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We study the existence and stability of stationary solutions of Poisson-Nernst- Planck equations with steric effects (PNP-steric equations) with two counter-charged species. These equations describe steady current through open ionic…

Analysis of PDEs · Mathematics 2018-01-26 Nir Gavish

In situations involving large potentials or surface charges, the Poisson Boltzman(PB) equation has shortcomings because it neglects ion-ion interactions and steric effects. This has been widely recognized by the electrochemistry community,…

Chemical Physics · Physics 2007-05-23 Mustafa Sabri Kilic , Martin Z. Bazant , Armand Ajdari

In this work, we numerically study linear stability of multiple steady-state solutions to a type of steric Poisson--Nernst--Planck (PNP) equations with Dirichlet boundary conditions, which are applicable to ion channels. With numerically…

Computational Physics · Physics 2020-12-02 Jie Ding , Hui Sun , Shenggao Zhou

Effective Poisson-Nernst-Planck (PNP) equations are derived for macroscopic ion transport in charged porous media under periodic fluid flow by an asymptotic multi-scale expansion with drift. The microscopic setting is a two-component…

Mathematical Physics · Physics 2014-07-16 Markus Schmuck , Martin Z. Bazant

Experiments measuring currents through single protein channels show unstable currents. Channels switch between 'open' or 'closed' states in a spontaneous stochastic process called gating. Currents are either (nearly) zero or at a definite…

Analysis of PDEs · Mathematics 2015-06-11 Tai-Chia Lin , Bob Eisenberg

A transient Poisson-Nernst-Planck system with steric effects is analyzed in a bounded domain with no-flux boundary conditions for the ion concentrations and mixed Dirichlet-Neumann boundary conditions for the electric potential. The steric…

Analysis of PDEs · Mathematics 2024-11-27 Peter Hirvonen , Ansgar Jüngel

The Poisson-Nernst-Planck equations with generalized Frumkin-Butler-Volmer boundary conditions (PNP-FBV) describe ion transport with Faradaic reactions and have applications in a wide variety of fields. Using an adaptive time-stepper based…

Numerical Analysis · Mathematics 2020-06-24 M. C. Pugh , D. Yan , F. P. Dawson

The Poisson-Nernst-Planck (PNP) system is a standard model for describing ion transport. In many applications, e.g., ions in biological tissues, the presence of thin boundary layers poses both modelling and computational challenges. In this…

Biological Physics · Physics 2018-09-12 Zilong Song , Xiulei Cao , Huaxiong Huang

Ion transport, often described by the Poisson--Nernst--Planck (PNP) equations, is ubiquitous in electrochemical devices and many biological processes of significance. In this work, we develop conservative, positivity-preserving, energy…

Numerical Analysis · Mathematics 2020-07-15 Jie Ding , Zhongming Wang , Shenggao Zhou

The steady-state Poisson-Nernst-Planck (ssPNP) equations are an effective model for the description of ionic transport in ion channels. It is observed that an ion channel exhibits voltage-dependent switching between open and closed states.…

Numerical Analysis · Mathematics 2017-11-17 Jie Ding , Hui Sun , Zhongming Wang , Shenggao Zhou

This work considers charged systems described by the modified Poisson--Nernst--Planck (PNP) equations, which incorporate ionic steric effects and the Born solvation energy for dielectric inhomogeneity. Solving the steady-state modified PNP…

Numerical Analysis · Mathematics 2025-06-04 Zhonghua Qiao , Zhenli Xu , Qian Yin , Shenggao Zhou

When ions are crowded, the effect of steric repulsion between ions becomes significant and the conventional Poisson--Boltzmann (PB) equation (without steric effect) should be modified. For this purpose, we study the asymptotic limit of…

Analysis of PDEs · Mathematics 2022-05-26 Jhih-Hong Lyu , Tai-Chia Lin

In this research, we explore how permanent charges affect the movement of ionic currents through ion channels. We use a quasi-one-dimensional classical Poisson-Nernst-Planck (PNP) model to study two types of ions, one positively charged and…

Dynamical Systems · Mathematics 2023-12-29 Hamid Mofidi

In this paper, we study the Poisson stability (in particular, stationarity, periodicity, quasi-periodicity, Bohr almost periodicity, almost automorphy, recurrence in the sense of Birkhoff, Levitan almost periodicity, pseudo periodicity,…

Dynamical Systems · Mathematics 2017-11-28 David Cheban , Zhenxin Liu

We propose a modified Poisson-Nernst-Planck (PNP) model to investigate charge transport in electrolytes of inhomogeneous dielectric environment. The model includes the ionic polarization due to the dielectric inhomogeneity and the ion-ion…

Computational Physics · Physics 2015-06-19 Zhenli Xu , Manman Ma , Pei Liu

The Poisson-Nernst-Planck (PNP) equations are fundamental for modeling ion transport in electrochemical systems, capturing the intricate interplay of concentration gradients, electric fields, and ion fluxes essential for applications such…

Chemical Physics · Physics 2025-01-13 Yitao He , Dan Zhao

The reduced 1D Poisson-Nernst-Planck (PNP) model of artificial nanopores in the presence of a permanent charge on the channel wall is studied. More specifically, we consider the limit where the channel length exceed much the Debye screening…

Chemical Physics · Physics 2008-11-23 I. D. Kosińska , I. Goychuk , M. Kostur , G. Schmid , P. Hänggi

Many models of physical systems, such as mechanical and electrical networks, exhibit algebraic constraints that arise from subsystem interconnections and underlying physical laws. Such systems are commonly formulated as…

Systems and Control · Electrical Eng. & Systems 2026-01-26 N. Hagelaars , G. J. E. van Otterdijk , S. Moradi , R. Tóth , N. O. Jaensson , M. Schoukens

PDEs with periodic boundary conditions are frequently used to model processes in large spatial environments, assuming solutions to extend periodically beyond some bounded interval. However, solutions to these PDEs often do not converge to a…

Analysis of PDEs · Mathematics 2025-09-04 Declan Jagt , Sergei Chernyshenko , Matthew Peet

An integral equation method is presented for the 1D steady-state Poisson-Nernst-Planck equations modeling ion transport through membrane channels. The differential equations are recast as integral equations using Green's 3rd identity…

Numerical Analysis · Mathematics 2023-04-11 Zhen Chao , Weihua Geng , Robert Krasny
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