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We theoretically investigate electron energy loss spectroscopy (EELS) of metallic nanoparticles in the optical frequency domain. Using a quasistatic approximation scheme together with a plasmon eigenmode expansion, we show that EELS can be…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Anton Hörl , Andreas Trügler , Ulrich Hohenester

Electron energy-loss spectroscopy (EELS) performed in transmission electron microscopes is shown to directly render the photonic local density of states (LDOS) with unprecedented spatial resolution, currently below the nanometer. Two…

Materials Science · Physics 2012-11-13 F. J. Garcia de Abajo , M. Kociak

Low-loss electron energy loss spectroscopy (EELS) has emerged as a technique of choice for exploring the localization of plasmonic phenomena at the nanometer level, necessitating analysis of physical behaviors from 3D spectral data sets.…

As the continual experimental advances made in Electron energy loss spectroscopy (EELS) and cathodoluminescence (CL) open the door to practical exploitations of plasmonic effects in metal nanoparticles, there is an increasing need for…

Mesoscale and Nanoscale Physics · Physics 2016-05-31 Yu Luo , Matthias Kraft , J. B. Pendry

In the quest for dynamic multimodal probing of a material's structure and functionality, it is critical to be able to quantify the chemical state on the atomic and nanoscale using element specific electronic and structurally sensitive tools…

The inelastic scattering of electrons is one route to study the vibrational and electronic properties of materials. Such experiments, also called electron energy-loss spectroscopy, are particularly useful for the investigation of the…

Materials Science · Physics 2014-06-24 Friedrich Roth , Andreas König , Jörg Fink , Bernd Büchner , Martin Knupfer

Over the last two decades, Electron Energy Loss Spectroscopy (EELS) imaging with a scanning transmission electron microscope (STEM) has emerged as a technique of choice for visualizing complex chemical, electronic, plasmonic, and phononic…

Electron energy loss spectroscopy (EELS) has been established as a powerful analytical technique for investigating the oxidation state, band structure, and dielectric properties of materials with exceptional spatial resolution. Inspired by…

Electron energy loss spectroscopy (EELS) can be used to probe plasmon excitations in nanostructured materials with atomic-scale spatial resolution. For structures smaller than a few nanometers quantum effects are expected to be important,…

Mesoscale and Nanoscale Physics · Physics 2013-01-03 Kirsten Andersen , Karsten W. Jacobsen , Kristian S. Thygesen

Electron microscopy techniques such as electron energy-loss spectroscopy (EELS) facilitate the spatio-spectral characterization of plasmonic nanostructures. In this work, a time-dependent perspective is presented, which significantly…

Understanding light-matter interactions using localized surface plasmons (LSPs) is of fundamental interest in classical and quantum plasmonics and has a wide range of applications. In order to understand the spatial properties of LSPs,…

Mesoscale and Nanoscale Physics · Physics 2016-03-22 Rong-Chun Ge , Stephen Hughes

Time-resolved and ultrafast electron energy-loss spectroscopy (EELS) is an emerging technique for measuring photoexcited carriers, lattice dynamics, and near-fields across femtosecond to microsecond timescales. When performed in either a…

Materials Science · Physics 2025-11-03 Wonseok Lee , Levi D. Palmer , Thomas E. Gage , Scott K. Cushing

Electron microscopy prevalently uses energy-dispersive x-ray spectroscopy (EDS) and electron energy loss spectroscopy (EELS) for elemental analysis. EDS and EELS energy resolutions are commonly between 30-100 eV or 0.01-1 eV, respectively.…

The optical properties of metallic nanoparticles are dominated by localized surface plasmons (LSPs). Their properties only depend on the constituting material, the size and shape of the nano-object as well as its surrounding medium. In…

Electron energy-loss spectroscopy (EELS) can measure similar information to X-ray, UV-Vis, and IR spectroscopies but with atomic resolution and increased scattering cross sections. Recent advances in electron monochromators have expanded…

Chemical Physics · Physics 2024-04-26 Ye-Jin Kim , Levi D. Palmer , Wonseok Lee , Nicholas J. Heller , Scott K. Cushing

Within the MNPBEM toolbox, we show how to simulate electron energy loss spectroscopy (EELS) of plasmonic nanoparticles using a boundary element method approach. The methodology underlying our approach closely follows the concepts developed…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Ulrich Hohenester

Electron energy-loss spectroscopy (EELS) is a powerful tool for imaging chemical variations at the nanoscale. Here, we investigate a polymer/organic small molecule-blend used as absorber layer in an organic solar cell and employ EELS for…

Spatial confinement of matter in functional nanostructures has propelled these systems to the forefront of nanoscience, both as a playground for exotic physics and quantum phenomena and in multiple applications including plasmonics,…

Electron energy loss spectroscopy (EELS) and Cathodoluminescence (CL) play a pivotal role in many of the cutting edge experiments in plasmonics. EELS and CL experiments are usually supported by numerical simulations, which, whilst accurate,…

Mesoscale and Nanoscale Physics · Physics 2016-07-18 Matthias Kraft , Yu Luo , J. B. Pendry

Scanning transmission electron microscopy (STEM) combined with electron energy loss spectroscopy (EELS) has become a standard technique to map localized surface plasmon resonances with a nanometer spatial and a sufficient energy resolution…

Mesoscale and Nanoscale Physics · Physics 2020-06-02 Michal Horák , Tomáš Šikola
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