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Epitaxial bilayer silicon oxide is a transferable two-dimensional material predicted to be a wide band gap semiconductor, with potential applications for deep UV optoelectronics, or as a building block of van der Waals heterostructures. The…

We use ab initio pseudopotential total energy calculations with a plane wave basis set to investigate the structural energetics of various phases of polymorphic NbN. Particular attention is given to its recently discovered superconducting…

mtrl-th · Physics 2015-06-26 S. Ogut , K. M. Rabe

The electronic structure of high-quality van der Waals multiferroic CuCrP$_2$S6 crystals was investigated applying photoelectron spectroscopy methods in combination with DFT analysis. Using X-ray photoelectron and near-edge X-ray absorption…

Comment on "Large energy gaps in CaC6 from tunneling spectroscopy: possible evidence of strong-coupling superconductivity"

Superconductivity · Physics 2008-09-22 N. Emery , C. Herold , S. Cahen , H. Rida , J. F. Mareche , P. Lagrange , G. Lamura

The electronic structure of the Fe-based superconductors is discussed, mainly from the point of view of first principles calculations in relation to experimental data. Comparisons and contrasts with cuprates are made. The problem of…

Superconductivity · Physics 2009-05-20 D. J. Singh

First-principles FLAPW-GGA band structure calculations were employed to examine the structural, electronic properties and the chemical bonding picture for four ZrCuSiAs-like Th-based quaternary pnictide oxides ThCuPO, ThCuAsO, ThAgPO, and…

Materials Science · Physics 2011-04-19 V. V. Bannikov , I. R. Shein , A. L. Ivanovskii

In their Comment (see cond-mat/0301237), Sandvik, Sengupta, and Campbell present some numerical evidences to support the existence of an extended bond-order-wave (BOW) phase at couplings (U,V) weaker than a tricritical point (U_t,V_t) in…

Strongly Correlated Electrons · Physics 2009-11-10 Eric Jeckelmann

It is shown that the van der Waals free-energy of polydisperse fluids, as introduced previously (L. Bellier-Castella, H. Xu and M. Baus, {J. Chem. Phys.} {113}, 8337 (2000)), predicts that for certain thermodynamic states (e.g. low…

Statistical Mechanics · Physics 2009-11-07 L. Bellier-Castella , M. Baus , H. Xu

The structural and elastic properties of orthorhombic black phosphorus have been investigated using first-principles calculations based on density functional theory. The structural parameters have been calculated using the local density…

Materials Science · Physics 2015-06-12 S. Appalakondaiah , G. Vaitheeswaran , S. Lebegue , N. E. Christensen , A. Svane

Building two-dimensional (2D) van der Waals (vdW) heterostructures and enhancing their properties through strain engineering unlocks new applications for their constituent materials. In this study, we present a comprehensive…

Materials Science · Physics 2024-10-23 Sarga P K , Karthik H J , Swastibrata Bhattacharyya

Non-metal nitrides are an exciting field of chemistry, featuring a significant number of compounds that can possess outstanding material properties. This characteristic relies on maximizing the number of strong covalent bonds, with…

Van der Waals (vdW) superconductors - atomically thin crystalline materials that can be stacked into more complex heterostructures - have opened a promising avenue for superconducting electronics thanks to their properties that are…

Superconductivity · Physics 2026-01-13 Angelo Di Bernardo , Elke Scheer

One of the central challenges in materials science is the design of functional and multifunctional materials, in which large responses are produced by applied fields and stresses. A rapidly developing paradigm for the rational design of…

Materials Science · Physics 2013-05-30 Anindya Roy , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

The discovery of new families of exfoliatable 2D crystals that have diverse sets of electronic, optical, and spin-orbit coupling properties, enables the realization of unique physical phenomena in these few-atom thick building blocks and in…

Misfit layered compounds are natural van der Waals heterostructures in which electronically active transition-metal dichalcogenide layers are decoupled by incommensurate blocking layers, enabling bulk realization of quasi-two-dimensional…

Novel structural building blocks in compounds could induce interesting physical and chemical properties. Although phosphorus tends to form very different motifs, the existence of lone pair electrons has always prevented the formation of…

Superconductivity · Physics 2022-01-13 Xing Li , Xiaohua Zhang , Aitor Bergara , Guoying Gao , Yong Liu , Guochun Yang

We show how van der Waals (vdW) forces outcompete covalent and ionic forces to control ferroelectric ordering in CuInP2S6 nanoflakes as well as in CuInP2S6 and CuBiP2Se6 crystals. While the self-assembly of these 2D layered materials is…

Materials Science · Physics 2018-05-31 Jeffrey R. Reimers , Sherif Abdulkader Tawfik , Michael J. Ford

Despite the increasing importance of hafnium in numerous technological applications, experimental and computational data on its binary alloys is sparse. In particular, data is scant on those binary systems believed to be phase separating.…

Materials Science · Physics 2009-07-30 Ohad Levy , Gus L. W. Hart , Stefano Curtarolo

The van der Waals density functional (vdW-DF) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)] is a promising approach for including dispersion in approximate density functional theory exchange-correlation functionals. Indeed, an…

Materials Science · Physics 2013-01-30 Jiří Klimeš , David R. Bowler , Angelos Michaelides

Ferroelectricity in atomically thin bilayer structures has been recently predicted1 and measured[2-4] in two-dimensional (2D) materials with hexagonal non-centrosymmetric unit-cells. Interestingly, the crystal symmetry translates lateral…

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