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We compare two theoretical approaches to dielectric diblock copolymer melts in an external electric field. The first is a relatively simple analytic expansion in the relative copolymer concentration, and includes the full electrostatic…

Soft Condensed Matter · Physics 2012-01-31 Yoav Tsori , David Andelman , Chin-Yet Lin , M. Schick

We demonstrated theoretically that the renormalization of the electron energy spectrum near the Dirac point of graphene by a strong high-frequency electromagnetic field (dressing field) drastically depends on polarization of the field.…

Mesoscale and Nanoscale Physics · Physics 2016-02-04 K. Kristinsson , O. V. Kibis , S. Morina , I. A. Shelykh

It has been revealed by mean-field theories and computer simulations that the nature of the collapse transition of a polymer is influenced by its bending stiffness $\epsilon_{\rm b}$. In two dimensions, a recent analytical work demonstrated…

Soft Condensed Matter · Physics 2009-11-13 Jie Zhou , Zhong-Can Ou-Yang , Haijun Zhou

We study structural phase transition of polymer-grafted colloidal particles by Monte Carlo simulations on hard spherical particles. The interaction potential, which has a weak repulsive step outside the hard core, was validated with use of…

Soft Condensed Matter · Physics 2007-05-23 Yuki Norizoe , Toshihiro Kawakatsu

We study the dynamics and conformation of polymers composed by active monomers. By means of Brownian dynamics simulations we show that when the direction of the self-propulsion of each monomer is aligned with the backbone, the polymer…

Soft Condensed Matter · Physics 2018-11-28 Valentino Bianco , Emanuele Locatelli , Paolo Malgaretti

We have studied the thermodynamics of isolated homopolymer chains of varying stiffness using a lattice model. A complex phase behaviour is found; phases include chain-folded `crystalline' structures, the disordered globule and the coil. It…

Soft Condensed Matter · Physics 2008-02-03 Jonathan Doye , Richard Sear , Daan Frenkel

We propose the quantitative mean-field theory of mechanical unfolding of a globule formed by long flexible homopolymer chain collapsed in poor solvent and subjected to extensional deformation. We demonstrate that depending on the degree of…

Soft Condensed Matter · Physics 2012-05-15 Alexey A. Polotsky , Mohamed Daoud , Oleg Borisov , Tatiana M. Birshtein

Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…

Soft Condensed Matter · Physics 2013-07-19 Jiajia Zhou , Roman Schmitz , Burkard Duenweg , Friederike Schmid

The nature of the globule-coil transition of surface-confined polymers has been an issue of debate. Here this 2D collapse transition is studied through a partially directed lattice model. In the general case of polymers with positive…

Soft Condensed Matter · Physics 2007-05-23 Haijun Zhou , Jie Zhou , Zhong-Can Ou-Yang , Sanjay Kumar

We study how dispersions of colloidal particles in a cholesteric liquid crystal behave under a time-dependent electric field. By controlling the amplitude and shape of the applied field wave, we show that the system can be reproducibly…

Soft Condensed Matter · Physics 2015-05-05 Giuseppe D'Adamo , D. Marenduzzo , C. Micheletti , E. Orlandini

Herein, we describe new methods to produce colloidal particle chains of three stiffness regimes that can be observed on a single-particle level, that is, on the level of the monomers that make up the chain; the chains can even be observed…

The structure and thermodynamic state of a system changes under the influence of external electric fields. Neutral systems are characterized by their dielectric constant epsilon, while charged ones also by their charge distribution. In this…

Soft Condensed Matter · Physics 2009-12-10 Yoav Tsori

We present the results from an extensive atomistic molecular dynamics simulation study of poly(ethylene oxide) (PEO) doped with various amounts of lithium-bis(trifluoromethane)sulfonimide (LiTFSI) salt under the influence of external…

Soft Condensed Matter · Physics 2021-03-10 Alina Wettstein , Diddo Diddens , Andreas Heuer

The equilibrium structure and dynamics of a single polymer chain in a thermal solvent is by now well-understood in terms of scaling laws. Here we consider a polymer in a bacterial bath, i.e. in a solvent consisting of active particles which…

Soft Condensed Matter · Physics 2014-07-29 Andreas Kaiser , Hartmut Löwen

We present Monte Carlo simulations of colloidal particles pulled into grafted polymer layers by external fields. The insertion free energy of a single colloid into the polymer layer is qualitatively different for surfaces with an ordered…

Soft Condensed Matter · Physics 2012-10-17 Tine Curk , Francisco J. Martinez-Veracoechea , Daan Frenkel , Jure Dobnikar

We study the dynamics of a polymer, described as a variant of a Rouse chain, driven by an active terminal monomer (head). The local active force induces a transition from a globule-like to an elongated state, as revealed by the study of the…

Statistical Mechanics · Physics 2020-01-28 Laura Natali , Lorenzo Caprini , Fabio Cecconi

A crystalline solid is a periodic sequence of identical cells, each containing one or more atoms. If the constituting unit cell is not centrosymmetric, charge may distribute unevenly between the atoms, resulting in internal electric…

Conjugated polymers are soft, one-dimensional conductors that admit complex interactions between their polymeric, conformational degrees of freedom and their electronic ones. The presence of extended electronic states along their backbone…

Soft Condensed Matter · Physics 2011-07-29 Jeremy D. Schmit , Alex J. Levine

An external electric field changes the physical properties of polar-liquids due to the reorientation of their permanent dipoles. For example it should affect significantly the physical properties of water confined in a nanochannel. The…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 Sobrino Fernández Mario , M. Neek-Amal , F. M. Peeters

It is nowadays a quite diffuse idea that variations of polarisation in condensed matter theory are related to a "Berry phase". The derivation of the latter geometric phase is correct $\it{only if}$ the restrictive periodic gauge\cite{KS-V}…

Materials Science · Physics 2009-06-26 Simone Selenu