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In a macroscopic (quantum or classical) Hamiltonian system, we prove the second law of thermodynamics in the forms of the minimum work principle and the law of entropy increase, under the assumption that the initial state is described by a…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…

Mathematical Physics · Physics 2009-10-31 Elliott H. Lieb , Jakob Yngvason

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

Mathematical Physics · Physics 2022-08-16 Walter F. Wreszinski

The microscopic derivation of the second law for macroscopic system is given under the phenomenological assumption that both the initial and final states are described by mutually different canonical ensembles. In particular, it is also…

Classical Physics · Physics 2011-11-08 Takaaki Monnai

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

Firstly, we calculate quantitatively decrease of entropy by the known formulas in the ordering phenomena and nucleation of thermodynamics of microstructure. They show again that a necessary condition of decrease of entropy in isolated…

General Physics · Physics 2009-05-04 Yi-Fang Chang

The chemical reactions are very complex, and include oscillation, condensation, catalyst and self-organization, etc. In these case changes of entropy may increase or decrease. The second law of thermodynamics is based on an isolated system…

General Physics · Physics 2008-07-03 Yi-Fang Chang

The second law of thermodynamics can be formulated as a restriction on the evolution of the entropy of any system undergoing Markovian dynamics. Here I show that this form of the second law is strengthened for multi-dimensional, complex…

Statistical Mechanics · Physics 2024-02-14 David H. Wolpert

Several comments are given to previous proofs of the generalised second law of thermodynamics: black hole entropy plus ordinary matter entropy never decreases for a thermally closed system. Arguments in favour of its truism are given in the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 S. -T. Sung

A classical and quantum mechanical generalized second law of thermodynamics in cosmology implies constraints on the effective equation of state of the universe in the form of energy conditions, obeyed by many known cosmological solutions,…

General Relativity and Quantum Cosmology · Physics 2009-10-31 Ram Brustein

We revisit the conjecture of a generalized second law of thermodynamics which states that the combined entropy of matter and horizons must grow. In an expanding universe a generalized second law restricts the equation of state. In…

Astrophysics · Physics 2007-05-23 Wilfried Buchmuller , Joerg Jaeckel

In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…

Quantum Physics · Physics 2017-06-28 Thibaut Josset

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

The entropy of a thermally isolated system should not decrease after a quench or external driving. For a classical system following Hamiltonian dynamics, we show how this statement emerges for a large system in the sense that the extensive…

Statistical Mechanics · Physics 2020-12-24 Udo Seifert

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

A version of the second law of thermodynamics states that one cannot lower the energy of an isolated system by a cyclic operation. We prove this law without introducing statistical ensembles and by resorting only to quantum mechanics. We…

Statistical Mechanics · Physics 2013-04-02 Sheldon Goldstein , Takashi Hara , Hal Tasaki

We argue that the entanglement entropy for a very small subsystem obeys a property which is analogous to the first law of thermodynamics when we excite the system. In relativistic setups, its effective temperature is proportional to the…

High Energy Physics - Theory · Physics 2013-03-14 Jyotirmoy Bhattacharya , Masahiro Nozaki , Tadashi Takayanagi , Tomonori Ugajin

The explanation of the apparent universality of thermodynamics points toward the extension of the usual conceptual background of the second law. Arguments are collected that a basic guiding idea of stability of thermodynamic equilibrium…

Classical Physics · Physics 2014-07-23 P. Ván

We seek here to unify the second law of thermodynamics with the other laws, or at least to put up a law behind the second law of thermodynamics. Assuming no fine tuning, concretely by a random Hamiltonian, we argue just from equations of…

High Energy Physics - Theory · Physics 2008-11-26 Holger B. Nielsen , Masao Ninomiya

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert