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We employ simulation based approach for enhancing the efficiency of Cu2ZnSnS4 (CZTS) based solar cells. Initial benchmarking of simulation with the experimentally reported solar cell in literature is performed by incorporating a suitable…

Applied Physics · Physics 2018-07-11 Atul Kumar , Ajay D. Thakur

Traditional CdS buffer layer in selenium-free Cu(In,Ga)S2 solar cells leads to reduced open-circuit voltage because of a negative conduction band offset at the Cu(In,Ga)S2/CdS interface. Reducing this loss necessitates the substitution of…

This study investigates the critical role of buffer layers in enhancing the efficiency of thin-film CdTe solar cells. We explore non-toxic buffer materials, specifically ZnSe, ZnMgO, 3C-SiC, and WS2, as potential replacements for the…

Cu2ZnSnS(e)4 (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu2ZnSn(S,Se)4 (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se2…

Applied Physics · Physics 2018-03-14 Shoushuai Gao , Zhenwu Jiang , Li Wu , Jianping Ao , Yu Zeng , Yun Sun , Yi Zhang

Sulfide chalcopyrite, Cu(In,Ga)S2, having wide bandgap (larger than 1.5 eV), favorable optoelectronic properties, and high stability, is a promising top-cell absorber for tandem applications. Adapting device structures optimized for 1.0 -…

We simulated photovoltaic characteristics of single heterojunction solar cell with Cu2ZnSnS4 and Cu2ZnSnSe4 absorber layer numerically using one dimensional solar cell capacitance simulator (SCAPS-1D). n-CdS/ZnO double buffer layer is used…

Applied Physics · Physics 2018-01-26 Goutam K Gupta , Ambesh Dixit

Kesterite is a leading candidate among inorganic thin-film photovoltaic technologies, offering sustainable and environmentally friendly solutions without reliance on critical raw materials. This study investigates the performance of…

Dual-absorber solar cells represent a promising approach to surpass the efficiency limit of single-junction devices by extending spectral absorption and minimizing thermalization losses. Among earth-abundant thin-film materials, kesterites…

Materials Science · Physics 2025-11-14 Hasib Md Abid Bin Farid , Md Tashfiq Bin Kashem

This paper proposes an efficient three-layered p-GaAs/p-CIGS/n-CdS (PPN), a unique solar cell architecture. Copper indium gallium selenide (CIGS)-based solar cells exhibit substantial performance than the ones utilizing cadmium sulfide…

Systems and Control · Electrical Eng. & Systems 2023-09-15 Satyam Bhatti , Habib Ullah Manzoor , Ahmed Zoha , Rami Ghannam

Cu2ZnSnS4 (CZTS) is a promising photovoltaic absorber material with earth abundant and nontoxic elements. However, the detrimental native defects and secondary phases of CSTS will largely reduce the energy conversion efficiencies. To…

Materials Science · Physics 2017-11-15 Yiou Zhang , Kinfai Tse , Xudong Xiao , Junyi Zhu

Ternary chalcostibite copper antimony selenide (CuSbSe2) is a promising absorber material for next generation thin film solar cells due to the non-toxic nature, earth-abundance, low-cost fabrication technique, optimum bandgap and high…

Solution-processed intrinsic ZnO and Al doped ZnO (ZnO:Al) were spin coated on textured n-type c-Si wafer to replace the phosphorus doped amorphous silicon as the electron selective transport layer (ESTL) of the Si heterojunction (SHJ)…

Applied Physics · Physics 2018-04-10 Jiangnan Ding , Yurong Zhou , Gangqiang Dong , Ming Liu , Donghong Yu , Fengzhen Liu

Solar cells with the structure ITO-PEDOT:PSS-Ag:SnS-Al were fabricated with the active layer of tin sulphide with silver nano-particles (Ag:SnS) grown by thermal co-evaporation. To understand the influence of the silver nanoparticles on the…

Materials Science · Physics 2015-04-02 Priyal Jain , P. Arun

The monolithic tandem integration of third-generation solar energy materials on silicon holds great promise for photoelectrochemistry and photovoltaics. However, this can be challenging when it involves high-temperature reactive processes,…

We present evidence that band gap narrowing at the heterointerface may be a major cause of the large open circuit voltage deficit of Cu$_2$ZnSnS$_4$/CdS solar cells. Band gap narrowing is caused by surface states that extend the…

Mesoscale and Nanoscale Physics · Physics 2017-04-05 Andrea Crovetto , Mattias Palsgaard , Tue Gunst , Troels Markussen , Kurt Stokbro , Mads Brandbyge , Ole Hansen

We considered modification of the defect density of states in CdTe as influenced by a buffer layer in ZnO(ZnS, SnSe)/CdS/CdTe solar cells. Compared to the solar cells employing ZnO buffer layers, implementation of ZnSe and ZnS resulted in…

Materials Science · Physics 2016-01-15 Y. G. Fedorenko , J. D. Major , A. Pressman , L. Phillips , K. Durose

Interface recombination at the absorber buffer interface impedes the efficiency of a solar cell with an otherwise excellent absorber. The internal voltage or the quasi-Fermi level splitting (qFLs) measures the quality of the absorber.…

A systematic survey and subsequent research have been made on MoTe2-based n-CdS/p-MoTe2/p+-CGS device in solar cell and photodetector field. The optimization has been established by altering the various properties of each constituent layer…

In this work, first principle calculations of Cu$_2$ZnSnS$_4$ (CZTS), Cu$_2$ZnGeS$_4$ (CZGS) and Cu$_2$ZnSiS$_4$ (CZSS) are performed to highlight the impact of the cationic substitution on the structural, electronic and optical properties…

Applied Physics · Physics 2022-02-22 Thomas Ratz , Jean-Yves Raty , Guy Brammertz , Bart Vermang , Ngoc Duy Nguyen

Solar cells based on kesterite-type $Cu_2ZnSnS_4$ (CZTS) thin films were fabricated using a chemical route to prepare the $CZTS$ films, consisting in sequential deposition of $Cu_2SnS_3$ (CTS) and $ZnS$ thin films followed by annealing at…

Applied Physics · Physics 2019-08-06 John M. Correa , Raúul A. Becerra , Asdrubal A. Ramírez , Gerardo Gordillo
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