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We have developed a theory for inhomogeneous systems that allows for incorporation of effects of mesoscopic fluctuations. A hierarchy of equations relating the correlation and direct correlation functions for the local excess $\phi({\bf…

Statistical Mechanics · Physics 2016-09-21 Alina Ciach , Wojciech T. Gozdz

Approximate expressions for correlation functions in binary inhomogeneous mixtures are derived in a framework of the mesoscopic theory [Ciach A., Mol. Phys., 2011, {\textbf{109}}, 1101]. Fluctuation contribution is taken into account in a…

Soft Condensed Matter · Physics 2020-05-26 A. Ciach , O. Patsahan , A. Meyra

Binary mixtures of hard-spheres with different diameters and square-well attraction between different particles are studied by theory and Monte Carlo simulations. In our mesoscopic theory, local fluctuations of the volume fraction of the…

Soft Condensed Matter · Physics 2021-10-04 O. Patsahan , A. Meyra , A. Ciach

Correlation functions in concentrated ionic systems are studied within the mesoscopic theory at the level of the Gaussian approximation. The previously neglected fluctuation contribution to the inverse charge-charge correlation function is…

Soft Condensed Matter · Physics 2025-06-26 O. Patsahan , A. Ciach

Mesoscopic density functional theory for inhomogeneous mixtures of sperical particles is developed in terms of mesoscopic volume fractions by a systematic coarse-graining procedure starting form microscopic theory. Approximate expressions…

Soft Condensed Matter · Physics 2015-05-20 A. Ciach

In a recent article, we showed how the properties of the density-density correlation function and its integral, the local structure factor, in the fluid interfacial region, in systems with short-ranged forces, can be understood…

Soft Condensed Matter · Physics 2019-11-20 Andrew O. Parry , Carlos Rascón

Mesoscopic theory for soft-matter systems that combines density functional and statistical field theory is derived from the microscopic theory by a systematic coarse-graining procedure. Within the framework of this theory we obtain the…

Soft Condensed Matter · Physics 2013-05-29 A. Ciach

Previously, it has been shown that the direct correlation function for a Lennard-Jones fluid could be modeled by a sum of that for hard-spheres, a mean-field tail and a simple linear correction in the core region constructed so as to…

Statistical Mechanics · Physics 2008-08-20 James F. Lutsko

We develop a theory of fluctuations for Brownian systems with weak long-range interactions. For these systems, there exists a critical point separating a homogeneous phase from an inhomogeneous phase. Starting from the stochastic…

Statistical Mechanics · Physics 2009-11-13 Pierre-Henri Chavanis

Equation of state for systems with particles self-assembling into aggregates is derived within a mesoscopic theory combining density functional and field-theoretic approaches. We focus on the effect of mesoscopic fluctuations in the…

Statistical Mechanics · Physics 2012-07-13 Alina Ciach , Oksana Patsahan

Correlation functions in the restricted primitive model are calculated within a field-theoretic approach in the one-loop self-consistent Hartree approximation. The correlation functions exhibit damped oscillatory behavior as found before in…

Soft Condensed Matter · Physics 2009-11-11 O. Patsahan , A. Ciach

Mesoscopic theory for self-assembling systems near a planar confining surface is developed. Euler- Lagrange (EL) equations and the boundary conditions (BC) for the local volume fraction and the correlation function are derived from the DFT…

Statistical Mechanics · Physics 2020-01-03 A. Ciach

We present first elements of kinetic theory appropriate to the inhomogeneous phase of the HMF model. In particular, we investigate the case of strongly inhomogeneous distributions for $T\to 0$ and exhibit curious behaviour of the force…

Statistical Mechanics · Physics 2009-11-11 P. H. Chavanis

In this work, we show in pedagogical detail that the most singular contributions to the slow part of the asymptotic density-density correlation function of Luttinger liquids with fermions interacting mutually with only short-range forward…

Strongly Correlated Electrons · Physics 2020-10-09 Nikhil Danny Babu , Joy Prakash Das , Girish S. Setlur

The low-T part of the phase diagram in self-assembling systems is correctly predicted by the known versions of the density functional theory (DFT). The high-T part obtained in DFT, however, does not agree with simulations even on the…

Soft Condensed Matter · Physics 2018-11-20 A. Ciach

We investigate the value of the correlation function of an inhomogeneous hard-sphere fluid at contact. This quantity plays a critical role in Statistical Associating Fluid Theory (SAFT), which is the basis of a number of recently developed…

Soft Condensed Matter · Physics 2013-09-10 Jeff Schulte , Patrick Kreitzberg , Chris Haglund , David Roundy

Disordered and hyperuniform structures of densely packed spheres near and at jamming are characterized by vanishing of long-wavelength density fluctuations, or equivalently by long-range power-law decay of the direct correlation function…

Statistical Mechanics · Physics 2021-10-04 Hiroshi Frusawa

We study the mass density distribution of the Newtonian self-gravitating system. Modeling the system either as a gas in thermal equilibrium, or as a fluid in hydrostatical equilibrium, we obtain the field equation of correlation function…

Cosmology and Nongalactic Astrophysics · Physics 2015-09-16 Yang Zhang , Qing Chen

A mesoscopic theory for water-in-salt electrolytes combining density functional and field-theoretic methods is developed in order to explain the unexpectedly large period of the oscillatory decay of the disjoining pressure observed in…

Soft Condensed Matter · Physics 2021-09-29 Oksana Patsahan , Alina Ciach

A recent mode coupling theory of higher-order correlation functions is tested on a simple hard-sphere fluid system at intermediate densities. Multi-point and multi-time correlation functions of the densities of conserved variables are…

Statistical Mechanics · Physics 2009-11-07 Ramses van Zon , Jeremy Schofield
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