Related papers: A proposed chemical scheme for HCCO formation in c…
The formation of complex organic molecules in the interstellar medium (ISM) is central to astrochemistry and prebiotic chemistry, as these species may act as precursors to biomolecules essential for life. Although glyceraldehyde…
It has been suggested that the dark halos of galaxies are constituted by cloudlets of cold (< 10 K) H_2 and dense (> 10^7$ cm^{-3}) molecular gas. Such gas is extremely difficult to detect, because the classical tracers of molecular gas, CO…
Carbon dioxide (CO$_2$) is one of the most important interstellar molecules. While it is considered that it forms on the surface of interstellar dust grains, the exact contribution of different chemical mechanisms is still poorly…
We present Jansky Very Large Array observations of 20 - 37 GHz absorption lines from nearby Galactic diffuse molecular gas seen against four cosmologically-distant compact radio continuum sources. The main new observational results are that…
We observed OH, H$_2$O, HN$_3$, C$^{18}$O, and C$_I$ towards the +50 km/s cloud (M-0.02-0.07), the CND and the +20 km/s (M-0.13-0.08) cloud in the Sgr A complex with the VLA, Odin and SEST. Strong OH absorption, H$_2$O emission and…
Little is known about the chemistry of isocyanates (compounds with the functional group R-N=C=O) in the interstellar medium, as only four of them have been detected so far: isocyanate radical (NCO), isocyanic acid (HNCO), N-protonated…
Massive molecular clumps fragment into cores where star formation takes place, hence star-forming studies should be done at different spatial scales. Using near-IR data obtained with Gemini, data of CH3OCHO and CH3CN from the ALMA database,…
Hydroxylamine (NH2OH) is one of the potential precursors of complex pre-biotic species in space. Here we present a detailed experimental study of hydroxylamine formation through nitric oxide (NO) surface hydrogenation for astronomically…
We report the detection of the oxygen-bearing complex organic molecules propenal (C2H3CHO), vinyl alcohol (C2H3OH), methyl formate (HCOOCH3), and dimethyl ether (CH3OCH3) toward the cyanopolyyne peak of the starless core TMC-1. These…
Ethanolamine (NH2CH2CH2OH) has recently been identified in the molecular cloud G+0.693-0.027, situated in the SgrB2 complex in the Galactic center. However, its presence in other regions, and in particular in star-forming sites, is still…
The Herschel Space Observatory's recent detections of water vapor in the cold, dense cloud L1544 allow a direct comparison between observations and chemical models for oxygen species in conditions just before star formation. We explain a…
We examine several different simplified approaches for modelling the chemistry of CO in three-dimensional numerical simulations of turbulent molecular clouds. We compare the different models both by looking at the behaviour of integrated…
We present synthetic line observations of a simulated molecular cloud, utilising a self-consistent treatment of the dynamics and time-dependent chemical evolution. We investigate line emission from the three most common CO isotopologues…
Massive young stellar objects in the Magellanic Clouds show infrared absorption features corresponding to significant abundances of CO, CO$_2$ and H$_2$O ice along the line of sight, with the relative abundances of these ices differing…
Formaldehyde is a key precursor in the formation routes of many complex organic molecules (COMs) in space. It is also an intermediate step in CO hydrogenation sequence that leads to methanol formation on the surface of interstellar grains…
We report a sensitive search for the rotational transitions of the carbon chain alcohol HC4OH in the frequency range of 21.2-46.7 GHz in the star-forming region L1527 and the dark cloud TMC-1. The motivation was laboratory detection of…
We present high-spatial-resolution (0.7 to 1.0 arcsec) submillimeter observations of continuum and molecular lines of CH3OCHO, CH3OCH3, and H2CCO toward 11 high-mass star-forming regions using the Atacama Large Millimetre/submillimetre…
Context: Dark cloud chemical models usually predict large amounts of O2, often above observational limits. Aims: We investigate the reason for this discrepancy from a theoretical point of view, inspired by the studies of Jenkins and Whittet…
The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a…
We present the first identification in interstellar space of the thioformyl radical (HCS) and its metastable isomer HSC. These species were detected toward the molecular cloud L483 thanks to observations carried out with the IRAM 30m…