Related papers: A universal chemical potential for sulfur vapours
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly…
Sulphur is an important, volatile alpha element but its role in the Galactic chemical evolution is still uncertain. We derive the S abundances in RGB stars in three Galactic globular clusters (GC) that cover a wide metallicity range…
Sulphur-bearing species are often used to probe the evolution of hot cores since their abundances are particularly sensitive to physical and chemical variations. However, the chemistry of sulphur is not well understood in these regions,…
We carefully consider numerous explanations for the sulfur abundance anomaly in planetary nebulae. No one rationale appears to be satisfactory, and we suggest that the ultimate explanation is likely to be a heretofore unidentified feature…
A model for the bonding of hypervalent molecules containing sulfur is presented using generalized valence bond wavefunctions. To delineate the model from more commonly used DFT and delocalized wavefunctions, we present detailed comparisons…
The ${\rm H_{5}S_{2}}$ and ${\rm H_{2}S}$ compounds are the two candidates for the low-temperature phase of compressed sulfur-hydrogen system. We have shown that the value of Coulomb pseudopotential ($\mu^{\star}$) for ${\rm H_{5}S_{2}}$…
Acoustical measurements, electron spin resonance, and Raman spectroscopy have been employed to probe sulfur over the temperature range 80 to 180 C, which includes the polymerization transition and the supercooled liquid state. Acoustical…
We theoretically give an infinite number of metastable crystal structures for the superconducting sulfur hydride H$_{x}$S under pressure. It has been thought that theoretically predicted structures of H$_{2}$S and H$_{3}$S exhibit low and…
High pressure serves as a path finding tool towards novel structures, including those with very high Tc.The superconductivity in sulfur hydrides with record value (203 K) is caused by the phonon mechanism. However, the picture differs from…
It is demonstrated that resistive transition at 203 K observed in metallic sulfur hydride system at high pressure can be magnetic (rather than superconducting (SC)) in nature. The onset temperature of genuine superconducting transition in…
Remarkable feature of the phase diagram of sulfur hydrides is a sharp increase in critical temperature from 120K up to200K. This increase is a signature of the structural transition. The study described below is concerned with the nature of…
The thermodynamics framework of an interacting quantum gas trapped by an arbitrary external potential is reviewed. We show that for each confining potential, in the thermodynamic limit, there emerge "generalized" volume and pressure…
The recent reports on high-temperature superconductivity above 190 K in hydrogen sulfide at 200 GPa pressure, exceeding all previously discovered superconductors, has greatly invigorated the interest in dense hydrogen-rich solids. In this…
We report exact numerical calculation of chemical potential, condensate fraction and specific heat of $N$ non-interacting bosons confined in an isotropic harmonic oscillator trap in one, two and three dimensions, as also for interacting…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial…
In 'supersingular' scattering the potential $g^2U_A(r)$ involves a variable nonlinear parameter $A$ upon the increase of which the potential also increases beyond all limits everywhere off the origin and develops a uniquely high level of…
Influence of the temperature dependent chemical potential on the condensation energy from a ternary Boson-Fermion model of superconductivity is reported, it consist of unbound electrons/holes which are fermions plus two-electron and…
Transition metals dichalcogenides (TMDs) are an emergent class of low-dimensional materials with growing applications in the field of nanoelectronics. However, efficient methods for synthesizing large mono-crystals of these systems are…
The newfound ability to detect SO2 in exoplanet atmospheres presents an opportunity to measure sulfur abundances and so directly test between competing modes of planet formation. In contrast to carbon and oxygen, whose dominant molecules…
Internal energies, enthalpies, phonon dispersion curves, and superconductivity of atomic metallic hydrogen are calculated. The (standard) use pseudopotentials in density-functional theory are compared with full (Coulomb)-potential…