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We derive a variational expression for the correlation time of physical observables in steady-state diffusive systems. As a consequence of this variational expression, we obtain lower bounds on the correlation time, which provide speed…

Statistical Mechanics · Physics 2023-03-24 Andreas Dechant , Jerome Garnier-Brun , Shin-ichi Sasa

A simple expression for the non-equilibrium distribution function in ultra-fast transient processes is proposed. Postulating its dependence on temporal derivatives of the equilibrium integrals of motion, non-equilibrium analogues of the…

Statistical Mechanics · Physics 2025-02-18 K. S. Glavatskiy

Using simulations of glassy systems under steady-state shear, we compare effective temperatures obtained from static linear response with those from time-dependent fluctuation-dissipation relations. Although these two definitions are not…

Soft Condensed Matter · Physics 2009-11-10 C. S. O'Hern , A. J. Liu , S. R. Nagel

Formation of the nonequilibrium subsystem in dynamical processes during defect generation is simulated by means of molecular dynamics. A particular process of dissipation of the low-frequency acoustic emission into high-frequency…

Computational Physics · Physics 2009-12-11 Leonid S. Metlov

The temperature in the transient climate response is lower than the equilibrium temperature for the same amount of forcing. The degree of disequilibrium is not constant in time and depends on various climate parameters. We derive intuition…

Atmospheric and Oceanic Physics · Physics 2026-03-03 Boriana Chtirkova

The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy…

Statistical Mechanics · Physics 2009-11-13 Alex V. Popov , Rigoberto Hernandez

We deal with a system of two coupled differential equations, describing the evolution of a first order phase transition. In particular, we have two non-linear parabolic equations: the first one is deduced from a balance law for entropy and…

Analysis of PDEs · Mathematics 2011-07-19 Manuela Girotti

Physical systems that power motion and create structure in a fixed amount of time dissipate energy and produce entropy. Whether living or synthetic, systems performing these dynamic functions must balance dissipation and speed. Here, we…

Statistical Mechanics · Physics 2020-12-18 Schuyler B. Nicholson , Luis Pedro Garcia-Pintos , Adolfo del Campo , Jason R. Green

In this article, we study a thermodynamically consistent thermo-visco-elastic model describing the balance of internal energy in a heat-conducting inelastic body. In the considered problem, the temperature dependence appears in both the…

Analysis of PDEs · Mathematics 2025-11-13 Tomasz Cieślak , Sebastian Owczarek , Karolina Wielgos

The second law of thermodynamics states that entropy production in macroscopic systems is non-negative, reaching zero only at thermodynamic equilibrium. As a corollary, this implies that the state trajectory of macroscopic systems is…

Statistical Mechanics · Physics 2025-01-30 O. Politano , Alejandro L. Garcia , F. Baras , M. Malek Mansour

This work extends the results of the recently developed theory of a rather complete thermodynamic formalism for discrete-state, continuous-time Markov processes with and without detailed balance. We aim at investigating the question that…

Statistical Mechanics · Physics 2011-05-30 Moises Santillan , Hong Qian

We define the heat capacity for steady periodically driven systems and as an example we compute it for dissipative two-level systems where the energy gap is time-modulated. There, as a function of ambient temperature, the Schottky peak…

Statistical Mechanics · Physics 2024-08-27 Elena Rufeil Fiori , Christian Maes

Thermal gradients lead to macroscopic fluid motion if a confining surface is present along the gradient. This fundamental nonequilibrium effect, known as thermo-osmosis, is held responsible for particle thermophoresis in colloidal…

Statistical Mechanics · Physics 2019-07-17 Pietro Anzini , Gaia Maria Colombo , Zeno Filiberti , Alberto Parola

A Hamiltonian-based model of many harmonically interacting massive particles that are subject to linear friction and coupled to heat baths at different temperatures is used to study the dynamic approach to equilibrium and non-equilibrium…

Statistical Mechanics · Physics 2020-09-17 Roland R. Netz

Recently, Kawai, Parrondo, and Van den Broeck have related dissipation to time-reversal asymmetry. We generalized the result by considering a protocol where the physical system is driven away from an initial thermal equilibrium state with…

Statistical Mechanics · Physics 2015-05-20 Pegah Zolfaghari , Somayeh Zare , Behrouz Mirza

We study the thermodynamic cost associated with driving systems between different non-equilibrium steady states. In particular, we combine a linear-response framework for non-equilibrium Markov systems with Lagrangian techniques to minimize…

Statistical Mechanics · Physics 2025-06-18 Dana Kamp , Karel Proesmans

Using very long molecular dynamics simulation runs, temperature protocols spanning up to five orders of magnitude in time-scales are performed to investigate thermally activated structural relaxation in a model amorphous solid. The…

Materials Science · Physics 2017-10-11 P. M. Derlet , R. Maass

The fluctuation-dissipation-theorem connects equilibrium to mildly (linearly) perturbed situations in a thermodynamic manner: It involves the observable of interest and the entropy production caused by the perturbation. We derive a relation…

Statistical Mechanics · Physics 2021-03-24 Tristan Holsten , Matthias Krüger

Constitutive equations are proposed for the relaxation of a glassy material in contact with a thermal reservoir. The dynamics of a single state variable, identified as an effective temperature accounts for the emergence of glassy behavior…

Disordered Systems and Neural Networks · Physics 2016-08-16 Anaël Lemaître

A definition of the thermodynamic entropy based on the time-dependent probability distribution of the macroscopic variables is developed. When a constraint in a composite system is released, the probability distribution for the new…

Statistical Mechanics · Physics 2016-11-23 Robert H. Swendsen