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In this paper we introduce a new structure similar to the graphane which we call it penta graphane. This structure is obtained by adding hydrogen to penta graphene bond. We study the electronic and phononic structure of penta graphane. We…

Mesoscale and Nanoscale Physics · Physics 2018-06-27 H. Einollahzadeh , R. S. Dariani , S. M. Fazeli

Recently, a new carbon 3D carbon allotrope named pentadiamond was proposed. Pentadiamond is composed of carbon atoms in mixed sp$^2$ and sp$^3$-like hybridization. In this work, we have carried out a detailed investigation of the electronic…

Materials Science · Physics 2021-02-03 Raphael M. Tromer , Levy C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Using systematic evolutionary structure searching we propose a new carbon allotrope, phagraphene, standing for penta-hexa-hepta-graphene, because the structure is composed of 5-6-7 carbon rings. This two-dimensional (2D) carbon structure is…

Materials Science · Physics 2015-09-02 Zhenhai Wang , Xiang-Feng Zhou , Xiaoming Zhang , Qiang Zhu , Huafeng Dong , Mingwen Zhao , Artem R. Oganov

We compare the classification of the electron bands in graphene, obtained by group theory algebra in the framework of tight-binding model (TBM), with that calculated in the density-functional theory (DFT) framework. Identification in the…

Mesoscale and Nanoscale Physics · Physics 2014-05-01 E. Kogan , V. U. Nazarov , V. M. Silkin , M. Kaveh

Penta-graphene is a quasi-two-dimensional carbon allotrope consisting of a pentagonal lattice in which both sp2 and sp3-like carbons are present. Unlike graphene, penta-graphene exhibits a non-zero bandgap, which opens the possibility of…

Density functional theory (DFT) and many body perturbation theory at the G$_0$W$_0$ level are employed to study the electronic properties of polythiophene (PT) adsorbed on graphene surface. Analysis of charge density difference shows the…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 F. Marsusi , I. A. Fedorov , S. Gerivani

A specific structure of doped graphene with substituted silicon impurity is introduced and ab. initio density-functional approach is applied for energy band structure calculation of proposed structure. Using the band structure calculation…

Mesoscale and Nanoscale Physics · Physics 2011-03-01 Mohammad S. Sharif Azadeh , Alireza Kokabi , Mehdi Hosseini , Mehdi Fardmanesh

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

In the present work, first-principles calculations based on the density functional theory (DFT), GW approximation and Bethe-Salpeter equation (BSE) are performed to study the electronic and optical properties of penta-graphene (PG)…

Computational Physics · Physics 2024-01-12 Babak Minaie , Seyed A. Ketabi , José M. De Sousa

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi

Potentially new, single-atom thick semiconducting 2D-graphene-like material, called Anisotropic-cyclicgraphene, have been generated by the two stage searching strategy linking molecular and ab initio approach. The candidate derived from the…

Mesoscale and Nanoscale Physics · Physics 2018-03-20 Marcin Maździarz , Adam Mrozek , Wacław Kuś , Tadeusz Burczyński

Using the GW approximation, we study the electronic structure of the recently synthesized hydrogenated graphene, named graphane. For both conformations, the minimum band gap is found to be direct at the $\Gamma$ point, and it has a value of…

Materials Science · Physics 2015-05-13 S. Lebegue , M. Klintenberg , O. Eriksson , M. I. Katsnelson

The power of polymorphism in carbon is vividly manifested by the numerous applications of carbon-based nano-materials. Ranging from environmental issues to biomedical applications, it has the potential to address many of today's dire…

Materials Science · Physics 2017-03-28 Obaidur Rahaman , Bohayra Mortazavi , Arezoo Dianat , Gianaurelio Cuniberti , Timon Rabczuk

We present a tight-binding parametrization for penta-graphene that correctly describes its electronic band structure and linear optical response. The set of parameters is validated by comparing to ab-initio density functional theory…

Materials Science · Physics 2020-12-25 Sergio Bravo , J. D. Correa , Leonor Chico , M. Pacheco

The advent of graphene has renewed the interest in other 2D carbon-based materials. Bhattacharya and Jana have proposed a new carbon allotrope, composed of different polygonal carbon rings containing 4, 5, 6, and 10 atoms, named…

Materials Science · Physics 2023-05-24 Caique C. Oliveira , Matheus Medina , Douglas S. Galvao , Pedro A. S. Autreto

We determine the band structure of graphene under strain using density functional calculations. The ab-initio band strucure is then used to extract the best fit to the tight-binding hopping parameters used in a recent microscopic model of…

Mesoscale and Nanoscale Physics · Physics 2009-11-08 R. M. Ribeiro , Vitor M. Pereira , N. M. R. Peres , P. R. Briddon , A. H. Castro Neto

Moving beyond traditional 2D materials is now desirable to have switching capabilities (e.g., transistors). Here we propose using graphyne because, as we will show in this letter, obtaining regions of the electronic bandstructure which act…

Materials Science · Physics 2020-12-16 Xianwei Sha , Clifford M. Krowne

The electronic structure in the vicinity of the 1-heptagonal and 1-pentagonal defects in the carbon graphene plane is investigated. Using a continuum gauge field-theory model the local density of states around the Fermi energy is calculated…

Mesoscale and Nanoscale Physics · Physics 2011-12-06 J. Smotlacha , R. Pincak , M. Pudlak

Lacking a band gap largely limits the application of graphene in electronic devices. Previous study shows that grain boundaries (GBs) in polycrystalline graphene can dramatically alter the electrical properties of graphene. Here, we…

Materials Science · Physics 2013-01-11 Jiangtao Wu , Xinghua Shi , Yujie Wei

Carbon-based materials have attracted great attention due to their exceptional structural diversity and wide-ranging applications. Recently, a new two-dimensional carbon allotrope, named pentagraphene (PG), was proposed. In this study, we…

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