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We study non-linear adiabatic connection paths in density-functional theory using modified electron-electron interactions that perform a long-range/short-range separation of the Coulomb interaction. These adiabatic connections allows to…

Chemical Physics · Physics 2009-11-11 Julien Toulouse , Francois Colonna , Andreas Savin

Time dependent quantum systems are the subject of intense inquiry, in mathematics, science, and engineering, particularly at the atomic and molecular levels. In 1984, Runge and Gross introduced time dependent density functional theory…

Analysis of PDEs · Mathematics 2021-02-24 Joseph W. Jerome

Semi-local density functionals for the exchange-correlation energy of a many-electron system cannot be exact for all one-electron densities. In 1981, Perdew and Zunger (PZ) subtracted the fully-nonlocal self-interaction error…

Chemical Physics · Physics 2019-04-26 Biswajit Santra , John P. Perdew

We present an investigation into the transferability of pseudopotentials (PPs) with a nonlinear core correction (NLCC) using the Goedecker, Teter, and Hutter (GTH) protocol across a range of pure GGA, meta-GGA and hybrid functionals, and…

Chemical Physics · Physics 2023-07-20 Wan-Lu Li , Kaixuan Chen , Elliot Rossomme , Martin Head-Gordon , Teresa Head-Gordon

We have investigated the electronic structures of various potentially half-metallic Heusler compounds with the Tran-Blaha modified Becke-Johnson (TB-mBJLDA) potential within the density functional theory. The half-metallic gaps are…

Materials Science · Physics 2013-05-30 Markus Meinert

Accurate prediction of spin-state energy difference is crucial for understanding the spin crossover (SCO) phenomena and is very challenging for the density functional approximations, especially for the local and semi-local approximations,…

Chemical Physics · Physics 2023-02-22 Selim Romero , Tunna Baruah , Rajendra R. Zope

Van der Waals (vdW) heterostructures consisting of bilayer graphene (BLG) encapsulated within monolayers of strong spin-orbit semiconductor WS$_2$ or ferromagnetic semiconductor Cr$_2$Ge$_2$Te$_6$ (CGT), are investigated. By performing…

Mesoscale and Nanoscale Physics · Physics 2021-08-18 Klaus Zollner , Jaroslav Fabian

We present the first principles results of point defect energetics in silicon calculated using the LDA+U method: a Hubbard type on-site interaction added to the local density approximation (LDA). The on-site Coulomb and exchange parameters…

Materials Science · Physics 2007-05-23 Panchapakesan Ramanarayanan , Renat F. Sabirianov , Kyeongjae Cho

\ni We develop a simple method to study the zero-point and thermally renormalized electron energy $\varepsilon_{\mathbf{k}n}(T)$ for $\mathbf{k}n$ the conduction band minimum or valence maximum in polar semiconductors. We use the adiabatic…

Materials Science · Physics 2016-09-21 Jean Paul Nery , Philip B. Allen

Variational Bayes (VB) applied to latent Dirichlet allocation (LDA) has become the most popular algorithm for aspect modeling. While sufficiently successful in text topic extraction from large corpora, VB is less successful in identifying…

Machine Learning · Computer Science 2022-08-22 Rebecca M. C. Taylor , Johan A. du Preez

Proximity coupling of bilayer graphene (BLG) to transition metal dichalcogenides (TMDs) offers a promising route to engineer gate-tunable spin-orbit coupling (SOC) while preserving BLG's exceptional electronic properties. This tunability…

Mesoscale and Nanoscale Physics · Physics 2026-04-13 E. Icking , F. Wörtche , A. W. Cummings , A. Wörtche , K. Watanabe , T. Taniguchi , C. Volk , B. Beschoten , C. Stampfer

First principle calculations based on LDA/GGA approximation for the exchange functional underestimate the position of the semi core 3d levels in GaX (X = N, P and As) semiconductors. A self-interaction correction scheme within the…

Materials Science · Physics 2007-06-05 Roby Cherian , Priya Mahadevan , Clas Persson

Accurately modeling the structural reconstruction and thermodynamic behavior of van der Waals (vdW) heterostructures remains a significant challenge due to the limitations of conventional force fields in capturing their complex mechanical,…

Computational Physics · Physics 2026-02-26 Hekai Bu , Wenwu Jiang , Penghua Ying , Ting Liang , Zheyong Fan , Wengen Ouyang

Standard approximations for the exchange-correlation (XC) functional in Kohn-Sham density functional theory (KS-DFT) typically lead to unacceptably large errors when applied to strongly-correlated electronic systems. Partition-DFT (PDFT) is…

Chemical Physics · Physics 2023-09-12 Yi Shi , Yuming Shi , Adam Wasserman

We assess the performance of a recently proposed renormalized adiabatic local density approximation (rALDA) for \textit{ab initio} calculations of electronic correlation energies in solids and molecules. The method is an extension of the…

Materials Science · Physics 2014-05-30 Thomas Olsen , Kristian S. Thygesen

Recently proposed local self-interaction correction (LSIC) method [Zope, R. R. et al., J. Chem. Phys. 151, 214108 (2019)] is a one-electron self-interaction-correction (SIC) method that uses an iso-orbital indicator to apply the SIC at each…

Chemical Physics · Physics 2023-02-22 Yoh Yamamoto , Tunna Baruah , Po-Hao Chang , Selim Romero , Rajendra R. Zope

The modified Becke-Johnson meta-GGA potential of density functional theory has been shown to be the best exchange-correlation potential to determine band gaps of crystalline solids. However, it cannot be consistently used for the electronic…

Mesoscale and Nanoscale Physics · Physics 2020-04-02 Tomáš Rauch , Miguel A. L. Marques , Silvana Botti

Low temperature quantum corrections to the density of states (DOS) and the conductivity are examined for a two-dimensional(2D) square crystal with substitutional impurities. By summing the leading logarithmic corrections to the DOS its…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 E. P. Nakhmedov , H. Feldmann , R. Oppermann , M. Kumru

We present a systematic first-principles study of substitutional 3d transition-metal (TM) defects in CsPbI3 using the spin-polarized GGA+U framework. TM incorporation is generally energetically favorable and induces lattice distortions that…

Materials Science · Physics 2025-12-18 Misbah Shaheen , Sheharyar Pervez

For closed-shell systems, the local density approximation (LDA) and the LYP, BLYP, and B3LYP functionals are shown to be compatible with reference-state one-particle density-matrix theory, where this recently introduced formalism is based…

Chemical Physics · Physics 2009-11-10 James P. Finley