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Dielectric measurements on molecular liquids just above the glass transition indicate that alpha relaxation is characterized by a generic high-frequency loss varying as $\omega^{-1/2}$, whereas deviations from this come from one or more…

Soft Condensed Matter · Physics 2009-11-11 Jeppe C. Dyre

We investigate the Kovacs (or crossover) effect in facilitated $f$-spin models of glassy dynamics. Although the Kovacs hump shows a behavior qualitatively similar for all cases we have examined (irrespective of the facilitation parameter…

Soft Condensed Matter · Physics 2007-05-23 J. J. Arenzon , M. Sellitto

Within the mode-coupling theory for ideal glass transitions, an analysis for the correlation functions of glass-forming systems for states near higher-order glass-transition singularities is presented. It is shown that the solutions of the…

Soft Condensed Matter · Physics 2007-05-23 W. Gotze , M. Sperl

The dynamics of glass-forming liquids display several outstanding features, such as two-step relaxation and dynamic heterogeneities, which are difficult to predict quantitatively from first principles. In this work, we revisit a simple…

Statistical Mechanics · Physics 2022-11-23 Daniele Coslovich , Atsushi Ikeda

We show that facilitated spin models of cooperative dynamics introduced by Fredrickson and Andersen display on Bethe lattices a glassy behaviour similar to the one predicted by the mode-coupling theory of supercooled liquids and the…

Statistical Mechanics · Physics 2009-11-10 Mauro Sellitto , Giulio Biroli , Cristina Toninelli

We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on…

Statistical Mechanics · Physics 2015-05-13 A. Andreanov , G. Biroli , J. -P. Bouchaud

Glasses derive their functional properties from complex relaxation dynamics that remain enigmatic under extreme conditions. While the temperature dependence of these relaxation processes is well-established, their behavior under…

Relaxation processes significantly influence the properties of glass materials. However, understanding their specific origins is difficult, even more challenging is to forecast them theoretically. In this study, using microseconds molecular…

Materials Science · Physics 2019-09-09 Yang Sun , Si-Xu Peng , Qun Yang , Feng Zhang , Meng-Hao Yang , Cai-Zhuang Wang , Kai-Ming Ho , Hai-Bin Yu

Extensive computer simulations are performed for a few model glass-forming liquids in both two and three dimensions to study their dynamics when a randomly chosen fraction of particles are frozen in their equilibrium positions. For all the…

Statistical Mechanics · Physics 2016-08-03 Saurish Chakrabarty , Rajsekhar Das , Smarajit Karmakar , Chandan Dasgupta

We present results from Molecular Dynamics simulations of the thermal glass transition in a dense polymer melt. In previous work we compared the simulation data with the idealized version of mode coupling theory (MCT) and found that the…

Soft Condensed Matter · Physics 2009-10-31 Christoph Bennemann , Wolfgang Paul , J"org Baschnagel , Kurt Binder

Aging refers to the evolution of system properties with waiting time $t_w$. It is a key feature of glassy dynamics. Recent experiments have demonstrated aging in biological systems that are inherently active with a magnitude of…

Soft Condensed Matter · Physics 2026-04-10 Soumitra Kolya , Nir S. Gov , Saroj Kumar Nandi

Nearly all glass forming liquids display secondary relaxations, dynamical modes seemingly distinct from the primary alpha relaxations. We show that accounting for driving force fluctuations and the diversity of reconfiguring shapes in the…

Soft Condensed Matter · Physics 2015-05-13 Jacob D. Stevenson , Peter G. Wolynes

In the mode coupling theory of the liquid to glass transition the long time structural relaxation follows from equations solely determined by equilibrium structural parameters. The present extension of these structural relaxation equations…

Soft Condensed Matter · Physics 2017-02-08 M. Fuchs , Th. Voigtmann

Active glasses refer to a class of driven non-equilibrium systems that share remarkably similar dynamical behavior as conventional glass-formers in equilibrium. Glass-like dynamical characteristics have been observed in various biological…

Soft Condensed Matter · Physics 2024-12-24 Subhodeep Dey , Smarajit Karmakar

Molecular-dynamics simulations are presented for two correlation functions formed with the partial density fluctuations of binary hard-sphere mixtures in order to explore the effects of mixing on the evolution of glassy dynamics upon…

Soft Condensed Matter · Physics 2007-05-23 G. Foffi , W. Gotze , F. Sciortino , P. Tartaglia , Th. Voigtmann

Long-range interacting systems, while relaxing towards equilibrium, may get trapped in nonequilibrium quasistationary states (QSS) for a time which diverges algebraically with the system size. These intriguing non-Boltzmann states have been…

Statistical Mechanics · Physics 2013-12-03 Shamik Gupta , David Mukamel

We explore the glassy dynamics of soft colloids using microgels and charged particles interacting by steric and screened Coulomb interactions, respectively. In the supercooled regime, the structural relaxation time $\tau_\alpha$ of both…

The shapes of cooperatively rearranging regions in glassy liquids change from being compact at low temperatures to fractal or ``stringy'' as the dynamical crossover temperature from activated to collisional transport is approached from…

Soft Condensed Matter · Physics 2015-06-25 Jacob D. Stevenson , Joerg Schmalian , Peter G. Wolynes

In this paper the phenomenon of dynamic heterogeneity in supercooled liquid systems is considered in terms of the recently proposed gauge theory of glass transition. The physical interpretation of the dynamic scaling is considered. It is…

Statistical Mechanics · Physics 2015-06-23 Mikhail Vasin

Idealized glass transitions are discussed within a novel mode-coupling theory (TMCT) proposed by Tokuyama(Physica A 395,31(2014)). This is done in order to identify common grounds with and differences to the conventional mode-coupling…

Statistical Mechanics · Physics 2015-04-23 Wolfgang Götze , Rolf Schilling