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Indium phosphide and derived compound semiconductors are materials often involved in high-efficiency solar water splitting due to their versatile opto-electronic properties. Surface corrosion, however, typically deteriorates the performance…

Chemical Physics · Physics 2022-11-16 Mario Löw , Margot Guidat , Jongmin Kim , Matthias M. May

First-principles density functional theory calculations were carried out to determine the low energy geometries of anatase TiO$_2$(001) with Pt implants in the sublayers as substitutional and interstitial impurities as well as on the…

Strongly Correlated Electrons · Physics 2009-03-19 E. Mete , D. Uner , O. Gulseren , S. Ellialtioglu

We study the chemical nature of the bonding of an oxide layer to the parent metal. In order to disentangle chemical effects from strain/misfit, Ti(10$\bar{1}$0)/TiO$_{2}$(100) interface has been chosen. We use the density functional…

Materials Science · Physics 2012-12-10 Linggang Zhu , Graeme J. Ackland

DFT and AIMD are used to investigate the structural, stability, electronic, thermal, and optical properties of the quasi-2D C2N2O structure. The structure exhibits thermal and energy stability, signifying robustness under ambient…

Materials Science · Physics 2026-04-30 Hemn. G. H , Nzar. R. Abdullah , Vidar Gudmundsson

Organic/inorganic donor-acceptor interfaces are gaining growing attention in organic photovoltaic applications as each component of the interface offers unique attributes. Here we use hybrid-density functional theory to examine the…

Materials Science · Physics 2011-03-29 Na Sai , Kevin Leung , James R. Chelikowsky

We use density functional theory (DFT) calculations to investigate structural models consisting of anatase TiO2(101) slabs covered by reduced overlayers formed by (101) crystallographic shear planes (CSPs). Ab initio thermodynamics supports…

Materials Science · Physics 2018-01-17 Xunhua Zhao , Sencer Selcuk , Annabella Selloni

Semiconductor heterostructures capable of separating photogenerated electrons and holes have a wide range of optoelectronic applications, including photodetectors, solar cells, and photocatalysts. ${\beta}$-Ga$_2$O$_3$ and rutile GeO$_2$…

Materials Science · Physics 2025-09-25 D. Q. Fang

We show that the formation of the wetting layer and the experimentally observed continuous shift of the H2O-OH balance towards molecular water at increasing coverage on a TiO2(110) surface can be rationalized on a molecular level. The…

Materials Science · Physics 2013-08-20 M. Amft , L. E. Walle , D. Ragazzon , A. Borg , P. Uvdal , N. V. Skorodumova , A. Sandell

The quasiparticle electronic structure and optical excitation of anatase TiO$_2$ is determined within the framework of many-body perturbation theory (MBPT) by combining the $G_0W_0$ method and the Bethe-Salpeter Equation (BSE). A modified…

Materials Science · Physics 2021-12-07 Sruthil Lal S. B , D Murali , Matthias Posselt , Assa Aravindh Sasikala Devi , Alok Sharan

Hydroxylation of the rutile TiO$_2$ (110) surface has attracted much attention as the excess unpaired electrons introduced by hydroxyls play a critical role in surface chemistry and photocatalysis process of this material. In this work,…

Materials Science · Physics 2015-10-13 Daoyu Zhang , Minnan Yang , Shuai Dong

Heterostructures comprising uncoated ZnO and coated with thin layers of Ga$_2$O$_3$ were produced using spin-coating and subsequent hydrothermal processing. X-ray diffraction examination verifies the structural integrity of the synthesized…

Materials Science · Physics 2025-06-25 Shashi Pandey , Swaroop Ganguly , Alok Shukla , Anurag Tripathi

Band alignment effects of anatase and rutile nanocrystals in TiO$_2$ powders lead to an electron hole separation, increasing the photo catalytic efficiency of these powders. While size effects and types of possible alignments have been…

Investigating quasiparticle excitations of molecules on surfaces through photoemission spectroscopy forms a major part of nanotechnology research. Resolving spectral features at these interfaces requires a comprehensive theory of electron…

Materials Science · Physics 2016-07-28 Christopher E. Patrick , Feliciano Giustino

A comprehensive phase diagram of lowest-energy structures and compositions of the rutile TiO_2(110) surface in equilibrium with a surrounding gas phase at finite temperatures and pressures has been determined using density functional theory…

Materials Science · Physics 2009-11-13 Piotr M. Kowalski , Bernd Meyer , Dominik Marx

Photothermal (photonic) sintering crystallizes as-deposited amorphous LiCoO2 (LCO) cathodes for solid-state thin-film batteries using millisecond, surface-localized heating. However, process design often relies on 1D models with…

Materials Science · Physics 2026-04-28 Yang Hu , Benoit Sklénard , Wouter Vels , Yaroslav E. Romanyuk , Vladyslav Turlo

We report thin-film InAs/GaAs quantum dot (QD) solar cells with $n-i-p{+}$ deep junction structure and planar back reflector fabricated by epitaxial lift-off (ELO) of full 3-inch wafers. External quantum efficiency measurements demonstrate…

Applied Physics · Physics 2018-05-28 F Cappelluti , D Kim , M van Eerden , AP Cédola , T Aho , G Bissels , F Elsehrawy , J Wu , H Liu , P Mulder , G Bauhuis , J Schermer , T Niemi , M Guina

Two-dimensional electron systems found at the interface of SrTiO3-based oxide heterostructures often display anisotropic electric transport whose origin is currently under debate. To characterize transport along specific crystallographic…

Strongly Correlated Electrons · Physics 2016-10-10 D. Fuchs , K. Wolff , R. Schäfer , R. Thelen , M. Le Tacon , R. Schneider

Atomic and electronic structures of TiO_2(110) surface with possible adsorptional, substitutional and interstitial Au or Pt elemental impurities at full and one-sixth monolayer concentrations were investigated by density functional theory…

Strongly Correlated Electrons · Physics 2012-11-19 Ersen Mete , Oğuz Gülseren , Şinasi Ellialtıoğlu

Accelerating the oxygen reduction reaction (ORR) is a main subject of electrocatalysis research.A critical step of ORR is the formation of the hydroperoxyl functional group (OOH*) intermediate. In this study, we investigate the influence of…

We propose a new linearizable model for the nonlinear photocurrent-voltage characteristics of nanocrystalline TiO$_2$ dye sensitized solar cells based on first principles and report predicted values for fill factors. Upon renormalization…

Other Condensed Matter · Physics 2009-11-13 J. S. Agnaldo , J. C. Cressoni , G. M. Viswanathan