Related papers: On determining absolute entropy without quantum th…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…
We show that for any perfect fluid in a static spacetime, if the Einstein constraint equation is satisfied and the temperature of the fluid obeys Tolman's law, then the other components of Einstein's equation are implied by the assumption…
A classical (non-quantum-mechanical) relativistic ideal gas in thermodynamic equilibrium in a uniformly accelerated frame of reference is studied using Gibbs's microcanonical and grand canonical formulations of statistical mechanics. Using…
A convenient model for estimating the total entropy ({\Sigma}Si) of atmospheric gases based on physical action is proposed. This realistic approach is fully consistent with statistical mechanics, but uses the properties of translational,…
According to maximum entropy principle, it has been proved that the gravitational field equations could be derived by the extrema of total entropy for perfect fluid, which implies that thermodynamic relations contain information of gravity.…
We consider a question motivated by the third law of thermodynamics: can there be a local temperature arbitrarily close to absolute zero in a nonequilibrium quantum system? We consider nanoscale quantum conductors with the source reservoir…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
This paper is the second part of a previous paper (Marquet, 2019) dealing with the need to define the entropy with an absolute way, by using the third law of thermodynamics. In this second part it is shown that there is a need and interest…
The article reveals the error that in classical thermodynamics leads to the Gibbs paradox. The essence of the error lies in the fact that the entropy of an ideal gas is attributed to additive quantities, but it is not correct. The value of…
Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…
We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…
Using a game theory approach and a new extremal problem, Gibbs formula is proved in a most simple and general way for the classical mechanics case. A corresponding conjecture on the asymptotics of the classical entropy is formulated. For…
The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single…
Evidence implies that basic laws of thermodynamics must be tested by experiments. In this paper, an experiment is designed to measure the entropy of a system with at least one known (measurable) equation of state, especially the gas…
A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…
Thermodynamics is usually developed starting from entropy and the maximum entropy principle. We investigate here to what extent one can replace entropy with relative entropy which has several advantages, for example in the context of local…
The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…
The third law of thermodynamics dictates that the entropy of materials becomes zero as temperature ($T$) approaches zero. Contrarily, glass and other similar materials exhibit nonzero entropy at $T=0$, which contradicts the third law. For…
Typically, the entropy of an isolated system in equilibrium is calculated by counting the number of accessible microstates, or in more general cases by using the Gibbs formula. In irreversible processes entropy spontaneously increases and…