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A remarkable property of Rydberg atoms is the possibility to create molecules formed by one highly excited atom and another atom in the ground state. The first realisation of such a Rydberg molecule has opened an active field of physical…

Atomic Physics · Physics 2013-04-02 Andrej Junginger , Jörg Main , Günter Wunner

Laser cooling and trapping of atomic matter waves in optical potentials has enabled rapid progress in quantum science, particularly when combined with Rydberg excitation of the atoms to induce long-range interactions. Here, we propose the…

Atomic Physics · Physics 2026-05-28 Homar Rivera-Rodríguez , Matthew T. Eiles , Tilman Pfau , Florian Meinert

Resonant energy transfer (RET), between equal parity 1s65s$^3\mathrm{S}_1$ and 1s66s$^3\mathrm{S}_1$ Rydberg levels in helium has been observed in low-temperature ($\sim80$ mK) collisions with ammonia molecules which undergo inversion…

Atomic Physics · Physics 2026-05-21 J. Zou , R. R. W. Wang , R. González-Férez , H. R. Sadeghpour , S. D. Hogan

We consider the magnetically tunable Feshbach resonances that may exist in ultracold mixtures of molecules in $^2\Sigma$ states and alkali-metal atoms. We focus on Rb+CaF as a prototype system. There are likely to be Feshbach resonances…

Atomic Physics · Physics 2023-06-05 Robert C. Bird , Michael R. Tarbutt , Jeremy M. Hutson

Pulsed laser excitation of a dense ultracold Cs vapor has been used to study the pairwise interactions between Cs atoms excited to $n$p$_{3/2}$ Rydberg states of principal quantum numbers in the range $n=22-36$. Molecular resonances were…

Atomic Physics · Physics 2015-09-14 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

We report on the observation of interactions between ultracold Rydberg atoms and ions in a Paul trap. The rate of observed inelastic collisions, which manifest themselves as charge transfer between the Rydberg atoms and ions, exceeds that…

Atomic Physics · Physics 2019-07-03 N. V. Ewald , T. Feldker , H. Hirzler , H. Fürst , R. Gerritsma

Atoms with a highly excited electron, called Rydberg atoms, can form unusual types of molecular bonds. The bond differs from the well known ionic and covalent bonds not only by its binding mechanism, but also by its bond length ranging up…

Atomic Physics · Physics 2022-05-20 N. Zuber , V. S. V. Anasuri , M. Berngruber , Y. -Q. Zou , F. Meinert , R. Löw , T. Pfau

Results of numerical Monte Carlo simulations for the Stark-tuned F\"orster resonance and dipole blockade between two to five cold rubidium Rydberg atoms in various spatial configurations are presented. The effects of the atoms' spatial…

Quantum Physics · Physics 2010-11-12 I. I. Ryabtsev , D. B. Tretyakov , I. I. Beterov , V. M. Entin , E. A. Yakshina

Electrons coupled to local lattice deformations end up in selftrapped localized molecular states involving their binding into bipolarons when the coupling is stronger than a certain critical value. Below that value they exist as essentially…

Superconductivity · Physics 2009-11-11 J. Ranninger , A. Romano

Non-radiative energy transfer between a Rydberg atom and a polar molecule can be controlled by a DC electric field. Here we show how to exploit this control for state-resolved, non-destructive detection and spectroscopy of the molecules…

Atomic Physics · Physics 2023-11-28 Sabrina Patsch , Martin Zeppenfeld , Christiane P. Koch

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

The recoil of atoms in dense ensembles during light matter interactions is studied using quantized vibrational states for the atomic motion. The recoil resulting from the forces due to the near-field collective dipole interactions and…

Quantum Physics · Physics 2025-03-24 Deepak A. Suresh , F. Robicheaux

We propose to apply stimulated adiabatic passage to transfer atoms from their ground state into Rydberg excited states. Atoms a few micrometers apart experience a dipole-dipole interaction among Rydberg states that is strong enough to shift…

Quantum Physics · Physics 2009-11-13 Ditte Moller , Lars Bojer Madsen , Klaus Molmer

We theoretically study collisions between ultracold polar molecules that are polarized by microwave or static electric fields. We systematically study the dependence on field strength, microwave polarization, and detuning from rotational…

Atomic Physics · Physics 2022-02-09 Tijs Karman , Zoe Z. Yan , Martin Zwierlein

Rydberg atoms represent a platform underpinning many recent developments in quantum computation, simulation, sensing, and metrology. They further facilitate optical nonlinearity at the single-photon level when coupled to photons propagating…

Strong resonant dipole-dipole interactions in flexible Rydberg aggregates enable the formation of exciton pulses, the interplay of atomic motion and electronic excitation transfer which feature high fidelity entanglement transport. Here, we…

Quantum Physics · Physics 2016-12-26 Karsten Leonhardt

Cold collisions between two Rydberg rubidium atoms ($^{87}$Rb) are investigated by controlling the impact parameter and collision energy. Optical tweezers are employed to hold one atom stationary while propelling the other to a constant…

Atomic Physics · Physics 2024-12-10 Hansub Hwang , Sunhwa Hwang , Jaewook Ahn , Shuhei Yoshida , Joachim Burgdorfer

A generalized class of ultra-long-range Rydberg molecules is proposed which consist of a multichannel Rydberg atom whose outermost electron creates a chemical bond with a distant ground state atom. Such multichannel Rydberg molecules…

Atomic Physics · Physics 2015-11-11 Matthew T. Eiles , Chris H. Greene

Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical…

Room temperature cavity quantum electrodynamics with molecular materials in optical cavities offers exciting prospects for controlling electronic, nuclear and photonic degrees of freedom for applications in physics, chemistry and materials…

Quantum Physics · Physics 2025-01-15 Felipe Herrera , William L. Barnes