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Understanding and computing the entropic forces exerted by polymer chains under confinement is important for many reasons, from research to applications. However, extracting properties related to the free energy, such as the force (or…

Soft Condensed Matter · Physics 2025-07-08 Marcio S. Gomes-Filho , Eugene M. Terentjev

In this article we study a \emph{non-directed polymer model} on $\mathbb Z$, that is a one-dimensional simple random walk placed in a random environment. More precisely, the law of the random walk is modified by the exponential of the sum…

Probability · Mathematics 2022-10-13 Quentin Berger , Chien-Hao Huang , Niccolo Torri , Ran Wei

We study a directed polymer model in a random environment on infinite binary trees. The model is characterized by a phase transition depending on the inverse temperature. We concentrate on the asymptotics of the partition function in the…

Probability · Mathematics 2012-05-04 Tom Alberts , Marcel Ortgiese

The crystallisation of entangled polymers from their melt is investigated using computer simulation with a coarse-grained model. Using hybrid Monte Carlo simulations enables us to probe the behaviour of long polymer chains. We identify…

Soft Condensed Matter · Physics 2020-06-12 Xiaoliang Tang , Fucheng Tian , Tingyu Xu , Liangbin Li , Aleks Reinhardt

Monte Carlo simulations are used to study the behavior of two polymers under confinement in a cylindrical tube. Each polymer is modeled as a chain of hard spheres. We measure the free energy of the system, F, as a function of the distance…

Soft Condensed Matter · Physics 2015-06-22 James M. Polson , Logan G. Montgomery

Monte Carlo simulations are used to study the conformational properties of a folded semiflexible polymer confined to a long channel. We measure the variation in the conformational free energy with respect to the end-to-end distance of the…

Soft Condensed Matter · Physics 2018-09-05 James M. Polson

We study a heteropolymer model with random contact interactions introduced some time ago as a simplified model for proteins. The model consists of self-avoiding walks on the simple cubic lattice, with contact interactions between nearest…

Soft Condensed Matter · Physics 2009-10-31 Ugo Bastolla , Peter Grassberger

In this paper we study a two-dimensional directed self-avoiding walk model of a random copolymer in a random emulsion. The copolymer is a random concatenation of monomers of two types, $A$ and $B$, each occurring with density 1/2. The…

Probability · Mathematics 2009-11-13 Frank den Hollander , Nicolas Pétrélis

We investigate by Monte Carlo simulations the zipping and unzipping dynamics of two polymers connected by one end and subject to an attractive interaction between complementary monomers. In zipping, the polymers are quenched from a high…

Soft Condensed Matter · Physics 2011-02-15 Alessandro Ferrantini , Enrico Carlon

Studies of the thermodynamics of complex coacervation of pairs of symmetric, strongly ionizable, oppositely charged polyelectrolyte chains are abundant. To generalize such understanding to asymmetric chain lengths and variable ionizability…

Soft Condensed Matter · Physics 2023-06-07 Souradeep Ghosh , Soumik Mitra , Arindam Kundagrami

We describe method to discuss thermodynamics of a defected semi-flexible homo-polymer chain in the two and three dimensions using fully directed self-avoiding walk lattice model. The defects are located along a line and these defects are…

Soft Condensed Matter · Physics 2020-11-23 Pramod Kumar Mishra

Taking into account the nonequivalence of fixed-force and fixed-length ensembles in the weak-force regime, equations of state are derived that describe the equilibrium extension or compression of an ideal Gaussian polymer chain in response…

Soft Condensed Matter · Physics 2007-05-23 Richard M. Neumann

We study the unfolding of a single polymer chain due to an external force. We use a simplified model which allows to perform all calculations in closed form without assuming a Boltzmann-Gibbs form for the equilibrium distribution.…

Statistical Mechanics · Physics 2009-11-13 Erik Van der Straeten , Jan Naudts

How accurate is pair additivity in describing interactions between soft polymer-based nanoparticles? Using numerical simulations we compute the free energy cost required to overlap multiple chains in the same region of space, and provide a…

Soft Condensed Matter · Physics 2015-06-03 Katherine Klymko , Angelo Cacciuto

We study the $1+1$-dimensional random directed polymer problem, i.e., an elastic string $\phi(x)$ subject to a Gaussian random potential $V(\phi,x)$ and confined within a plane. We mainly concentrate on the short-scale and…

Disordered Systems and Neural Networks · Physics 2015-05-19 V. S. Dotsenko , V. B. Geshkenbein , D. A. Gorokhov , G. Blatter

In this paper we present a new and flexible method to show that, in one dimension, various self-repellent random walks converge to self-repellent Brownian motion in the limit of weak interaction after appropriate space-time scaling. Our…

Probability · Mathematics 2007-05-23 R. van der Hofstad , F. den Hollander , W. Koenig

In this note we give upper bounds for the free energy of discrete polymers in random media. The bounds are given by the so-called generalized multiplicative cascades from the statistical theory of turbulence. For the polymer model, we…

Probability · Mathematics 2007-05-23 Francis Comets , Vincent Vargas

Consider directed polymers in a random environment on the complete graph of size $N$. This model can be formulated as a product of i.i.d. $N\times N$ random matrices and its large time asymptotics is captured by Lyapunov exponents and the…

Probability · Mathematics 2018-01-22 Francis Comets , Gregorio R. Moreno Flores , Alejandro F. Ramirez

We study energy relaxation in a phenomenological model for polymer built from rheological considerations: a one dimensional nonlinear lattice with dissipative couplings. These couplings are well known in polymer's community to be possibly…

Statistical Mechanics · Physics 2009-11-07 F. Gobet , S. Ciliberto , T. Dauxois

We suggest a theoretical description of the force-induced translocation dynamics of a polymer chain through a nanopore. Our consideration is based on the tensile (Pincus) blob picture of a pulled chain and the notion of propagating front of…

Soft Condensed Matter · Physics 2012-04-17 J. L. A. Dubbeldam , V. G. Rostiashvili , A. Milchev , T. A. Vilgis