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Discretizing an analytic function on a uniform real-space grid is often done via a straightforward collocation method. This is ubiquitous in all areas of computational physics and quantum chemistry. An example in Density Functional Theory…

Computational Physics · Physics 2016-01-20 Luigi Genovese , Thierry Deutsch

We present a mean-field approach for accurately describing strong correlations via electron number fluctuations and pairings constrained to an active space. Electron number conservation is broken and correct only on average but both spin…

Materials Science · Physics 2013-06-28 Takashi Tsuchimochi , Gustavo E. Scuseria

In this work we revisit the arithmetic and bit complexity of Hermitian eigenproblems. Recently, [BGVKS, FOCS 2020] proved that a (non-Hermitian) matrix can be diagonalized with a randomized algorithm in $O(n^{\omega}\log^2(n/\epsilon))$…

Data Structures and Algorithms · Computer Science 2025-04-29 Aleksandros Sobczyk

We use a variational Monte Carlo algorithm to solve the electronic structure of two-dimensional semiconductor quantum dots in external magnetic field. We present accurate many-body wave functions for the system in various magnetic field…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Ari Harju

In the context of change-point detection, addressed by Total Variation minimization strategies, an efficient on-the-fly algorithm has been designed leading to exact solutions for univariate data. In this contribution, an extension of such…

Machine Learning · Computer Science 2016-08-30 Jordan Frecon , Nelly Pustelnik , Patrice Abry , Laurent Condat

The complexity of quantum many-body problems scales exponentially with the size of the system, rendering any finite size scaling analysis a formidable challenge. This is particularly true for methods based on the full representation of the…

Strongly Correlated Electrons · Physics 2025-02-19 Robin Schäfer , David J. Luitz

The data input model is a fundamental component of every quantum algorithm, as its efficiency is crucial for achieving potential speed-ups over classical methods. For quantum linear algebra tasks that utilize quantum eigenvalue or singular…

Quantum Physics · Physics 2025-09-03 Andreas Sturm , Niclas Schillo

Density Functional Theory (DFT) is widely used for atomistic simulations. However, its reach stays limited due to several limitations such as lack of accurate exchange-correlation functional, requirement of costly O(N 3) diagonalization…

Quantum Physics · Physics 2026-05-18 Namrata Manglani , Samrit Kumar Maity , Shashank Sharma , Soham Phulare , Sanjay Wandhekar

We introduce a neural network impurity solver for real-frequency DMFT that employs a multihead cross-attention mechanism to map hybridization functions to spectral functions, conditioned on impurity parameters. Trained on high-quality MPS…

Strongly Correlated Electrons · Physics 2025-11-19 Fenglin Deng , Yi Lu , Xiaodong Cao , Zhicheng Zhong

Understanding and characterising quantum many-body dynamics remains a significant challenge due to both the exponential complexity required to represent quantum many-body Hamiltonians, and the need to accurately track states in time under…

Quantum Physics · Physics 2024-08-19 Timothy Heightman , Edward Jiang , Antonio Acín

Recently, sophisticated deep learning-based approaches have been developed for generating efficient initial guesses to accelerate the convergence of density functional theory (DFT) calculations. While the actual initial guesses are often…

Chemical Physics · Physics 2026-03-24 Zhe Liu , Yuyan Ni , Zhichen Pu , Qiming Sun , Siyuan Liu , Wen Yan

We present a novel algorithm based on the ensemble Kalman filter to solve inverse problems involving multiscale elliptic partial differential equations. Our method is based on numerical homogenization and finite element discretization and…

Numerical Analysis · Mathematics 2020-12-16 Assyr Abdulle , Giacomo Garegnani , Andrea Zanoni

A fundamental roadblock to the exact numerical solution of many-fermion problems is the exponential growth of the Hilbert space with system size. It manifests as extreme dynamical memory and computation-time requirements for simulating…

Strongly Correlated Electrons · Physics 2023-09-01 Prabhakar , Anamitra Mukherjee

Quantum algorithms for electronic-structure simulations are actively being developed, yet many hybrid quantum-classical approaches are bottlenecked by the measurement overhead associated with large molecular Hamiltonians. Here we introduce…

Quantum Physics · Physics 2026-03-10 Benjamin Mokhtar , Noboru Inoue , Takashi Tsuchimochi

Quantum computing is an advancing area of research in which computer hardware and algorithms are developed to take advantage of quantum mechanical phenomena. In recent studies, quantum algorithms have shown promise in solving linear systems…

Computational Physics · Physics 2023-06-16 Katherine Asztalos , René Steijl , Romit Maulik

Given a partition of a large system into an active quantum mechanical (QM) region and its environment, we present a simple way of embedding the QM region into an effective electrostatic potential representing the environment. This potential…

Chemical Physics · Physics 2017-07-20 Stephan Mohr , Michel Masella , Laura E. Ratcliff , Luigi Genovese

We propose a framework to solve non-linear and history-dependent mechanical problems based on a hybrid classical computer -- quantum annealer approach. Quantum Computers are anticipated to solve particular operations exponentially faster.…

Computational Engineering, Finance, and Science · Computer Science 2024-02-20 Van-Dung Nguyen , Ling Wu , Françoise Remacle , Ludovic Noels

Quantum computers have the potential to advance material design and drug discovery by performing costly electronic structure calculations. A critical aspect of this application requires optimizing the limited resources of the quantum…

We present a real-space formulation and higher-order finite-difference implementation of periodic Orbital-free Density Functional Theory (OF-DFT). Specifically, utilizing a local reformulation of the electrostatic and kernel terms, we…

Computational Physics · Physics 2015-12-23 Swarnava Ghosh , Phanish Suryanarayana

Achieving an accurate description of fermionic systems typically requires considerably many more orbitals than fermions. Previous resource analyses of quantum chemistry simulation often failed to exploit this low fermionic number…

Quantum Physics · Physics 2022-05-24 Sam McArdle , Earl Campbell , Yuan Su
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