^{3+}$ at the octahedral site of TbMnO$_3$ on the magnetic phase sequence, ferroelectric and magnetoelectric properties, keeping the Fe$^{3+}$ concentration below 5%. The…

Strongly Correlated Electrons · Physics 2017-05-29 R. Vilarinho , E. Queiros , D. J. Passos , D. A. Mota , P. B. Tavares , M. Mihalik , M. Zentkova , M. Mihalik , A. Almeida , J. Agostinho Moreira

We have grown a YCrO$_3$ single crystal by the floating-zone method and studied its temperature-dependent crystalline structure and magnetization by X-ray powder diffraction and PPMS DynaCool measurements. All diffraction patterns were well…

Strongly Correlated Electrons · Physics 2024-03-08 Qian Zhao , Yinghao Zhu , Si Wu , Junchao Xia , Pengfei Zhou , Kaitong Sun , Hai-Feng Li

Orthoferrites are a class of magnetic materials with a magnetic ordering temperature above 600 K, predominant G-type antiferromagnetic ordering of the Fe-spin system and, depending on the rare-earth ion, a spin reorientation of the Fe spin…

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