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A parallel plate capacitor containing an electrolytic solution is the simplest model of a supercapacitor, or electric double layer capacitor. Using both analytical and numerical techniques, we solve the Poisson-Nernst-Planck equations for…

Soft Condensed Matter · Physics 2025-10-02 Ivan Palaia , Adelchi J. Asta , Megh Dutta , Patrick B. Warren , Benjamin Rotenberg , Emmanuel Trizac

The crystallization of amorphous solids under ultrafast laser irradiation represents a paradigm of non-equilibrium phase transitions, where the interplay between electromagnetic energy localization and atomic-scale dynamics remains largely…

The pinning of the contact line adversely influences the electrowetting performance of sessile liquid droplets. In this paper, we report the electrowetting hysteresis characteristics of 100 mM aq. KCl sessile liquid droplet placed on a…

Soft Condensed Matter · Physics 2019-01-23 Sumit Kumar , Pawan Kumar , Sunando DasGupta , Suman Chakraborty

We use density functional theory calculations to study simple but diverse stoichiometries within the novel chemical capacitor (CC) setup. We look at main effects occurring in this device, extremes of the physicochemical properties, and we…

Materials Science · Physics 2025-11-18 Łukasz Wolański , Dawid Ciszewski , Piotr Szkudlarek , José Lorenzana , Wojciech Grochala

Platinum step edges dominate electrocatalytic activity in fuel cells and electrolysers, yet their atomistic electrochemical behaviour remains poorly understood. Here, we employ \textit{ab initio} molecular dynamics under controlled…

Materials Science · Physics 2025-10-15 Matthew T. Darby , Muhammad Saleh , Marialore Sulpizi , Clotilde S. Cucinotta

We use molecular simulations of an ionic liquid in contact with a range of nanoporous carbons to investigate correlations between ion size, pore size, pore topology and properties of the adsorbed ions. We show that diffusion coefficients…

Materials Science · Physics 2020-02-21 El Hassane Lahrar , Anouar Belhboub , Patrice Simon , Céline Merlet

Metallic nanoparticles have been used as catalysts for various reactions, and the huge literature on the subject is hard to overlook. In many applications, the nanoparticles must be affixed to a colloidal carrier for easy handling during…

The thermal transport properties of porous silicon and nano-hybrid "porous silicon/water" systems are presented here. The thermal conductivity was evaluated with equilibrium molecular dynamics technique for porous systems made of spherical…

Mesoscale and Nanoscale Physics · Physics 2020-12-03 Mykola Isaiev , Xiaorui Wang , Konstantinos Termentzidis , David Lacroix

The development of high-energy and high-power density supercapacitors (SCs) is critical for enabling next-generation energy storage applications. Nanocarbons are excellent SC electrode materials due to their economic viability, high-surface…

Slow ionic transport and high voltage drop (IR drop) of homogeneous porous electrodes are the critical causes of severe performance degradation of lithium-ion (Li-ion) batteries under high charging rates. Herein, we demonstrate that a…

Materials Science · Physics 2021-07-30 Chenxi Sui , Yao-Yu Li , Xiuqiang Li , Genesis Higueros , Keyu Wang , Wanrong Xie , Po-Chun Hsu

Nanocomposites comprised of insulated magnetic single-domain particles are promising candidates for high-frequency, eddy current free, soft magnetic materials, but tend to suffer from low magnetic susceptibility ($<20$). Particle alignment…

When the electron density of highly crystalline thin films is tuned by chemical doping or ionic liq- uid gating, interesting effects appear including unconventional superconductivity, sizeable spin-orbit coupling, competition with…

Mesoscale and Nanoscale Physics · Physics 2018-12-19 G. Dezi , N. Scopigno , S. Caprara , M. Grilli

This study employs modified Poisson-Boltzmann theory to systematically investigate the influence of zwitterionic osmolyte additives to an electrolyte solution on disjoining pressure and electric differential capacitance within charged…

Soft Condensed Matter · Physics 2025-06-30 Victoria A. Vasileva , Daria A. Mazur , Petr E. Brandyshev , Yury A. Budkov

Dielectric capacitors are critical components in electronics and energy storage devices. The polymer based dielectric capacitors have advantages of flexibility, fast charge and discharge, low loss, and graceful failure. Elevating the use of…

Short nanopores have various applications in biosensing, desalination, and energy conversion. Here, the modulation of charged exterior surfaces on ionic transport is investigated through simulations with sub-200 nm long nanopores under…

Soft Condensed Matter · Physics 2024-02-08 Long Ma , Zhe Liu , Jia Man , Jianyong Li , Zuzanna S. Siwy , Yinghua Qiu

Enhancing the performance of nanoscale ferroelectric (FE) field-effect transistors and FE capacitors for memory devices and logic relies on miniaturizing the metal electrode/ferroelectric area and reducing the thickness of the insulator.…

Materials Science · Physics 2017-07-24 Danilo Puggioni , Gianluca Giovannetti , James M. Rondinelli

Metal nanoparticles are receiving increased scientific attention owing to their unique physical and chemical properties that make them suitable for a wide range of applications in diverse fields, such as electrochemistry, biochemistry, and…

Chemical Physics · Physics 2020-10-09 Bendix Petersen , Rafael Roa , Joachim Dzubiella , Matej Kanduc

Endowed with a multitude of exquisite properties such as rich electrochemistry, superb topology and eccentric electromagnetic phenomena, honeycomb layered oxides have risen to the top echelons of science with applications in diverse fields…

All-solid-state batteries using sodium are promising candidates for next-generation rechargeable batteries due to the limited lithium resources. A practical sodium battery requires an electrolyte with high conductivity. Cubic Na$_3$PS$_4$…

Effective passivation of lithium metal surfaces, and prevention of battery-shorting lithium dendrite growth, are critical for implementing lithium-metal-anodes for batteries with increased power densities. Nanoscale surface heterogeneities…

Materials Science · Physics 2017-10-03 Kevin Leung , Katherine L. Jungjohann
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