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A positive rate of entropy production at steady state is a distinctive feature of truly non-equilibrium processes. Exact results, while being often limited to simple models, offer a unique opportunity to explore the thermodynamic features…

Statistical Mechanics · Physics 2022-06-29 Henry Alston , Luca Cocconi , Thibault Bertrand

Small thermodynamic systems exhibit peculiar behavior different from that observed in long-scale systems. Non-equilibrium processes taking place in those systems are strongly influenced by the presence of fluctuations which can be large.…

Statistical Mechanics · Physics 2007-05-23 J. M. Rubi

We develop non-equilibrium theory by using averages in time and space as a generalized way to upscale thermodynamics in non-ergodic systems. The approach offers a classical perspective on the energy dynamics in fluctuating systems. The rate…

Soft Condensed Matter · Physics 2021-09-29 James E. McClure , Steffen Berg , Ryan T. Armstrong

We compare two approaches to nonequilibrium thermodynamics, the two-generator bracket formulation of time-evolution equations for averages and the macroscopic fluctuation theory, for an isothermal driven diffusive system under steady state…

Statistical Mechanics · Physics 2010-11-10 Hans Christian Ottinger

We introduce a finite-time detailed fluctuation theorem for the environmental entropy of the form $\tilde P(\Delta S_{env}) = e^{\Delta S_{env}} \tilde P(-\Delta S_{env})$ for an appropriately weighted probability density of the external…

Statistical Mechanics · Physics 2013-04-22 David Luposchainsky , Andre Cardoso Barato , Haye Hinrichsen

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

We present the theoretical study on non-equilibrium (NEQ) fluctuations for diffusion dynamics in high dimensions driven by a linear drift force. We consider a general situation in which NEQ is caused by two conditions: (i) drift force not…

Statistical Mechanics · Physics 2013-05-29 Chulan Kwon , Jae Dong Noh , Hyunggyu Park

The past twenty years have seen a resurgence of interest in nonequilibrium thermodynamics, thanks to advances in the theory of stochastic processes and in their thermodynamic interpretation. Fluctuation theorems provide fundamental…

Statistical Mechanics · Physics 2017-11-16 Robert Marsland , Jeremy England

Fluctuations in thermal many-particle systems reflect fundamental dynamical processes in both equilibrium and nonequilibrium (NEQ) physics. In NEQ systems \cite{ritort} fluctuations are important in a variety of contexts ranging from…

Statistical Mechanics · Physics 2012-01-17 Marco G. Mazza , Martin Schoen

Thermodynamic uncertainty relations have emerged as universal bounds on current fluctuations in non-equilibrium systems. Here we derive a new bound for a particular class of run-and-tumble type processes using the mathematical framework of…

Statistical Mechanics · Physics 2019-07-02 Mayank Shreshtha , Rosemary J. Harris

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

Non-EQuilibrium (NEQ) statistical physics has not had the same general foundation as that of EQuilibrium (EQ) statistical physics, where forces are derived from potentials such as $1/T = \partial S/\partial U$, and from which other key…

Statistical Mechanics · Physics 2025-05-07 Ying-Jen Yang , Ken A. Dill

We investigate thermodynamics of general nonequilibrium processes stopped at stochastic times. We propose a systematic strategy for constructing fluctuation-theorem-like martingales for each thermodynamic functional, yielding a family of…

Statistical Mechanics · Physics 2023-06-02 Haoran Yang , Hao Ge

This work extends a recently developed mathematical theory of thermodynamics for Markov processes with, and more importantly, without detailed balance. We show that the Legendre transform in connection to ensemble changes in Gibbs'…

Statistical Mechanics · Physics 2015-10-28 Moisés Santillán , Hong Qian

This work brings together Keldysh non-equilibrium quantum theory and thermodynamics, by showing that a real-time diagrammatic technique is an equivalent of stochastic thermodynamics for non-Markovian quantum machines (heat engines,…

Mesoscale and Nanoscale Physics · Physics 2021-03-16 Robert S. Whitney

We develop a Thermodynamic Formalism for bounded continuous potentials defined on the sequence space $X\equiv E^{\mathbb{N}}$, where $E$ is a general Borel standard space. In particular, we introduce meaningful concepts of entropy and…

Dynamical Systems · Mathematics 2020-06-26 L. Cioletti , E. A. Silva , M. Stadlbauer

We discuss the non-equilibrium critical phenomena in liquids, and the models for these phenomena based on local equilibrium and extended scaling assumptions. Special situations are proposed for experimental tests of the theory.…

Statistical Mechanics · Physics 2009-10-31 Alexander Patashinski

We study non-normalizable quasi-equilibrium states (NNQE) arising from anomalous diffusion. Initially, particles in contact with a thermal bath are released from an asymptotically flat potential well, with dynamics that is described by…

Statistical Mechanics · Physics 2023-08-24 Lucianno Defaveri , Maike A. F. dos Santos , David A. Kessler , Eli Barkai , Celia Anteneodo

To describe the nonequilibrium states of a system we introduce a new thermodynamic parameter - the lifetime of a system. The statistical distributions which can be obtained out of the mesoscopic description characterizing the behaviour of a…

Statistical Mechanics · Physics 2007-05-23 V. V. Ryazanov , S. G. Shpyrko

The total entropy production of stochastic systems can be divided into three quantities. The first corresponds to the excess heat, whilst the second two comprise the house-keeping heat. We denote these two components the transient and…

Statistical Mechanics · Physics 2015-06-03 Richard E. Spinney , Ian J. Ford
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