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We have systematically studied the mechanical stability of all noble metal carbides with the rock-salt structure by calculating their elastic constants within the density function theory scheme. It was found that only four carbides (RuC,…

Materials Science · Physics 2009-11-11 Chang-Zeng Fan , Song-Yan Zeng , Zai-Ji Zhan , Ri-Ping Liu , Wen-Kui Wang , Ping Zhang , Yu-Gui Yao

The high-pressure phase transitions of B1-structured stoichiometric transition metal carbides (TMCs, TM=Ti, Zr, Hf, V, Nb, and Ta) were systematically investigated using ab initio calculations. These carbides underwent universal phase…

Materials Science · Physics 2015-03-17 Zhisheng Zhao , Xiang-Feng Zhou , Li-Min Wang , Bo Xu , Julong He , Zhongyuan Liu , Hui-Tian Wang , Yongjun Tian

A new type of heavy transition metal carbide (TMC), Ru2C with a space group of p3 - m1(164) was synthesized experimentally at high pressurehigh temperature [J Phys. Condens. Matter. 2012 Sep 12; 24(36): 362202.] and it was consequently…

Materials Science · Physics 2015-06-17 Weiwei Sun , Sudip Chakraborty , Rajeev Ahuja

We perform density functional theory calculation to investigate the structural and electronic properties of various two-dimensional transition metal dichalcogenides, MX$_2$ (M$=$Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W, and X$=$S or Se), and…

Materials Science · Physics 2019-05-21 Seoung-Hun Kang , Young-Kyun Kwon

Multicomponent transition metal carbides are promising for extreme-environment applications, but identifying compositions that are both synthesizable and hard remains challenging. We fine-tune the MACE machine-learned interatomic potential…

Materials Science · Physics 2026-05-29 Xin Liu , Anirudh Raju Natarajan

We have studied the physical properties of M2InC (M = Zr, Hf and Ta) MAX phases ternary carbides using density functional theory (DFT) methodology. The structural, elastic and electronic properties are revisited (and found to be in good…

Materials Science · Physics 2018-05-23 F. Sultana , M. M. Uddin , M. A. Ali , M. M. Hossain , S. H. Naqib , A. K. M. A. Islam

The elastic constant tensors for the hcp phases of three transition metals (Co, Re, and Fe) are computed as functions of pressure using the Linearized Augmented Plane Wave method with both the local density and generalized gradient…

Materials Science · Physics 2009-10-31 G. Steinle-Neumann , L. Stixrude , R. E. Cohen

Properties of the $\omega$ structure are investigated for 27 transition elements from the viewpoints of thermodynamical and mechanical stability based on first-principles calculations. The thermodynamical stability of the $\omega$ structure…

Materials Science · Physics 2016-04-20 Yuji Ikeda , Isao Tanaka

Cubic rocksalt structured transition-metal carbides, nitrides, and related alloys (TMC/Ns) are attractive for a wide variety of applications, notably as hard, wear-resistant material. To-date, valence electron concentration (VEC) is used as…

Materials Science · Physics 2024-05-14 Hanna Kindlund , Theodora Ciobanu , Suneel Kodambaka , C. V. Ciobanu

MAX phases are nanolaminated ternary materials that combine metallic and ceramic properties. Currently, the A-site elements replacement in traditional ones by later transition-metals opens a door to explore new types of MAX phases. In this…

Materials Science · Physics 2021-11-25 Erxiao Wu , Yiming Zhang , Mian Li , Youbing Li , Kan Luo , Shiyu Du , Qing Huang

First principle DFT simulations are employed to study structural and mechanical properties of orthorhombic B12-based metal carbide-borides. The simulations predict the existence of Ca- and Sr- based phases with the structure similar to that…

Materials Science · Physics 2025-04-15 Oleksiy Bystrenko , Jingxian Zhang , Tianxing Sun , Hu Ruan , Yusen Duan , Kaiqing Zhang , Xiaoguang Li

The elastic properties of the $B_1$-structured transition-metal nitrides and their carbide counterparts are studied using the {\it ab initio\} density functional perturbation theory. The linear response results of elastic constants are in…

Materials Science · Physics 2009-11-10 Zhigang Wu , Xiao-Jia Chen , Viktor V. Struzhkin , Ronald E. Cohen

We report an ab-initio study of the stability and electronic properties of transition metal silicides in order to study their potential for high temperature thermoelectric applications. We focus on the family M5Si3 (M = Ta, W) which is…

Materials Science · Physics 2015-06-03 P. Jund , X. Tao , R. Viennois , C. Colinet , J. -C. Tedenac

By means of density-functional calculations, we systematically investigated 24 transition metals for possible metastable phases in body-centered tetragonal structure (bct), including face-centered cubic (fcc) and body-centered cubic (bcc)…

Structural, mechanical, electronic, and thermodynamic properties of fluorite and tetragonal phases of ZrH$_{2}$ are systematically studied by employing the density functional theory within generalized gradient approximation. The existence…

Materials Science · Physics 2010-08-02 Peng Zhang , Bao-Tian Wang , Chao-Hui He , Ping Zhang

The elastic properties of rutile transition metal dioxides XO$_{2}$ (X=Ru, Rh, Os, and Ir) are investigated using first-principles calculations based on density functional theory. Elastic constants, bulk modulus, shear modulus, and Young's…

Materials Science · Physics 2008-09-25 Yanling Li , Zhi Zeng

We present a comprehensive first-principles study of the structural and elastic properties of 2H-MX$_2$ transition metal dichalcogenides (TMDs) (M = W, Mo, Ta, Nb; X = S, Se). Using density functional theory with various van der Waals…

Materials Science · Physics 2025-05-12 S. Azadi , A. Azhar , R. V. Belosludov , T. D. Kühne , M. S. Bahramy

Recently several theoretical predictions were made about 2D planar FeC, CoC, NiC, and CuC while their bulk phases still remain unknown. Here, we present generalization of 2D family of 3d transition metal monocarbides (TMC) by searching…

Materials Science · Physics 2020-07-03 Konstantin V. Larionov , Gotthard Seifert , Pavel B. Sorokin

In this work, we report an ab initio investigation based on density functional theory of the structural, energetic and electronic properties of 2D layered chalcogenides compounds based in the combination of the transition-metals (Ti, Zr,…

Materials Science · Physics 2019-04-17 Carlos M. O. Bastos , Rafael Besse , Juarez L. F. Da Silva , Guilherme M. Sipahi

Stable compounds in the V-N system are systematically searched and four new high-pressure phases are found, including C2/m-V$_9$N, Pbam-V$_5$N$_2$, Pnma-V$_2$N and I4/mcm-VN$_2$. V$_2$N undergoes a phase transition from…

Materials Science · Physics 2020-03-03 Jin Zhang , Xinfeng Li , Xiao Dong , Huafeng Dong , Artem R. Oganov
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