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The presence of a switchable spontaneous electric polarization makes ferroelectrics ideal candidates for the use in many applications such as memory and sensors devices. Since known ferroelectrics are rather limited, finding new…

Materials Science · Physics 2016-02-25 Ke Xu , Xue-Zeng Lu , H. J. Xiang

Using first-principles methods, we predict the energy landscape and ferroelectric states of double perovskites of the form AA$'$BB$'$O$_6$ in which the atoms on both the A and B sites are arranged in rock-salt order. While we are not aware…

Materials Science · Physics 2011-04-25 Anindya Roy , David Vanderbilt

Strain engineering of perovskite oxide thin films has proven to be an extremely powerful method for enhancing and inducing ferroelectric behavior. In ferroelectric thin films and superlattices, the polarization is intricately linked to…

The effect of epitaxial strain on the phonon spectra, crystal structure, spontaneous polarization, dielectric, piezoelectric, and elastic properties of (001)-oriented ferroelectric (BaTiO$_3$)$_m$/(SrTiO$_3$)$_n$ superlattices ($m = n =…

Materials Science · Physics 2016-07-11 Alexander I. Lebedev

Polar topological structures in ferroelectric thin films have recently drawn significant interest due to their fascinating physical behaviors and promising applications in high-density nonvolatile memories. However, most polar topological…

Materials Science · Physics 2024-02-26 Bo Xu , Zhanpeng Gong , Jingran Liu , Yunfei Hong , Yang Yang , Lou Li , Yilun Liu , Junkai Deng , Jefferson Zhe Liu

We investigate the strain dependence of the ferroelectric polarization and the structure of the ferroelectric domain walls in the layered perovskite-related barium fluorides, BaMF$_4$ (M=Mg, Zn). The unusual "geometric ferroelectricity" in…

Materials Science · Physics 2016-02-24 Maribel Núñez Valdez , Hendrik Th. Spanke , Nicola A. Spaldin

The structural, elastic, magnetic properties, as well as electronic structure and chemical bonding picture of new oxide 3d1-perovskite BaVO3, recently synthesized, were systematically investigated involving the first-principles FLAPW-GGA…

Materials Science · Physics 2019-04-18 V. V. Bannikov

Perovskite structure SrMnO$_3$ is a rare example of a multiferroic material where strain-tuning and/or cation substitution could lead to coinciding magnetic and ferroelectric ordering temperatures, which would then promise strong…

Materials Science · Physics 2018-10-24 Alexander Edström , Claude Ederer

Using an extension of a first-principles method developed by King-Smith and Vanderbilt [Phys. Rev. B {\bf 49}, 5828 (1994)], we investigate the effects of in-plane epitaxial strain on the ground-state structure and polarization of eight…

Materials Science · Physics 2009-12-22 Oswaldo Dieguez , Karin M. Rabe , David Vanderbilt

We performed first principles calculations for epitaxially strained orthorhombic CaTiO$_3$. The computational results reveal the existence of a metastable ferroelectric phase at compressive strain with unexpected in-plane polarization.…

Materials Science · Physics 2013-08-27 Qibin Zhou , Karin M. Rabe

Using first-principles calculations, we estimated the impact of large applied electric E fields on the structural, dielectric, and ferroelectric properties of typical ferroelectrics. At large fields, the structural parameters change…

Materials Science · Physics 2016-05-25 Daniel I. Bilc , Liviu Zarbo , Sorina Garabagiu , Eric Bousquet , Liliana Mitoseriu

Switchable order parameters in ferroic materials are essential for functional electronic devices, yet disruptions of the ordering can take the form of planar boundaries or defects that exhibit distinct properties. Characterizing the…

Hybrid organic inorganic formate perovskites, AB(HCOO)$_3$, is a large family of compounds which exhibit variety of phase transitions and diverse properties. Some examples include (anti)ferroelectricity, ferroelasticity,…

Using first-principles calculations based on a variational density functional perturbation theory, we investigate the lattice dynamics of solid solutions of barium and strontium titanates. Averaging the information available for the related…

Materials Science · Physics 2009-10-31 Ph. Ghosez , D. Desquesnes , X. Gonze , K. M. Rabe

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

We propose a design strategy - based on the coupling of spins, optical phonons, and strain - for systems in which magnetic (electric) phase control can be achieved by an applied electric (magnetic) field. Using first-principles…

Materials Science · Physics 2015-06-25 Craig J. Fennie , Karin M. Rabe

We propose to insert TiO layers to perovskite ATiO$_{3}$ to form a superlattice and use first-principles calculations to investigate its basic properties. Our computational analysis shows that the structure, which consists of repeated…

Materials Science · Physics 2020-02-11 S. Raza , R. Zhang , N. Zhang , Z. Li , L. Liu , F. Zhang , D. Wang , C. -L. Jia

Going down to the limit of ultrathin films holds promise for a new generation of devices such as ferroelectric tunnel junctions or resistive memories. However, these length scales also make the devices sensitive to parasitic effects related…

While nature provides a plethora of perovskite materials, only a few exhibits large ferroelectricity and possibly multiferroicity. The majority of perovskite materials have the non-polar CaTiO$_3$(CTO)structure, limiting the scope of their…

Materials Science · Physics 2022-05-25 Hongwei Wang , Fujie Tang , Massimiliano Stengel , Hongjun Xiang , Qi An , Tony Low , Xifan Wu

First principles study of structural, elastic, and electronic properties of the cubic perovskitetype BaHfO$_3$ has been performed using the plane wave ultrasoft pseudo-potential method based on density functional theory with revised…

Materials Science · Physics 2008-09-23 Hongsheng Zhao , Aimin Chang , Yunlan Wang