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In this work we discuss the measurement protocols for indirect determination of the isothermal entropy change associated with first order phase transitions in caloric materials. The magneto- structural phase transitions giving rise to giant…

Materials Science · Physics 2017-01-04 Luana Caron , Nguyen Ba Doan , Laurent Ranno

Off-stoichiometric alloys based on Ni 2 MnIn have drawn attention due to the coupled first order magnetic and structural transformations, and the large magnetocaloric entropy associated with the transformations. Here we describe…

Materials Science · Physics 2016-01-05 Jing-Han Chen , Nickolaus M. Bruno , Ibrahim Karaman , Yujin Huang , Jianguo Li , Joseph H. Ross

Off-stoichiometric Ni$_2$MnIn Heusler alloys have drawn recent attention due to their large magnetocaloric entropy change associated with the first-order magneto-structural transition. Here we present crystal structural, calorimetric and…

Ni-Mn-based Heusler alloys, in particular all-d-metal Ni(-Co)-Mn-Ti, are highly promising materials for energy-efficient solid-state refrigeration as large multicaloric effects can be achieved across their magnetostructural martensitic…

We study the magnetocaloric effect and critical behavior of Co$_2$Cr$_{1-x}$Mn$_x$Al ($x=$ 0.25, 0.5, 0.75) Heusler alloys across the ferromagnetic (FM) transition (T$_{\rm C}$). The Rietveld refinement of x-ray diffraction patterns exhibit…

Materials Science · Physics 2020-01-08 Priyanka Nehla , V. K. Anand , Bastian Klemke , Bella Lake , R. S. Dhaka

The non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{36}$In$_{14}$ undergoes a martensitic phase transformation in the vicinity of 345 K, with the high temperature austenite phase exhibiting paramagnetic rather than ferromagnetic behavior, as…

Materials Science · Physics 2015-06-30 Jing-Han Chen , Nickolaus M. Bruno , Ibrahim Karaman , Yujin Huang , Jianguo Li , Joseph H. Ross

Systematic measurements pertinent to the magnetocaloric effect and nature of magnetic transition around the transition temperature are performed in the 10 nm Pr0.5Ca0.5MnO3 nanoparticles (PCMO10) . Maxwell relation is employed to estimate…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 S. Narayana Jammalamadaka , S. S. Rao , S. V. Bhat , J. Vanacken , V. V. Moshchalkov

We report a systematic study on the magneto-structural transition in Mn-rich Fe-doped Mn-Fe-Ni-Sn(Sb/In) Heusler alloys by keeping the total valence electron concentration (e/a ratio) fixed. The martensitic transition (MT) temperature is…

Materials Science · Physics 2019-01-30 Arup Ghosh , Rajeev Rawat , Arpan Bhattacharyya , Guruprasad Mandal , A. K. Nigam , Sunil Nair

We have studied the effect of magnetic field on a non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$ that undergoes a martensitic as well as a magnetic transition near room temperature. Temperature dependent magnetization…

Materials Science · Physics 2009-11-13 P. A. Bhobe , K. R. Priolkar , A. K. Nigam

We describe magneto-, baro- and elastocaloric effects (MCEs, BCEs and eCEs) in materials which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions. Our ab initio theory of the interacting…

Materials Science · Physics 2020-06-03 Eduardo Mendive-Tapia , Julie B. Staunton

Definitive determination of first order character of the magnetocaloric magnetic transition remains elusive. Here we use a microcalorimetry technique in two modes of operation to determine the contributions to entropy change from latent…

The isothermal magnetic entropy changes are studied in Ni80Fe20/Ni67Cu33/Co90Cu10/Mn80Ir20 stacks at temperatures near the Curie point of the Ni67Cu33 spacer by applying magnetic fields in a few tens of Oersted. Such low fields were…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 S. N. Vdovichev , N. I. Polushkin , I. D. Rodionov , V. N. Prudnikov , J. Chang , A. A. Fraerman

We report the magnetic, thermal, magnetocaloric and transport properties of polycrystalline NdCuSi. The compound shows a weak antiferromagnetic ordering, as confirmed by different measurements. Arrott plots indicate that the magnetic phase…

Strongly Correlated Electrons · Physics 2019-09-19 Sachin Gupta , K. G. Suresh1 , A. K. Nigam

The structural and magnetic properties of functional Ni-Mn-Z (Z = Ga, In, Sn) Heusler alloys are studied by first-principles and Monte Carlo methods. The \textit{ab initio} calculations give a basic understanding of the underlying physics…

At certain compositions Ni-Mn-$X$ Heusler alloys ($X$: group IIIA-VA elements) undergo martensitic transformations, and many of them exhibit inverse magnetocaloric effects. In alloys where $X$ is Sn, the isothermal entropy change is largest…

Materials Science · Physics 2009-11-13 Thorsten Krenke , Eyup Duman , Mehmet Acet , Xavier Moya , Lluis Manosa , Antoni Planes

Magnetocaloric effect (MCE), magnetization, specific heat, and magnetostriction measurements were performed in both pulsed and steady high magnetic fields to investigate the magnetocaloric properties of Heusler alloys Ni50-xCoxMn31.5Ga18.5…

Materials Science · Physics 2021-03-24 T. Kihara , T. Roy , X. Xu , A. Miyake , M. Tsujikawa , H. Mitamura , M. Tokunaga , Y. Adachi , T. Eto , T. Kanomata

Magnetic refrigeration based on the magnetocaloric effect (MCE) of materials is a potential technique that has prominet advantages over the currently used gas compression-expansion technique in the sense of its high efficiency and…

Materials Science · Physics 2023-10-18 B. G. Shen , J. R. Sun , F. X. Hu , H. W. Zhang , Z. H. Cheng

This work investigates the magnetic properties and the magnetocaloric effect in the spin-1 Blume-Capel model. The study was carried out using the mean-field theory from the Bogoliubov inequality to obtain the expressions of free energy,…

Materials Science · Physics 2022-03-29 S. Oliveira , R. H. M. Morais , J. P. Santos , F. C. Sá Barreto

Polycrystalline CrTe1-xSex samples were prepared using the conventional solid-state reaction technique and characterized by x-rad diffraction, temperature- and field- dependent magnetization for possible use in magnetocaloric cooling.…

Strongly Correlated Electrons · Physics 2022-11-15 Morad Kh. Hamad , I. C. Nlebedim , Yazan Maswadec , R. Hamad , Kh. A. Ziq

The elastocaloric effect in the vicinity of the martensitic transition of a Cu-Zn-Al has been studied by inducing the transition by strain or stress measurements. While transition trajectories show significant differences, the entropy…

Materials Science · Physics 2009-11-13 Erell Bonnot , Ricardo Romero , Lluis Manosa , Eduard Vives , Antoni Planes
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