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We present an approach to accelerate real-space electronic structure methods several fold, without loss of accuracy, by reducing the dimension of the discrete eigenproblem that must be solved. To accomplish this, we construct an efficient,…

Computational Physics · Physics 2018-05-01 Qimen Xu , Phanish Suryanarayana , John E. Pask

We introduce a practical and efficient approach for calculating the all-electron full potential bandstructure in real space, employing a finite element basis. As an alternative to the k-space method, the method involves the self-consistent…

Materials Science · Physics 2023-07-25 Dongming Li , James Kestyn , Eric Polizzi

We propose a unique scheme to construct fully optimized atomic basis sets for density-functional calculations. The shapes of the radial functions are optimized by minimizing the {\it spillage} of the wave functions between the atomic…

Materials Science · Physics 2015-05-19 Mohan Chen , G-C Guo , Lixin He

We present a mixed basis-set approach to obtain optical absorption spectra within a generalized Kohn-Sham time-dependent density functional theory framework. All occupied valence molecular orbitals (MOs) are expanded in a plane-wave (PW)…

Chemical Physics · Physics 2025-08-13 Kyle Chen , Barry Y. Li , Tucker Allen , Daniel Neuhauser

We apply reduced density-matrix functional theory to the parabolically confined quantum Hall droplet in the spin-frozen strong magnetic field regime. One-body reduced density matrix functional method performs remarkably well in obtaining…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 E. Tölö , A. Harju

B-spline functions have been widely used in computational atomic physics. Different from the traditional B-spline basis (a simple product of two B-splines), the recently developed correlated B-spline basis functions(C-BSBF), in which the…

Atomic Physics · Physics 2023-01-16 Hao Fang , Yong-Hui Zhang , Pei-Pei Zhang , Ting-Yun Shi

Previous studies have used numerical methods to optimize the hyperpolarizability of a one-dimensional quantum system. These studies were used to suggest properties of one-dimensional organic molecules, such as the degree of modulation of…

Optics · Physics 2015-05-18 Urszula B. Szafruga , Mark G. Kuzyk , David S. Watkins

In areas such as kernel smoothing and non-parametric regression there is emphasis on smooth interpolation and smooth statistical models. Splines are known to have optimal smoothness properties in one and higher dimensions. It is shown, with…

Computation · Statistics 2008-09-29 Ron A. Bates , Hugo Maruri-Aguilar , Henry P. Wynn

We present a method which enables solid-state density functional theory calculations to be applied to systems of almost unlimited size. Computations of physical effects up to the micron length scale but which nevertheless depend on the…

Materials Science · Physics 2021-01-04 Tristan Müller , Sangeeta Sharma , E. K. U. Gross , J. K. Dewhurst

We present an efficient scheme for representing many-body wavefunctions in quantum Monte Carlo (QMC) calculations. The scheme is based on B-splines (blip functions), which consist of localized cubic splines centred on the points of a…

Materials Science · Physics 2016-08-16 D. Alfè , M. J. Gillan

Strongly interacting one-dimensional (1D) Bose-Fermi mixtures form a tunable XXZ spin chain. Within the spin-chain model developed here, all properties of these systems can be calculated from states representing the ordering of the bosons…

Quantum Gases · Physics 2017-04-25 F. Deuretzbacher , D. Becker , J. Bjerlin , S. M. Reimann , L. Santos

The non-relativistic static and dynamic dipole polarizabilities of hydrogen atom experiencing a cylindrical confinement are investigated. Two methods based on B-Splines are used for the computations of the energies and wavefunctions. The…

Atomic Physics · Physics 2013-08-15 S. A. Ndengué , O. Motapon , R. L. Melingui Melono , A. J. Etindele

This paper investigates a computational strategy for studying the interactions between multiple through-the-width delaminations and global or local buckling in composite laminates taking into account possible contact between the delaminated…

Numerical Analysis · Mathematics 2012-09-03 Karin Saavedra , Olivier Allix , Pierre Gosselet

A system of electrons in a local or nonlocal external potential can be studied with 1-matrix functional theory (1MFT), which is similar to density functional theory (DFT) but takes the one-particle reduced density matrix (1-matrix) instead…

Strongly Correlated Electrons · Physics 2008-07-23 Ryan Requist , Oleg Pankratov

This paper presents an immersed, isogeometric finite element framework to predict the response of multi-material, multi-physics problems with complex geometries using locally refined discretizations. To circumvent the need to generate…

Numerical Analysis · Mathematics 2022-12-05 Mathias Schmidt , Lise Noel , Keenan Doble , John A. Evans , Kurt Maute

We present an efficient approach for simulating Coulomb systems confined by planar polarizable surfaces. The method is based on the solution of Poisson equation using periodic Green functions. It is shown that the electrostatic energy…

Soft Condensed Matter · Physics 2017-12-12 Alexandre P. dos Santos , Matheus Girotto , Yan Levin

When described through a plane-wave basis set, the inclusion of exact nonlocal exchange in hybrid functionals gives rise to a singularity, which slows down the convergence with the density of sampled $k$ points in reciprocal space. In this…

Materials Science · Physics 2009-09-10 Peter Broqvist , Audrius Alkauskas , Alfredo Pasquarello

We present a local density approximation (LDA) for one-dimensional (1D) systems interacting via the soft-Coulomb interaction based on quantum Monte-Carlo calculations. Results for the ground-state energies and ionization potentials of…

Strongly Correlated Electrons · Physics 2015-05-27 N. Helbig , J. I. Fuks , M. Casula , M. J. Verstraete , M. A. L. Marques , I. V. Tokatly , A. Rubio

An interacting lattice model describing the subspace spanned by a set of strongly-correlated bands is rigorously coupled to density functional theory to enable ab initio calculations of geometric and topological material properties. The…

Strongly Correlated Electrons · Physics 2019-03-26 Ryan Requist , E. K. U. Gross

Functional data analysis is typically performed in two steps: first, functionally representing discrete observations, and then applying functional methods to the so-represented data. The initial choice of a functional representation may…

Applications · Statistics 2024-05-15 Rani Basna , Hiba Nassar , Krzysztof Podgórski