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Slater determinants have underpinned quantum chemistry for nearly a century, yet their full potential has remained challenging to exploit. In this work, we show that a variational wavefunction composed of a few hundred optimized…

Chemical Physics · Physics 2026-04-17 Clemens Giuliani , Jannes Nys , Rocco Martinazzo , Giuseppe Carleo , Riccardo Rossi

Diabatization of the molecular Hamiltonian is a standard approach to removing the singularities of nonadiabatic couplings at conical intersections of adiabatic potential energy surfaces. In general, it is impossible to eliminate the…

Chemical Physics · Physics 2021-03-26 Seonghoon Choi , Jiří Vaníček

Anomaly detection techniques enable effective anomaly detection and diagnosis in multi-variate time series data, which are of major significance for today's industrial applications. However, establishing an anomaly detection system that can…

Machine Learning · Computer Science 2024-05-02 Lingrui Yu

A numerical method is developed to solve the time-dependent Dirac equation in cylindrical coordinates for 3-D axisymmetric systems. The time evolution is treated by a splitting scheme in coordinate space using alternate direction iteration,…

Computational Physics · Physics 2015-04-03 François Fillion-Gourdeau , Emmanuel Lorin , André D. Bandrauk

This paper focuses on providing the computation methods for the backward time tempered fractional Feynman-Kac equation, being one of the models recently proposed in [Wu, Deng, and Barkai, Phys. Rev. E, 84 (2016) 032151]. The discretization…

Numerical Analysis · Mathematics 2017-05-01 Weihua Deng , Zhijiang Zhang

We consider a family of variable time-stepping Dahlquist-Liniger-Nevanlinna (DLN) schemes, which is unconditional non-linear stable and second order accurate, for the Allen-Cahn equation. The finite element methods are used for the spatial…

Numerical Analysis · Mathematics 2024-10-01 YiMing Chen , Dianlun Luo , Wenlong Pei , Yulong Xing

In this work, we study time-splitting strategies for the numerical approximation of evolutionary reaction-diffusion problems. In particular, we formulate a family of domain decomposition splitting methods that overcomes some typical…

Numerical Analysis · Mathematics 2016-09-01 Andrés Arrarás , Laura Portero

We study several numerical discretization techniques for the one-space plus one-time dimensional Dirac equation, including finite difference and space-time finite element methods. Two finite difference schemes and several space-time finite…

Numerical Analysis · Mathematics 2014-12-04 Robert Vaselaar , Hyun Lim , Jung-Han Kimn

We apply a recently developed quasi-diabatic (QD) scheme to the symmetric quasi-classical (SQC) approach for accurate quantum dynamics propagation. By using the adiabatic states as the quasi-diabatic states during a short-time quantum…

Chemical Physics · Physics 2018-07-11 Juan Sebastian C. Sandoval , Arkajit Mandal , Pengfei Huo

Hybrid numerical-experimental testing is a standard approach for complex dynamical structures that are, on the one hand, not easy to model due to complexity and parameter uncertainty and, on the other hand, too expensive for full-scale…

Dynamical Systems · Mathematics 2020-03-24 Benjamin Unger

The time-marching strategy, which propagates the solution from one time step to the next, is a natural strategy for solving time-dependent differential equations on classical computers, as well as for solving the Hamiltonian simulation…

Quantum Physics · Physics 2023-03-22 Di Fang , Lin Lin , Yu Tong

Quantum computers have been proposed as a solution for efficiently solving non-linear differential equations (DEs), a fundamental task across diverse technological and scientific domains. However, a crucial milestone in this regard is to…

Quantum Physics · Physics 2025-03-31 Annie Paine , Casper Gyurik , Antonio Andrea Gentile

We propose a systematic approach to the basis set extension for nonadiabatic dynamics of entangled combination of nuclear coherent states (CSs) evolving according to the time-dependent variational principle (TDVP). TDVP provides a rigorous…

Chemical Physics · Physics 2017-03-14 Artur F. Izmaylov , Loïc Joubert-Doriol

A numerical method is proposed for computing time-periodic and relative time-periodic solutions in dissipative wave systems. In such solutions, the temporal period, and possibly other additional internal parameters such as the propagation…

Pattern Formation and Solitons · Physics 2014-08-28 Jianke Yang

We present a novel quantum-classical approach to non-adiabatic dynamics, deduced from the coupled electronic and nuclear equations in the framework of the exact factorization of the electron-nuclear wave function. The method is based on the…

Chemical Physics · Physics 2015-08-19 Seung Kyu Min , Federica Agostini , E. K. U. Gross

In this paper, we study a fast and linearized finite difference method to solve the nonlinear time-fractional wave equation with multi fractional orders. We first propose a discretization to the multi-term Caputo derivative based on the…

Numerical Analysis · Mathematics 2019-02-22 Pin Lyu , Yuxiang Liang , Zhibo Wang

We consider a classical and superadiabatic version of an iterative quantum adiabatic algorithm to solve combinatorial optimization problems. This algorithm is deterministic because it is based on purely classical dynamics, that is, it does…

Statistical Mechanics · Physics 2020-05-08 Takuya Hatomura

We introduce an analytical framework to calculate the values of key observables in a strongly disordered discrete time crystal (DTC) without fitting parameter. The perturbatively obtained closed-form formulae show quantitative agreement…

Disordered Systems and Neural Networks · Physics 2025-12-25 Yang-Ren Liu , Biao Huang

The iterative problem of solving nonlinear equations is studied. A new Newton like iterative method with adjustable parameters is designed based on the dynamic system theory. In order to avoid the derivative function in the iterative…

Numerical Analysis · Mathematics 2022-11-09 Yonglong Liao , Limin Cui

The theoretical investigation of non-adiabatic processes is hampered by the complexity of the coupled electron-nuclear dynamics beyond the Born-Oppenheimer approximation. Classically, the simulation of such reactions is limited by the…

Quantum Physics · Physics 2021-01-06 Pauline J. Ollitrault , Guglielmo Mazzola , Ivano Tavernelli