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The phase behavior of linear dendritic triblock copolymer melts(AB2C4) is studied by self-consistent-field theory (SCFT) in order to find the effects of branching on the phase behavior of ABC linear triblock copolymer melts. We focus on a…

Soft Condensed Matter · Physics 2023-09-19 Danyang Chen , Xiaowei Ning

The phase behaviour of blends of ABC triblock and ac diblock copolymers is examined using self-consistent field theory. Several equilibrium lamellar structures are observed, depending on the volume fraction of the diblocks, phi_2, the…

Soft Condensed Matter · Physics 2009-11-07 Robert A. Wickham , An-Chang Shi

The elastic property of membranes self-assembled from AB diblock and ABA triblock copolymers, as coarse-grained model of lipids and the bolalipids, are studied using the self-consistent field theory (SCFT). Specifically, solutions of the…

Soft Condensed Matter · Physics 2019-05-17 Rui Xu , Ashkan Dehghan , An-Chang Shi , Jiajia Zhou

Self-consistent field theory (SCFT) is one of the useful methods to simulate phase separated structures of multi-component polymer systems. In this article, we propose an SCFT for semiflexible polymer melts, where the basic equations for…

Soft Condensed Matter · Physics 2025-03-04 Yutaka Oya , Toshihiro Kawakatsu

Using the self-consistent field approach, the effect of asymmetry of the coil block on the microphase separation is focused in ABC coil-rod-coil triblock copolymers. For different fractions of the rod block $f_{\text B}$, some stable…

Disordered Systems and Neural Networks · Physics 2017-12-15 X. -G. Han , H. -H. Meng , Y. -H. Ma , S. -L. Ouyang

The self-assembly of block copolymers containing rigid blocks have received abiding attention due to its rich phase behavior and potential for use in a variety of applications. In this work, under asymmetric interactions between rod/coil…

Soft Condensed Matter · Physics 2021-01-20 X. -G. Han , N. Liang , H. Zhang

This paper concerns the analytic structure of the self-consistent field theory (SCFT) energy functional of multicomponent block copolymer systems which contain more than two chemically distinct blocks. The SCFT has enjoyed considered…

Computational Physics · Physics 2013-10-07 Kai Jiang , Weiquan Xu , Pingwen Zhang

Self-consistent field theory (SCFT) is one of the most widely-used framework in studying the equilibrium phase behaviors of inhomogenous polymers. For liquid crystalline polymeric systems, the main numerical challenges of solving SCFT…

Numerical Analysis · Mathematics 2024-09-16 Zhijuan He , Kai Jiang , Liwei Tan , Xin Wang

We present a numerical algorithm to evaluate the self-consistent field theory for melts composed of block copolymers with multiply-branched architecture. We present results for the case of branched copolymers with doubly-functional groups…

Soft Condensed Matter · Physics 2007-05-23 Gregory M. Grason , Randall D. Kamien

Self-consistent field theory (SCFT) and strong segregation theory (SST) are used to explore the parameter space governing the self-assembly of cylinder forming block copolymers (BCPs) on a modulated substrate. The stability of in-plane…

Materials Science · Physics 2018-11-16 Karim Gadelrab , Alfredo Alexander-Katz

We introduce a mesoscale technique for simulating the structure and rheology of block copolymer melts and blends in hydrodynamic flows. The technique couples dynamic self consistent field theory (DSCFT) with continuum hydrodynamics and flow…

Soft Condensed Matter · Physics 2009-11-11 David M. Hall , Turab Lookman , Glenn H. Fredrickson , Sanjoy Banerjee

Block copolymers provide a wonderful platform in studying the soft condensed matter systems. Many fascinating ordered structures have been discovered in bulk and confined systems. Among various theories, the self-consistent field theory…

Soft Condensed Matter · Physics 2019-05-01 Huayi Wei , Ming Xu , Wei Si , Kai Jiang

The self-consistent field theory (SCFT) is a powerful framework for the study of the phase behavior and structural properties of many-body systems. In particular, polymeric SCFT has been successfully applied to inhomogeneous polymeric…

Soft Condensed Matter · Physics 2019-01-31 An-Chang Shi

We compare two theoretical approaches to dielectric diblock copolymer melts in an external electric field. The first is a relatively simple analytic expansion in the relative copolymer concentration, and includes the full electrostatic…

Soft Condensed Matter · Physics 2012-01-31 Yoav Tsori , David Andelman , Chin-Yet Lin , M. Schick

We present a self-consistent field theory (SCFT) of semiflexible (wormlike) diblock copolymers, each consisting of a rigid and a flexible part. The segments of the polymers are otherwise identical, in particular with regard to their…

Soft Condensed Matter · Physics 2009-11-07 Dominik Düchs , D. E. Sullivan

An efficient pseudo-spectral numerical method is introduced for calculating a self-consistent field (SCF) approximation for the linear susceptibility of ordered phases in block copolymer melts (sometimes referred to as the random phase…

Soft Condensed Matter · Physics 2009-11-13 Amit Ranjan , Jian Qin , David C. Morse

Diblock copolymers blended with homopolymer may self-assemble into spherical, cylindrical or lamellar aggregates. Transitions between these structures may be driven by varying the homopolymer molecular weight or the molecular weight or…

Statistical Mechanics · Physics 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish

X-shaped liquid crystalline molecules (XLCMs) are obtained by tethering two flexible end A-blocks and two flexible side B-blocks to a rigid backbone (R). A rich array of ordered structures can be formed from XLCMs, driven by the competition…

Soft Condensed Matter · Physics 2024-10-25 Dan Wei , Zhijuan He , Yunqing Huang , An-Chang Shi , Kai Jiang

In this work we investigated the phase behavior of melts of block-copolymers with one charged block by means of dissipative particle dynamics with explicit electrostatic interactions. We assumed that all the Flory-Huggins \c{hi} parameters…

Soft Condensed Matter · Physics 2019-06-12 Alexey A. Gavrilov , Alexander V. Chertovich , Igor I. Potemkin

We present a self-consistent field theory (SCFT) study of spherical micelle formation in a blend of poly(styrene-butadiene) diblocks and homopolystyrene. The micelle core radii, corona thicknesses and critical micelle concentrations are…

Soft Condensed Matter · Physics 2011-06-28 M. J. Greenall , D. M. A. Buzza , T. C. B. McLeish
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