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A complete solution to the inverse problem of Kohn-Sham (KS) density functional theory is proposed. Our method consists of two steps. First, the effective KS potential is determined from the ground state density of a given system. Then, the…

Nuclear Theory · Physics 2022-03-14 A. Liardi , F. Marino , G. Colò , X. Roca-Maza , E. Vigezzi

We present a first-principles framework to extract deformation potentials in Silicon based on density-functional theory (DFT) and density-functional perturbation theory (DFPT). We compute the electronic band structures, phonon dispersion…

Materials Science · Physics 2021-11-05 Zhen Li , Patrizio Graziosi , Neophytos Neophytou

The coefficients of interatomic potential of simple form Exp-6 for neon are obtained. Repulsive part is calculated ab-initio in the Hartree-Fock approximation using the basis of atomic orbitals orthogonalized exactly on different lattice…

Chemical Physics · Physics 2007-05-23 Yu. V. Eremeichenkova , L. S. Metlov , A. F. Morozov

Aiming to combine density functional theory (DFT) and wavefunction theory, we study a mapping from the many-body interacting system to an effectively-interacting Kohn-Sham system instead of a non-interacting Kohn-Sham system. Because a…

Chemical Physics · Physics 2020-02-19 Shunsuke A. Sato , Angel Rubio

We describe a method of solving the nuclear Skyrme-Hartree-Fock problem by using a deformed Cartesian harmonic oscillator basis. The complete list of expressions required to calculate local densities, total energy, and self-consistent…

Nuclear Theory · Physics 2009-10-30 J. Dobaczewski , J. Dudek

A discrete Hubbard-Stratonovich transformation is presented for systems with an orbital degeneracy $N$ and a Hubbard Coulomb interaction without multiplet effects. An exact transformation is obtained by introducing an external field which…

Strongly Correlated Electrons · Physics 2009-10-30 O. Gunnarsson , E. Koch

We establish a condition for obtaining nonsingular potentials using the Cox-Thompson inverse scattering method with one phase shift. The anomalous singularities of the potentials are avoided by maintaining unique solutions of the underlying…

Mathematical Physics · Physics 2011-11-28 Tamas Palmai , Barnabas Apagyi

A method for constructing semianalytical strongly correlated wave functions for single and molecular quantum dots is presented. It employs a two-step approach of symmetry breaking at the Hartree-Fock level and of subsequent restoration of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Constantine Yannouleas , Uzi Landman

A simple algebraic technique is developed to obtain deformed energy spectra for the P\"oschl-Teller potentials.

High Energy Physics - Theory · Physics 2016-08-15 Abilio De Freitas , Sebastián Salamó

We introduce affordable computational strategies for calculating orbital and pair-orbital energies in atomic and molecular systems. Our methods are based on the pair Coupled Cluster Doubles (pCCD) ansatz and its orbital-optimized variant.…

Chemical Physics · Physics 2025-02-06 Seyedehdelaram Jahani , Somayeh Ahmadkhani , Katharina Boguslawski , Paweł Tecmer

We have performed self-consistent calculations for first and second row atoms using a variant of density-functional theory, the optimized effective potential method, with an approximation due to Krieger, Li and Iafrate and a…

chem-ph · Physics 2009-10-28 Tobias Grabo , E. K. U. Gross

An extrapolation method in shell model calculations with deformed basis is presented, which uses a scaling property of energy and energy variance for a series of systematically approximated wave functions to the true one. Such approximated…

Nuclear Theory · Physics 2009-11-10 Takahiro Mizusaki

In this letter the conceptual and computational implications of the Hartree product type nuclear wavefunction introduced recently within the context of the ab initio non-Born-Oppenheimer Nuclear-electronic orbital (NEO) methodology are…

Chemical Physics · Physics 2016-10-31 Masumeh Gharabaghi , Shant Shahbazian

A two-parameter extension of the density-scaled double hybrid approach of Sharkas et al. [J. Chem. Phys. 134, 064113 (2011)] is presented. It is based on the explicit treatment of a fraction of multideterminantal exact exchange. The…

Chemical Physics · Physics 2012-01-12 Emmanuel Fromager

A direct orbital optimization method is presented for density functional calculations of excited electronic states using either a real space grid or a plane wave basis set. The method is variational, provides atomic forces in the excited…

Computational Physics · Physics 2022-11-09 Aleksei V. Ivanov , Gianluca Levi , Elvar Ö. Jónsson , Hannes Jónsson

We compute the isotope shifts of the \emph{total} electron binding energy of neutral atoms and singly charged ions up to element $Z=120$, using relativistic Hartree-Fock method including the Breit interaction. Field shift coefficients are…

Atomic Physics · Physics 2025-07-30 V. A. Dzuba , V. V. Flambaum

In our work we construct a Hamiltonian, whose eigenstates approximate the solutions of the self-consistent Hartree-Fock equations for nonrelativistic atoms and ions. Its eigenvalues are given by completely algebraic expressions and the…

Quantum Physics · Physics 2025-06-18 N. Q. San , O. D. Skoromnik , V. V. Triguk , I. D. Feranchuk

A recent study of Mejia-Rodriguez and Trickey [Phys. Rev. A 96, 052512 (2017)] showed that the deorbitalization procedure (replacing the exact Kohn-Sham kinetic-energy density by an approximate orbital-free expression) applied to…

Materials Science · Physics 2018-10-10 Fabien Tran , Péter Kovács , Leila Kalantari , Georg K. H. Madsen , Peter Blaha

We extensively develop a method of implementing mean-field calculations for deformed nuclei, using the Gaussian expansion method (GEM). This GEM algorithm has the following advantages: (i) it can efficiently describe the energy-dependent…

Nuclear Theory · Physics 2008-11-26 H. Nakada

An algorithm$^{\ref{Fig1}}$ has been developed with the purpose of obtaining inverse potentials, where the Riccati-type non-linear differential equation, also called phase equation, has been kept in tandem with the Variational Monte Carlo…

Nuclear Theory · Physics 2024-04-09 Anil Khachi , Shikha Awasthi , Lalit Kumar , O. S. K. S Sastri