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We present ab-initio transport calculations for molecular junctions that include graphene as a protecting layer between a single molecule and gold electrodes. This vertical setup has recently gained significant interest in experiment for…

Mesoscale and Nanoscale Physics · Physics 2015-12-15 Falco Hüser , Gemma C. Solomon

Here we present a theoretical study of the thermoelectric transport through {[}2,2{]}para\-cyclo\-phane-based single-molecule junctions. Combining electronic and vibrational structures, obtained from density functional theory (DFT), with…

Mesoscale and Nanoscale Physics · Physics 2017-04-07 Marius Bürkle , Thomas J. Hellmuth , Fabian Pauly , Yoshihiro Asai

Non-equilibrium transport and phonon branch-resolved size effects in single-layer graphene materials are studied under a multi-temperature kinetic model, which is developed for capturing the branch-dependent electron-phonon coupling.…

Mesoscale and Nanoscale Physics · Physics 2025-10-07 Chuang Zhang , Houssem Rezgui , Meng Lian , Hong Liang

Defects can significantly degrade the thermal conductivity of ThO2, an advanced nuclear fuel material as well as a surrogate for other fluorite-structured materials. We investigate how point defects in ThO2 impact phonon mode-resolved…

Materials Science · Physics 2024-09-24 Beihan Chen , Linu Malakkal , Marat Khafizov , David H. Hurley , Miaomiao Jin

We report finite-volume simulations of the phonon Boltzmann transport equation (BTE) for heat conduction across the heterogeneous interfaces in SiGe superlattices. The diffuse mismatch model incorporating phonon dispersion and polarization…

Mesoscale and Nanoscale Physics · Physics 2010-05-17 Dhruv Singh , Jayathi Y. Murthy , Timothy S. Fisher

Phonons are the primary heat carriers in non-metallic solids. In compositionally heterogeneous materials, the thermal properties are believed to be mainly governed by the disrupted phonon transport due to mass disorder and strain…

In typical thermoelectric energy harvesters and sensors, the Seebeck effect is caused by diffusion of electrons or holes in a temperature gradient. However, the Seebeck effect can also have a phonon drag component, due to momentum exchange…

The role of optical-phonons in frictional drag between two adjacent but electrically isolated two-dimensional electron gases is investigated. Since the optical-phonons in III-V materials have a considerably larger coupling to electrons than…

Mesoscale and Nanoscale Physics · Physics 2008-02-03 Ben Yu-Kuang Hu

Declining the lattice thermal conductivity in graphene is essential for its thermoelectric applications. In high electron density systems, scatterings of phonons by electrons are no less than the phonon scatterings by other phonons. With…

Materials Science · Physics 2019-08-08 Ajit Jena , Wu Li

The electronic and phonon transport properties of graphene-like boron phosphide (BP), boron arsenide (BAs), and boron antimonide (BSb) monolayers are investigated using first-principles calculations and Boltzmann theory. By considering both…

Materials Science · Physics 2019-07-24 Z. Z. Zhou , H. J. Liu , D. D. Fan , G. H. Cao

In low-dimensional systems, the combination of reduced dimensionality, strong interactions, and topology has led to a growing number of many-body quantum phenomena. Thermal transport, which is sensitive to all energy-carrying degrees of…

The low-temperature thermal conductivity in polycrystalline graphene is theoretically studied. The contributions from three branches of acoustic phonons are calculated by taking into account scattering on sample borders, point defects and…

Materials Science · Physics 2015-06-05 D. V. Kolesnikov , V. A. Osipov

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

Materials Science · Physics 2015-10-20 Tian Lan

First-principles calculations are employed to investigate the phonon transport of BiCuOSe. Our calculations reproduce the lattice thermal conductivity of BiCuOSe. The calculated gruneisen parameter is 2.4~2.6 at room temperature, a fairly…

Materials Science · Physics 2016-03-10 Hezhu Shao , Xiaojian Tan , Guo-Qiang Liu , Jun Jiang , Haochuan Jiang

In conventional metals, thermal transport is governed by electrons, with phonon contributions often considered negligible. Here, through rigorous first-principles calculations, we uncover a phonon-dominated thermal transport regime in the…

Materials Science · Physics 2026-01-13 Xianyong Ding , Xin Jin , Dengfeng Li , Jing Fan , Peng Yu , Xiaoyuan Zhou , Xiaolong Yang , Rui Wang

While using first-principles-based Boltzmann transport equation approach to predict the thermal conductivity of crystalline semiconductor materials has been a routine, the validity of the approach is seldom tested for high-temperature…

Mesoscale and Nanoscale Physics · Physics 2020-03-05 Xiaokun Gu , Shouhang Li , Hua Bao

Departures in phonon heat conduction from diffusion have been extensively observed in nanostructures through their thermal conductivity reduction and largely explained with classical size effects neglecting phonon's wave nature. Here, we…

Nanostructured materials exhibit low thermal conductivity because of the additional scattering due to phonon-boundary interactions. As these interactions are highly sensitive to the mean free path (MFP) of a given phonon mode, MFP…

Materials Science · Physics 2016-01-13 Giuseppe Romano , Keivan Esfarjani , David A. Strubbe , David Broido , Alexie M. Kolpak

Energy transfer to acoustic phonons is the dominant low-temperature cooling channel of electrons in a crystal.For cold neutral graphene we find that the weak cooling power of its acoustical modes relative to the heat capacity of the system…

Mesoscale and Nanoscale Physics · Physics 2013-05-29 R. Bistritzer , A. H. MacDonald

Recently, an anisotropic Debye model [Dames et al., Physical Review B 87, 12 (2013)] was proposed for calculations of the interfacial thermal conductance and the minimum thermal conductivity of graphite-like layered materials. Despite…

Applied Physics · Physics 2018-12-13 Hongkun Li , Weidong Zheng , Yee Kan Koh